Propagation Mechanisms in Ring-Opening Polymerization of Small Phosphorus Heterocycles:  Toward Free-Radical Polymerization of Phosphines?

2005 ◽  
Vol 38 (21) ◽  
pp. 8902-8910 ◽  
Author(s):  
Jennifer L. Hodgson ◽  
Michelle L. Coote
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Free Radical Polymerization ◽  
Ring Opening Polymerization ◽  
Phosphorus Heterocycles

Vinyl benzoxazine: a novel heterobifunctional monomer that can undergo both free radical polymerization and cationic ring-opening polymerization

RSC Advances ◽  
2015 ◽  
Vol 5 (124) ◽  
pp. 102441-102447 ◽  
Author(s):  
He-Ming Ma ◽  
Yun Liu ◽  
Ying-Xuan Liu ◽  
Jin-Jun Qiu ◽  
Cheng-Mei Liu
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Free Radical Polymerization ◽  
Ring Opening Polymerization ◽  
Vinyl Group ◽  
Cationic Ring Opening Polymerization

A novel heterobifunctional monomer (6-ethenyl-3-phenyl-3,4-dihydro-2H-1,3-benzoxazine (VBOZO)) containing both a vinyl group and benzoxazine group was successfully prepared and the homo- and copolymerization reactions of this monomer were studied.

Free-Radical Polymerization and Ring-Expansion of a Cubane Acrylate: a Unique Low-Shrink Polymer

2009 ◽  
Vol 62 (2) ◽  
pp. 145 ◽  
Author(s):  
Alison E. McGonagle ◽  
G. Paul Savage
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Free Radical Polymerization ◽  
Ring Expansion ◽  
Side Chain ◽  
Molecular Volume ◽  
Acrylate Polymer

A pendant cubane substituent has been incorporated into an acrylate polymer side chain to give poly[methyl 4-(acryloyloxymethyl)cubane carboxylate]. Treating this polymer with a rhodium(i) salt triggers a catalytic, ring-opening rearrangement of the cubane substructure to cyclooctatetraene, with a concomitant expansion in molecular volume. This system offers a unique opportunity to reverse the shrinkage associated with polymerization.

scholarly journals Novel Multifunctional Epoxy (Meth)acrylate Resins and Coatings Preparation via Cationic and Free-Radical Photopolymerization

Polymers ◽  
2021 ◽  
Vol 13 (11) ◽  
pp. 1718
Author(s):  
Paulina Bednarczyk ◽  
Izabela Irska ◽  
Konrad Gziut ◽  
Paula Ossowicz-Rupniewska
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Free Radical Polymerization ◽  
Matter Content ◽  
Polymer Chains ◽  
Rate Coefficients ◽  
Structural Factors ◽  
Yellowness Index ◽  
Free Radical Photopolymerization

In this work, a series of novel multifunctional epoxy (meth)acrylate resins based on a low-viscosity aliphatic triepoxide triglycidyl ether of trimethylolethane (TMETGE) and acrylic acid (AA) or methacrylic acid (MMA) have been synthesized. Thanks to the performed modification, the obtained prepolymers have both epoxides as well as carbon–carbon double bonds and differ in their amount. The obtained results indicate that the carboxyl-epoxide addition esterification occurs in the presence of a catalyst (triphenylphosphine) at a temperature of 90 °C, whilst the required degree of conversion can be achieved simply by varying both the reagents ratio and reaction time. The structure of synthesized copolymers was confirmed by spectroscopic analyses (FT-IR, 1H NMR, 13C NMR) and studied regarding its nonvolatile matter content (NV), acid value (PAVs), as well as its epoxy equivalent value (EE). Due to the presence of both epoxy and double carbon–carbon pendant groups, one can apply two distinct mechanisms: (i) cationic ring-opening polymerization or (ii) free-radical polymerization to crosslink polymer chains. Synthesized epoxy (meth)acrylate prepolymers were further employed to formulate photocurable coating compositions. Hence, when cationic photoinitiators were applied, polyether-type polymer chains with pending acrylate or methacrylate groups were formed. In the case of free-radical polymerization, epoxy (meth)acrylates certainly formed a poly(meth)acrylate backbone with pending epoxy groups. Further, photopolymerization behavior and properties of cured coatings were investigated regarding some structural factors and parameters. Moreover, reaction rate coefficients of photo-cross-linking by both cationic ring-opening and free-radical photopolymerization of the received epoxy (meth)acrylate resins were determined via real-time infrared spectroscopy (RT-IR). Lastly, basic physicomechanical properties, such as tack-free time, hardness, adhesion, gloss, and yellowness index of cured coatings, were evaluated.

Fabrication of cross-linked fluorescent polymer nanoparticles and their cell imaging applications

2015 ◽  
Vol 3 (8) ◽  
pp. 1854-1860 ◽  
Author(s):  
Ke Wang ◽  
Xiaoyong Zhang ◽  
Xiqi Zhang ◽  
Bin Yang ◽  
Zhen Li ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Ring Opening ◽  
Cell Imaging ◽  
Free Radical Polymerization ◽  
Polymer Nanoparticles ◽  
Aggregation Induced Emission ◽  
Ring Opening Reaction ◽  
Fluorescent Polymer

Fabrication of aggregation induced emission dye based cross-linked fluorescent polymer nanoparticlesviafree radical polymerization and ring-opening reaction for bioimaging.

Sign in / Sign up

Export Citation Format

Share Document