Free Radical Polymerization ofn-Butyl Methacrylate in Ionic Liquids

2006 ◽  
Vol 39 (3) ◽  
pp. 923-930 ◽  
Author(s):  
Veronika Strehmel ◽  
André Laschewsky ◽  
Hendrik Wetzel ◽  
Eckhard Görnitz
Keyword(s):  
Ionic Liquids ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Butyl Methacrylate

scholarly journals Fluoroponytailed Ionic Liquids as Co-Porogens for Poly(butyl methacrylate-co-ethylene dimethacrylate) Monolithic Supports for Thin Layer Chromatography

The Analyst ◽  
2022 ◽  
Author(s):  
Manuel Otter ◽  
Gabriel Partl ◽  
Michael Franz Noisternig ◽  
Rania Bakry
Keyword(s):  
Ionic Liquids ◽  
Free Radical ◽  
Thin Layer ◽  
Thin Layer Chromatography ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Butyl Methacrylate ◽  
Ethylene Dimethacrylate ◽  
Layer Chromatography

Porous layered monolithic substrates of poly(butyl methacrylate-co-ethylene dimethacrylate) were synthesized via UV initiated free radical polymerization in presence of fluoroponytailed ionic liquids as co-porogenic constituents. The effects of the type...

scholarly journals New ionic liquids with hydrolytically stable anions as alternatives to hexafluorophosphate and tetrafluoroborate salts in the free radical polymerization and preparation of ion-conducting composites

2010 ◽  
Vol 43 (2) ◽  
pp. 126-135 ◽  
Author(s):  
Yakov S Vygodskii ◽  
Dmitrii A Sapozhnikov ◽  
Alexander S Shaplov ◽  
Elena I Lozinskaya ◽  
Nikolai V Ignat'Ev ◽  
...  
Keyword(s):  
Ionic Liquids ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Ion Conducting ◽  
Conducting Composites

Ionic Liquids as Advantageous Reaction Media for Free Radical Polymerization

2014 ◽  
Vol 342 (1) ◽  
pp. 78-85 ◽  
Author(s):  
Veronika Strehmel ◽  
Hendrik Wetzel ◽  
André Laschewsky
Keyword(s):  
Ionic Liquids ◽  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Reaction Media

scholarly journals Sodium nitrite and ascorbic acid: a metal-free combination that controls the free-radical polymerization of tert-butyl methacrylate in water

e-Polymers ◽  
2002 ◽  
Vol 2 (1) ◽  
Author(s):  
Christophe Detrembleur ◽  
Ange Mouithys-Mickalad ◽  
Philippe Teyssié ◽  
Robert Jérôme
Keyword(s):  
Nitric Oxide ◽  
Ascorbic Acid ◽  
Free Radical ◽  
Radical Polymerization ◽  
Sodium Nitrite ◽  
Free Radical Polymerization ◽  
Nitroxyl Radicals ◽  
Butyl Methacrylate ◽  
Metal Free ◽  
Tert Butyl

AbstractA mixture of sodium nitrite and ascorbic acid is able to control the radical polymerization of tert-butyl methacrylate (tBMA) in water at 80°C. Indeed, sodium nitrite is reduced by the ascorbic acid, and the nitric oxide (NO) which is formed insitu is nothing but a promoter of nitroxyl radicals. The radical polymerization of tBMA is thus basically controlled by a nitroxide-mediated process.

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