Asymmetric Electrochemical Polymerization:  Preparation of Polybithiophene in a Chiral Nematic Liquid Crystal Field and Optically Active Electrochromism

2005 ◽  
Vol 38 (4) ◽  
pp. 1091-1098 ◽  
Author(s):  
Hiromasa Goto ◽  
Kazuo Akagi
Keyword(s):  
Liquid Crystal ◽  
Crystal Field ◽  
Nematic Liquid Crystal ◽  
Electrochemical Polymerization ◽  
Optically Active ◽  
Chiral Nematic

Macroscopically Aligned Helical Conjugated Polymers in Orientation-Controllable Chiral Nematic Liquid Crystal Field

2009 ◽  
Vol 42 (6) ◽  
pp. 1817-1823 ◽  
Author(s):  
Taizo Mori ◽  
Tetsuya Sato ◽  
Mutsumasa Kyotani ◽  
Kazuo Akagi
Keyword(s):  
Liquid Crystal ◽  
Conjugated Polymers ◽  
Crystal Field ◽  
Nematic Liquid Crystal ◽  
Chiral Nematic

Macroscopically Aligned Helical Polyacetylene Synthesized in Magnetically Oriented Chiral Nematic Liquid Crystal Field

2010 ◽  
Vol 43 (14) ◽  
pp. 5943-5948 ◽  
Author(s):  
Munju Goh ◽  
Takayuki Matsushita ◽  
Hikaru Satake ◽  
Mutsumasa Kyotani ◽  
Kazuo Akagi
Keyword(s):  
Liquid Crystal ◽  
Crystal Field ◽  
Nematic Liquid Crystal ◽  
Chiral Nematic

A robust and inexpensive all optical switch with chiral nematic liquid crystal

2021 ◽  
Vol 119 ◽  
pp. 111306
Author(s):  
Hossein mehrzad ◽  
Ezeddin Mohajerani ◽  
Mohammad Mohammadimasoudi ◽  
Kristiaan Neyts
Keyword(s):  
Liquid Crystal ◽  
Nematic Liquid Crystal ◽  
Optical Switch ◽  
Chiral Nematic ◽  
All Optical ◽  
All Optical Switch

Optically activated shutter using a photo-tunable short-pitch chiral nematic liquid crystal

2013 ◽  
Vol 103 (10) ◽  
pp. 101105 ◽  
Author(s):  
S. M. Morris ◽  
M. M. Qasim ◽  
K. T. Cheng ◽  
F. Castles ◽  
D.-H. Ko ◽  
...  
Keyword(s):  
Liquid Crystal ◽  
Nematic Liquid Crystal ◽  
Chiral Nematic

scholarly journals Mechanisms of Chiral Transfer in Optically Active Dopant – Nematic Liquid Crystal Systems

2020 ◽  
Vol 20 (4) ◽  
pp. 6-26
Author(s):  
V. A. Burmistrov ◽  
V. V. Aleksandriiskii ◽  
I. V. Novikov ◽  
O. I. Koifman
Keyword(s):  
Liquid Crystal ◽  
Nematic Liquid Crystal ◽  
Self Assembly ◽  
Liquid Crystalline ◽  
High Efficiency ◽  
Stationary Phases ◽  
Theoretical Description ◽  
Optically Active ◽  
Axial Coordination ◽  
Chiral Dopants

Induction of helical mesophases by incorporating chiral dopants into the nematics matrix is the promising modern trends in the chemistry of liquid crystals. This process is associated with a unique phenomenon - an amplification of chirality in liquid-crystalline phases, which ensures the detection of enantiomers by their chiral induction, much more sensitive than other methods. The relevance of this approach is due to the need to create perspective electro-optical devices operating with ultra-low control voltages based on twist effects, chromatographic stationary phases with high chiral selectivity, flexible magnets, photo-sensitive nanostructures, and other smart LC materials. The successful solution of these problems is impossible without experimental research and theoretical comprehension of the mechanisms of third level chiral transfer optically active dopant – nematic liquid crystal. In the last decade, a large number of works have appeared on the solution of these problems. This review is devoted to a generalization of the experimental results and a theoretical description of the transfer of molecular chirality to orientationally ordered systems with the participation of both chiral molecular substituents with an asymmetric carbon atom and planar or quasi-planar fragments chirally distorted relative to each other. The stereochemical aspects of induction associated with the structural correspondences of the dopant and nematic liquid crystal, as well as the main classes of optically active additives, are discussed. Application of metal complexes, both Werner and macroheterocyclic, are presented. Special attention is paid to the results of the mechanisms study of chiral transfer due to various intermolecular interactions: hydrogen bonding, axial coordination, and the formation of inclusion compounds. The high efficiency of induction of spiral mesophases has been demonstrated with a combination of different self-assembly mechanisms in liquid crystal - chiral additive systems.

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