A Systematic Study on Activation Processes in Organotellurium-Mediated Living Radical Polymerizations of Styrene, Methyl Methacrylate, Methyl Acrylate, and Vinyl Acetate

2006 ◽  
Vol 39 (14) ◽  
pp. 4671-4679 ◽  
Author(s):  
Yungwan Kwak ◽  
Atsushi Goto ◽  
Takeshi Fukuda ◽  
Yu Kobayashi ◽  
Shigeru Yamago
2001 ◽  
Vol 34 (3) ◽  
pp. 402-408 ◽  
Author(s):  
Atsushi Goto ◽  
Koichi Sato ◽  
Yoshinobu Tsujii ◽  
Takeshi Fukuda ◽  
Graeme Moad ◽  
...  

The paper describes the construction of a cinematographic recording interferometer based on the Jamin type. By using the interferometer tubes as reaction cells the instrument has been used for following the photopolymerization of styrene, methyl methacrylate, methyl acrylate and vinyl acetate. The sensitivity of the apparatus permits the non-stationary phase of the reaction to be followed. In this way the velocity coefficients for the elementary steps of these reactions have been measured and compared with the values obtained by other non-stationary state methods and by the rotating sector technique.


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