DFT Investigation of the Single-Center, Two-State Model for the Broken Rate Order of Transition Metal Catalyzed Olefin Polymerization

2005 ◽  
Vol 38 (24) ◽  
pp. 10266-10278 ◽  
Author(s):  
Vidar R. Jensen ◽  
Debasis Koley ◽  
Mavinahalli N. Jagadeesh ◽  
Walter Thiel
Keyword(s):  
Transition Metal ◽  
Olefin Polymerization ◽  
State Model ◽  
Single Center ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Two State Model

Late transition metal catalyzed α-olefin polymerization and copolymerization with polar monomers

2017 ◽  
Vol 1 (12) ◽  
pp. 2487-2494 ◽  
Author(s):  
Lihua Guo ◽  
Wenjing Liu ◽  
Changle Chen
Keyword(s):  
Transition Metal ◽  
Olefin Polymerization ◽  
Late Transition Metal ◽  
Recent Developments ◽  
Polar Monomers ◽  
Transition Metal Catalyzed ◽  
Late Transition ◽  
Metal Catalyzed

Recent developments on late transition metal catalyzed α-olefin polymerization and copolymerization with polar comonomers are reviewed.

scholarly journals α-Diimine Synthesis via Titanium-Mediated Multicomponent Diimination of Alkynes with C-Nitrosos 

2022 ◽  
Author(s):  
Connor Wesley Frye ◽  
Dominic Thomas Egger ◽  
Errikos Kounalis ◽  
Adam J Pearce ◽  
Yukun Cheng ◽  
...  
Keyword(s):  
Transition Metal ◽  
Olefin Polymerization ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

α-Diimines are commonly used as supporting ligands for a variety of transition metal-catalyzed processes, most notably in α-olefin polymerization. They are also precursors to valuable synthetic targets, such as chiral...

Flexible cycloalkyl substituents in insertion polymerization with α-diimine nickel and palladium species

2020 ◽  
Vol 11 (7) ◽  
pp. 1393-1400 ◽  
Author(s):  
Shengyu Dai ◽  
Shuaikang Li ◽  
Guoyong Xu ◽  
Cheng Wu ◽  
Yudan Liao ◽  
...  
Keyword(s):  
Transition Metal ◽  
Olefin Polymerization ◽  
Insertion Polymerization ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
The Relationship ◽  
Broad Interest

The investigation of the relationship between the structure of the catalyst and the microstructure of the obtained polymer has attracted much attention and broad interest in the field of transition metal-catalyzed olefin polymerization.

Ion pairing in transition metal catalyzed olefin polymerization

2020 ◽  
pp. 1-78 ◽  
Author(s):  
Francesco Zaccaria ◽  
Leonardo Sian ◽  
Cristiano Zuccaccia ◽  
Alceo Macchioni
Keyword(s):  
Transition Metal ◽  
Olefin Polymerization ◽  
Ion Pairing ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

Chelation-assisted transition metal-catalysed C–H chalcogenylations

2020 ◽  
Vol 7 (8) ◽  
pp. 1022-1060 ◽  
Author(s):  
Wenbo Ma ◽  
Nikolaos Kaplaneris ◽  
Xinyue Fang ◽  
Linghui Gu ◽  
Ruhuai Mei ◽  
...  
Keyword(s):  
Transition Metal ◽  
Recent Advances ◽  
Site Selectivity ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed

This review summarizes recent advances in C–S and C–Se formations via transition metal-catalyzed C–H functionalization utilizing directing groups to control the site-selectivity.

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