Phase Behavior and Viscoelastic Properties of Thermoplastic Elastomer Gels Based on ABC Triblock Copolymers

2005 ◽  
Vol 38 (18) ◽  
pp. 7798-7806 ◽  
Author(s):  
Daisuke Yamaguchi ◽  
Michel Cloitre ◽  
Pierre Panine ◽  
Ludwik Leibler
Keyword(s):  
Phase Behavior ◽  
Viscoelastic Properties ◽  
Triblock Copolymers ◽  
Thermoplastic Elastomer ◽  
Abc Triblock Copolymers

Phase Behavior of Triblock Copolymers upon Incorporation of Non-Parent, Midblock-Associating Additives

1996 ◽  
Vol 461 ◽  
Author(s):  
J. H. Laurer ◽  
J. F. Mulling ◽  
R. Bukovnik ◽  
R. J. Spontak
Keyword(s):  
Molecular Weight ◽  
Block Copolymer ◽  
Phase Behavior ◽  
Triblock Copolymer ◽  
Triblock Copolymers ◽  
Thermoplastic Elastomer ◽  
Low Molecular Weight ◽  
Repulsive Interactions

ABSTRACTAddition of a block-selective homopolymer to a microphase-ordered block copolymer is known to result in preferential swelling of the chemically compatible microdomain. In this work, we examine the miscibility between a triblock copolymer and a relatively low-molecular-weight, chemically dissimilar, midblock-associating homopolymer and demonstrate that the homopolymer molecules residing in the swollen midblock matrix self-assemble to avoid repulsive interactions with neighboring microdomains. We extend this investigation to include systems composed of a very low-molecular-weight, midblock-associating additive (an oil). At high oil concentrations, the glassy copolymer endblocks micellize, resulting in the formation of a thermoplastic elastomer gel.

Phase Behavior of Nonfrustrated ABC Triblock Copolymers: Weak and Intermediate Segregation

2010 ◽  
Vol 43 (11) ◽  
pp. 5128-5136 ◽  
Author(s):  
Jian Qin ◽  
Frank S. Bates ◽  
David C. Morse
Keyword(s):  
Phase Behavior ◽  
Triblock Copolymers ◽  
Abc Triblock Copolymers

scholarly journals Effect of solvophobicity on the phase behavior of linear ABC triblock copolymers in selective solvents: a Monte Carlo study

RSC Advances ◽  
2018 ◽  
Vol 8 (47) ◽  
pp. 26959-26967
Author(s):  
Zhihua Gao ◽  
Jie Cui ◽  
Yuanyuan Han ◽  
Wei Jiang
Keyword(s):  
Monte Carlo ◽  
Phase Behavior ◽  
Triblock Copolymers ◽  
Monte Carlo Study ◽  
Abc Triblock Copolymers ◽  
Selective Solvents ◽  
Micro Structures

The solvophobicity difference and incompatibility between different solvophobic blocks determine the overall shapes and micro-structures of micelles formed by linear ABC terpolymers.

Stable Superhydrophobic Porous Coatings from Hybrid ABC Triblock Copolymers and Their Anticorrosive Performance

2017 ◽  
Vol 9 (35) ◽  
pp. 30056-30063 ◽  
Author(s):  
Xin Zhou ◽  
Junhua Kong ◽  
Jiaotong Sun ◽  
Hui Li ◽  
Chaobin He
Keyword(s):  
Triblock Copolymers ◽  
Porous Coatings ◽  
Abc Triblock Copolymers

Antinucleation Effect of the Polyethylene Block on the Polycaprolactone Block in ABC Triblock Copolymers

1998 ◽  
Vol 31 (22) ◽  
pp. 7756-7763 ◽  
Author(s):  
V. Balsamo ◽  
A. J. Müller ◽  
R. Stadler
Keyword(s):  
Triblock Copolymers ◽  
Abc Triblock Copolymers
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