Nanotube Networks in Polymer Nanocomposites:  Rheology and Electrical Conductivity

2004 ◽  
Vol 37 (24) ◽  
pp. 9048-9055 ◽  
Author(s):  
Fangming Du ◽  
Robert C. Scogna ◽  
Wei Zhou ◽  
Stijn Brand ◽  
John E. Fischer ◽  
...  
Keyword(s):  
Electrical Conductivity ◽  
Polymer Nanocomposites

Dual percolations of electrical conductivity and electromagnetic interference shielding in progressively agglomerated CNT/polymer nanocomposites

2021 ◽  
pp. 108128652110214
Author(s):  
Xiaodong Xia ◽  
George J. Weng
Keyword(s):  
Experimental Data ◽  
Electrical Conductivity ◽  
Carbon Nanotube ◽  
Percolation Threshold ◽  
Polymer Nanocomposites ◽  
Electromagnetic Interference ◽  
Effective Medium Theory ◽  
Scale Model ◽  
Shielding Effectiveness ◽  
Emi Shielding

Recent experiments have revealed two distinct percolation phenomena in carbon nanotube (CNT)/polymer nanocomposites: one is associated with the electrical conductivity and the other is with the electromagnetic interference (EMI) shielding. At present, however, no theories seem to exist that can simultaneously predict their percolation thresholds and the associated conductivity and EMI curves. In this work, we present an effective-medium theory with electrical and magnetic interface effects to calculate the overall conductivity of a generally agglomerated nanocomposite and invoke a solution to Maxwell’s equations to calculate the EMI shielding effectiveness. In this process, two complex quantities, the complex electrical conductivity and complex magnetic permeability, are adopted as the homogenization parameters, and a two-scale model with CNT-rich and CNT-poor regions is utilized to depict the progressive formation of CNT agglomeration. We demonstrated that there is indeed a clear existence of two separate percolative behaviors and showed that, consistent with the experimental data of poly-L-lactic acid (PLLA)/multi-walled carbon nanotube (MWCNT) nanocomposites, the electrical percolation threshold is lower than the EMI shielding percolation threshold. The predicted conductivity and EMI shielding curves are also in close agreement with experimental data. We further disclosed that the percolative behavior of EMI shielding in the overall CNT/polymer nanocomposite can be illustrated by the establishment of connective filler networks in the CNT-poor region. It is believed that the present research can provide directions for the design of CNT/polymer nanocomposites in the EMI shielding components.

Copolymer-Nanoparticles Mixture in a Cylindrical Pore

NANO ◽  
2017 ◽  
Vol 12 (04) ◽  
pp. 1750045
Author(s):  
Jun-Xing Pan ◽  
Yu-Qi Guo ◽  
Yu-Fang Han ◽  
Min-Na Sun ◽  
Jin-Jun Zhang
Keyword(s):  
Phase Transition ◽  
Electrical Conductivity ◽  
Polymer Nanocomposites ◽  
Diblock Copolymer ◽  
Large Diameter ◽  
Small Diameter ◽  
Confinement Effect ◽  
Cylindrical Pore ◽  
Disorder Phase Transition ◽  
Novel Structures

Computer simulation is carried out for investigating the effect of nanoparticles on diblock copolymer morphology under cylindrical confinement. The phase diagrams of polymer nanocomposites with nanoparticle-block wetting strength and concentration of nanoparticles are obtained in different nanopores. In small diameter nanopore, there is almost no influence of nanoparticles on the diblock copolymer morphology because of the stronger confinement effect; in middle diameter nanopore, the system can self-assemble into various novel structures due to the interaction between confinement effect and nanoparticles effect; in large diameter nanopore, due to the stronger effect of nanoparticles, a disorder-order-disorder phase transition occurs with the wetting strength and concentration of nanoparticles increasing. This result can be useful in designing new nanocomposites with advanced electrical conductivity and/or mechanical strength.

Analysis of Clustering and Interphase Region Effects on the Electrical Conductivity of Carbon Nanotube-Polymer Nanocomposites via Computational Micromechanics

2008 ◽  
Author(s):  
Gary D. Seidel ◽  
Kelli L. Boehringer ◽  
Dimitris C. Lagoudas
Keyword(s):  
Electrical Conductivity ◽  
Polymer Nanocomposites ◽  
Effective Conductivity ◽  
Interphase Layer ◽  
Finite Element Software ◽  
Interphase Region ◽  
Effective Electrical Conductivity ◽  
Wide Range ◽  
Electrical Conductivities ◽  
Computational Micromechanics

In the present work, computational micromechanics techniques are applied towards predicting the effective electrical conductivities of polymer nanocomposites containing aligned bundles of SWCNTs at wide range of volume fractions. Periodic arrangements of well-dispersed and clustered/bundled SWCNTs are studied using the commercially available finite element software COMSOL Multiphysics 3.4. The volume averaged electric field and electric flux obtained are used to calculate the effective electrical conductivity of nanocomposites in both cases, therefore indicating the influence of clustering on the effective electrical conductivity. In addition, the influence of the presence of an interphase region on the effective electrical conductivity is considered in a parametric study in terms of both interphase thickness and conductivity for both the well dispersed case and for the clustered arrangements. Comparing the well-dispersed case with an interphase layer to the same arrangement without the interphase layer allows for the assessment of the influence of the interphase layer on the effective electrical conductivities, while similar comparisons for the clustered arrangements yield information about the combined effects of clustering and interphase regions. Initial results indicate that there is very little influence of the interphase layer on the effective conductivity prior to what is identified as the interphase percolation concentration, and that there is an appreciable combined effect of clustering in the presence of interphase regions which leads to increases in conductivity larger than the sum of the two effects independently.

Modeling electrical conductivity of polymer nanocomposites with aggregated filler

2020 ◽  
Vol 60 (7) ◽  
pp. 1556-1565 ◽  
Author(s):  
Aleksey D. Drozdov ◽  
Jesper Claville Christiansen
Keyword(s):  
Electrical Conductivity ◽  
Polymer Nanocomposites

Electrical conductivity of multiwalled carbon nanotubes/polyester polymer nanocomposites

2016 ◽  
Vol 50 (23) ◽  
pp. 3283-3290 ◽  
Author(s):  
K Abazine ◽  
H Anakiou ◽  
M El Hasnaoui ◽  
MPF Graça ◽  
MA Fonseca ◽  
...  
Keyword(s):  
Carbon Nanotubes ◽  
Electrical Conductivity ◽  
Polymer Nanocomposites ◽  
Multiwalled Carbon Nanotubes ◽  
Multiwalled Carbon

Electrical Conductivity of Graphene/Polymer Nanocomposites

2014 ◽  
Vol 3 (1) ◽  
pp. 48-65 ◽  
Author(s):  
Jizhen Zhang ◽  
Jianguo Qiu ◽  
Jingquan Liu
Keyword(s):  
Electrical Conductivity ◽  
Polymer Nanocomposites
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