A Dual Catalyst System for Atom Transfer Radical Polymerization Based on a Halogen-Free Neutral Cu(I) Complex

2003 ◽  
Vol 36 (20) ◽  
pp. 7432-7438 ◽  
Author(s):  
Yoshihisa Inoue ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalyst System ◽  
Atom Transfer ◽  
Halogen Free

Synthesis of halogen-free amino-functionalized polymethyl methacrylate by atom transfer radical polymerization(ATRP)

2004 ◽  
Vol 210 (1) ◽  
pp. 147-155 ◽  
Author(s):  
Veera Bhadraiah Sadhu ◽  
Jürgen Pionteck ◽  
Dieter Voigt ◽  
Hartmut Komber ◽  
Brigitte Voit
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Polymethyl Methacrylate ◽  
Free Amino ◽  
Atom Transfer ◽  
Halogen Free

ATRP Synthesis of PS-b-PtBMA and Preparation of Porous Film

2013 ◽  
Vol 364 ◽  
pp. 679-683
Author(s):  
Chang Hao Yan ◽  
Zhi Jiao Zhang ◽  
Hai Yan Chen ◽  
Zhong Yi Xie ◽  
Ting Zhu ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalyst System ◽  
Porous Film ◽  
Atom Transfer ◽  
H Nmr ◽  
Breath Figure ◽  
Breath Figure Method ◽  
End Group

The polystyrene with end group of Br was synthesized by using MBrP as the initiator, CuBr/ PMDETA as the catalyst system according to atom transfer radical polymerization (ATRP). The effect of reaction temperature was studied and the system was confirmed as the active polymerization. Then PS-Br and CuBr/ PMDETA were respectively used as macroinitiator and catalyst to polymerize tBMA according to atom transfer radical polymerization (ATRP). The structure of the product was characterized by GPCFTIR1H-NMR. The amphiphilic block copolymer was obtained after hydrolysis. And the honeycomb porous film was prepared by PS-b-PMAA through using breath figure method.

Synthesis of Novel Amphiphilic Block Copolymers of Poly-N-vinylpyrrolidone and Poly (D, L-lactide) by Atom Transfer Radical Polymerization

2006 ◽  
Vol 11-12 ◽  
pp. 461-464 ◽  
Author(s):  
Shu Xian Shi ◽  
Jian Liu ◽  
Yu Zheng Xia ◽  
Shu Ke Jiao ◽  
Xiao Yu Li
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Triblock Copolymers ◽  
Analytical Techniques ◽  
Catalyst System ◽  
Amphiphilic Polymer ◽  
Amphiphilic Block Copolymers ◽  
Atom Transfer ◽  
Polymer Micelle ◽  
Core Shell Structure

In order to improve the hydrophilicity of poly (D,L-latide) (PDLLA), a novel amphiphilic ABA-type triblock copolymers of poly-N-vinylpyrrolidone (A) and poly (D, L-lactide) (B), were successfully synthesized by atom transfer radical polymerization (ATRP) using N-vinylpyrrolidone (VP) as monomer, bromide-terminated poly (D,L-latide) oligomer (Br-PDLLA-Br) as functional macromolecular initiator which was prepared when hydroxy-terminated poly(D,L-latide) oligomer (HO-PDLLA-OH) reacted with 2-bromopropanoyl bromide, CuBr/2,2’-bipyridine complex as the catalyst system. The resulting copolymers were characterized by various analytical techniques. The results showed that the introduction of poly (N-vinylpyrrolidone) (PVP) segments into polylactide enhanced the surface hydrophilicity of the copolymers remarkably and amphiphilic polymer can self-assemble into core-shell structure (polymer micelle) in water by the balance of the hydrophilic and hydrophobic interaction.

Atom transfer radical polymerization of styrene initiated by the novel initiator 2-bromo-2-nitropropane

e-Polymers ◽  
2005 ◽  
Vol 5 (1) ◽  
Author(s):  
Gang Wang ◽  
Xiulin Zhu ◽  
Cheng Zhengping ◽  
Jian Zhu
Keyword(s):  
Molecular Weight ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Average Molecular Weight ◽  
Monomer Conversion ◽  
Catalyst System ◽  
Chain Extension ◽  
Atom Transfer ◽  
The Novel ◽  
H Nmr

AbstractHeterogeneous atom transfer radical polymerization (ATRP) of styrene initiated by 2-bromo-2-nitropropane in bulk was carried out with CuCl/2,2′-bipyridine as the catalyst. The kinetics was first order in monomer and the numberaverage molecular weight of the polymer increased linearly with monomer conversion, indicating the ‘living’/controlled nature of the polymerization. However, the number-average molecular weight was usually higher than the theoretical one. The nitro group might react with the Cu complex, resulting in insufficient initiation. The amount of catalyst has no effect on the controllability of this catalyst system for the ATRP of styrene. The presence of a halide end group in the obtained polymer was confirmed by both 1H NMR and chain-extension reaction.

Addressing the role of triphenylphosphine in copper catalyzed ATRP

2018 ◽  
Vol 9 (44) ◽  
pp. 5348-5358 ◽  
Author(s):  
João R. C. Costa ◽  
Joana R. Góis ◽  
Francesco De Bon ◽  
Arménio C. Serra ◽  
Tamaz Guliashvili ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Catalyst System ◽  
Atom Transfer

A new Atom Transfer Radical Polymerization (ATRP) process with triphenylphosphine (PPh3) and [CuIIMe6TREN]2+ as the catalyst system is reported.

A Route to Modify Polymeric Pigment Dispersants with Polysiloxanes by Atom Transfer Radical Polymerization

2012 ◽  
Vol 441 ◽  
pp. 478-483 ◽  
Author(s):  
Chuan Xia Huang ◽  
Ling Min Yi ◽  
Hao Yu Yuan ◽  
Chang Qin Chen
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Butyl Acrylate ◽  
Allyl Alcohol ◽  
Graft Copolymers ◽  
Catalyst System ◽  
Side Chains ◽  
Atom Transfer ◽  
Novel Approach ◽  
Dispersing Agents

A novel approach to modify polymeric pigment dispersants with polysiloxanes was developed based on the sequential atom transfer radical polymerization (ATRP) of styrene (St) and tert-butyl acrylate (tBA), using multifunctional α-bromoisobutyryl-containing poly (dimethylsiloxane) (PDMS-Brm) as the macroinitiators and CuBr/N,N,N,N,N- pentamethyldiethylenetriamine (PMDETA) as the catalyst system. The PDMS-Brm macroinitiators were obtained from the sequential hydrosilylation of commercially available methyl polysiloxanes containing SiH groups with allyl alcohol and then α-bromoisobutyryl bromide. And then, a series of well-defined comb-like graft copolymers with a PDMS backbone and several polystyrene-block-poly (tert-butyl acrylate) (PS-b-PtBA) side-chains were synthesized via ATRP. After hydrolyzing the tert-butyl groups, the comb-like copolymers may serve as multifunctional dispersing agents in the pigment printing.

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