Synthesis and Properties of a Novel Through-Space Conjugated Polymer with [2.2]Paracyclophane and Ferrocene in the Main Chain

2003 ◽  
Vol 36 (25) ◽  
pp. 9319-9324 ◽  
Author(s):  
Yasuhiro Morisaki ◽  
Yoshiki Chujo
Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2425
Author(s):  
Jiuchao Dong ◽  
Shigeki Nimori ◽  
Hiromasa Goto

A new method for fabricating conjugated polymer films was developed using electrochemical polymerization in liquid crystals and magnetic orientation. A uniaxial main chain orientation and a crosslinked network structure were achieved with this method. By employing eight types of monomers, the influence of the crosslinking for the film was investigated. The crosslinking was found to improve the solvent resistance of the conjugated polymer films. This new method is expected to be useful in various applications, such as high-powered organic electronic devices with durability.


2011 ◽  
Vol 49 (16) ◽  
pp. 3550-3558 ◽  
Author(s):  
Kenjiro Onimura ◽  
Mieko Matsushima ◽  
Munetoshi Nakamura ◽  
Tatsuya Tominaga ◽  
Kazuhiro Yamabuki ◽  
...  

1995 ◽  
Vol 413 ◽  
Author(s):  
Qiao-Sheng Hu ◽  
Dilrukshi Vitharana ◽  
Lin Pu

ABSTRACTThe synthesis and characterization of a 1,1′-binaphthyl based main chain chiral conjugated polymer, R-9, is described. The polymer is prepared from the palladium-catalyzed Suzuki coupling of an optically active binaphthyl molecule, (R)-2,2′-dihexyloxy-1,1′-binaphthyl-6,6′- diboronic acid, R-4 with 1,4-bis(p-bromostyryl)benzene (E:Z = 1:1.2), 8. The Suzuki coupling of 8 with 6-neopentyloxynaphthyl-2-boronic acid, 1 1, leads to the formation of a conjugated molecule 10. The structure of this molecule represents the repeat unit of R-9. The electronic absorption spectrum of 10 demonstrates that the degree of conjugation in the chiral conjugated polymer is almost the same as that of its repeat unit.


2009 ◽  
Vol 66 (6) ◽  
pp. 238-241
Author(s):  
Takuya ISHIDA ◽  
Ryutaro FURUKAWA ◽  
Arata ISHIKAWA ◽  
Hiroaki KOUZAI

2003 ◽  
Vol 89 (10) ◽  
pp. 2618-2623 ◽  
Author(s):  
Su-Yang Zhang ◽  
Fan Kong ◽  
Rong Sun ◽  
Ren-Kuan Yuan ◽  
Xi-Qun Jiang ◽  
...  

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