Kinetics of the Benzoyl Peroxide/Amine Initiated Free-Radical Polymerization of Dental Dimethacrylate Monomers:  Experimental Studies and Mathematical Modeling for TEGDMA and Bis-EMA

2004 ◽  
Vol 37 (11) ◽  
pp. 4254-4265 ◽  
Author(s):  
Dimitris S. Achilias ◽  
Irini D. Sideridou
Keyword(s):  
Mathematical Modeling ◽  
Free Radical ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Experimental Studies ◽  
Free Radical Polymerization ◽  
Kinetics Of

scholarly journals Highlight on the Mathematical Modeling of Controlled Free Radical Polymerization

2015 ◽  
Vol 2015 ◽  
pp. 1-12 ◽  
Author(s):  
Mamdouh A. Al-Harthi
Keyword(s):  
Mathematical Modeling ◽  
Monte Carlo Simulation ◽  
Free Radical ◽  
Radical Polymerization ◽  
Method Of Moments ◽  
Experimental Studies ◽  
Free Radical Polymerization ◽  
Polymer Science ◽  
Science And Engineering ◽  
Quarter Century

Over the last quarter century, controlled free radical polymerization (CFRP) has received great attention by the researchers of polymer science and engineering. In addition to the experimental studies, many publications in the literature dealt with the modeling of CFRP processes. A review of acknowledged and well-received researches on mathematical modeling in the area of CFRP is presented in this work. Three main categories of CFRP (namely, ATRP, RAFT, and NMP) are taken into consideration in the review. The different techniques used in modeling CFRP processes are also enumerated with more emphasis on Monte Carlo simulation and the method of moments. The review provides a better understanding of the processes and the recent efforts to model CFRP.

Non-isothermal Kinetics of Free Radical Polymerization of 2-Phenylethyl (Meth)acrylate

2018 ◽  
Vol 8 (3) ◽  
pp. 585-594
Author(s):  
Khdbudin Mulani ◽  
Ravindra Ghorpade ◽  
Surendra Ponrathnam ◽  
Nayaku Chavan ◽  
Kamini Donde
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Isothermal Kinetics ◽  
Kinetics Of

The Kinetics of Free-Radical Polymerization: Fundamental Aspects

2002 ◽  
Vol 55 (7) ◽  
pp. 399 ◽  
Author(s):  
G. T. Russell
Keyword(s):  
Molecular Weight ◽  
Steady State ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Free Radical Polymerization ◽  
Length Dependence ◽  
Model Independent ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed.

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