scholarly journals Mechanism of Fatigue Crack Growth in Carbon Black Filled Natural Rubber

2004 ◽  
Vol 37 (13) ◽  
pp. 5011-5017 ◽  
Author(s):  
J.-B. Le Cam ◽  
B. Huneau ◽  
E. Verron ◽  
L. Gornet
Author(s):  
Lewis B. Tunnicliffe

ABSTRACT Fatigue crack growth behavior of carbon black–reinforced natural rubber is investigated. Rubber compounds of Shore A = 70 are prepared by varying the formulation loadings of a wide range of carbon black types based on their structure and surface area properties. The resulting fatigue crack growth behavior shows significant variation in β exponent values, depending on the properties of the carbon black. These variations are rationalized by considering the strain amplification of natural rubber by carbon black aggregates in the region of compound directly ahead of the crack tip. An assumption is made that little networking of the carbon black aggregates exists in this region of very high strain and that hydrodynamic calculations that consider occluded rubber can therefore provide realistic values for strain amplification. A reasonable scaling of power law crack growth parameters to calculated strain amplification factors is found, with the exponent, β, decreasing with increasing strain amplification. The implication here is that enhanced strain amplification promotes the formation of strain-induced crystallites in the crack tip region. Performance tradeoffs resulting from the crossover of crack growth data sets dependent on the carbon black type are discussed. Of practical significance is the fact that the strain amplification factors can be calculated directly from knowledge of carbon black type and loading in rubber formulations.


2012 ◽  
Vol 41 (7) ◽  
pp. 273-276 ◽  
Author(s):  
L. Munoz ◽  
L. Vanel ◽  
O. Sanseau ◽  
P. Sotta ◽  
D. Long ◽  
...  

2010 ◽  
Vol 83 (4) ◽  
pp. 391-403 ◽  
Author(s):  
G. Andreini ◽  
P. Straffi ◽  
S. Cotugno ◽  
G. Gallone ◽  
G. Polacco

Abstract Fatigue crack growth experiments on carbon black-filled rubber compounds have been carried out to evaluate the influence of testing conditions over different compound formulations. Investigations on the influence of waveform, data acquisition, and compound formulation have been performed on strip-tensile specimens reproducing the mode I of crack opening. The response of three different compound formulations (based on either natural rubber, butadiene rubber, or styrene-butadiene rubber) to the application of two different waveforms, pulse and sine, has been analyzed, showing significant differences in fatigue behavior and ranking of the various compounds. Compared to the sinusoidal waveform, the use of a pulse waveform provided an improved correlation of the tearing energy with the crack propagation speed. This difference was particularly evident in the case of natural rubber and butadiene rubber, while it resulted negligible in the case of styrene-butadiene rubber. Such a different behavior could be attributed to differences in macromolecular chains orientation. Fine-tuning of video acquisition parameters provided an accurate observation of the crack growth process, as confirmed by the low standard deviation of the estimated tearing energy and crack growth rate.


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