Morphology of Alternating Poly(ester amide)s Based on 1,4-Butylene Established by13C Solid-State NMR Relaxation Measurements

2002 ◽  
Vol 35 (21) ◽  
pp. 8013-8019 ◽  
Author(s):  
Peter J. M. Serrano ◽  
John P. M. van Duynhoven ◽  
Reinoud J. Gaymans ◽  
Ron Hulst
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Nmr Relaxation ◽  
Relaxation Measurements

scholarly journals Unraveling the complexity of protein backbone dynamics with combined 13C and 15N solid-state NMR relaxation measurements

2015 ◽  
Vol 17 (34) ◽  
pp. 21997-22008 ◽  
Author(s):  
Jonathan M. Lamley ◽  
Matthew J. Lougher ◽  
Hans Juergen Sass ◽  
Marco Rogowski ◽  
Stephan Grzesiek ◽  
...  
Keyword(s):  
Solid State ◽  
Magnetic Fields ◽  
Solid State Nmr ◽  
Nmr Relaxation ◽  
Backbone Dynamics ◽  
Relaxation Rates ◽  
Protein Backbone ◽  
Combined Analysis ◽  
Protein Backbone Dynamics ◽  
Relaxation Measurements

Combined analysis of 13C′ and 15N R1 and R1ρ relaxation rates measured at two magnetic fields leads to improved modeling of backbone dynamics in crystalline protein and provides unique insights into how the same motions contribute differently to relaxation rates in solution and solid state.

Study of Polyethylene by Solid State NMR Relaxation and Spin Diffusion

1997 ◽  
Vol 30 (8) ◽  
pp. 2474-2481 ◽  
Author(s):  
R. R. Eckman ◽  
P. M. Henrichs ◽  
A. J. Peacock
Keyword(s):  
Solid State ◽  
Solid State Nmr ◽  
Spin Diffusion ◽  
Nmr Relaxation

scholarly journals High-Resolution Structural Insights into Bone: A Solid-State NMR Relaxation Study Utilizing Paramagnetic Doping

2012 ◽  
Vol 116 (38) ◽  
pp. 11656-11661 ◽  
Author(s):  
Kamal H. Mroue ◽  
Neil MacKinnon ◽  
Jiadi Xu ◽  
Peizhi Zhu ◽  
Erin McNerny ◽  
...  
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Solid State Nmr ◽  
Nmr Relaxation ◽  
Relaxation Study ◽  
Structural Insights

scholarly journals Characterization of water in hydrated Bombyx mori silk fibroin fiber and films by 2H NMR relaxation and 13C solid state NMR

2017 ◽  
Vol 50 ◽  
pp. 322-333 ◽  
Author(s):  
Tetsuo Asakura ◽  
Kotaro Isobe ◽  
Shunsuke Kametani ◽  
Obehi T. Ukpebor ◽  
Moshe C. Silverstein ◽  
...  
Keyword(s):  
Solid State ◽  
Bombyx Mori ◽  
Silk Fibroin ◽  
Solid State Nmr ◽  
Nmr Relaxation ◽  
2H Nmr ◽  
Silk Fibroin Fiber ◽  
Bombyx Mori Silk

Investigation of Methyl Reorientations in 1,4-Dimethoxy- 2,6-dimethylbenzene by NMR and Inelastic Neutron Scattering

1979 ◽  
Vol 34 (5) ◽  
pp. 631-645 ◽  
Author(s):  
R. A. Wind ◽  
W. M. M. J. Bovée ◽  
J. C. F. Kupers ◽  
J. Smidt ◽  
Chr. Steenbergen
Keyword(s):  
Solid State ◽  
Neutron Scattering ◽  
Liquid State ◽  
Solid State Nmr ◽  
Inelastic Neutron Scattering ◽  
Nmr Relaxation ◽  
Inelastic Neutron ◽  
Methyl Groups ◽  
Methyl Group ◽  
Nmr Study

Abstract In this paper a solid state NMR relaxation study and inelastic neutron scattering (INS) experiments (the latter in the solid and liquid phase) are reported for a molecule containing methyl groups in different surroundings, namely 1,4-dimethoxy-2,6-dimethylbenzene. The results are compared with each other and with those of a liquid state NMR study reported earlier. It is found that in this way both the shapes and magnitudes of the various hindering potentials can be determined. The result is that the methyl groups 1, 2 and 4 possess a threefold cosine-shaped potential with heights given by 7.7, 9.0 and 15.0 kJ/mol according to the solid state NMR measurements (from the INS study the values 7.5, 7.5 and 16.0 kJ/mol were obtained). For methyl group 6 a mixture of a three-and six-fold symmetry had to be taken into account in order to explain the experiments. Except for methyl group 4 the liquid state NMR results deviate from those obtained with the other two techniques. A possible cause for this discrepancy is discussed. For the molecular structure it is concluded that the reorientations of the methyl groups 1 and 2 are influenced by mutual hindering and that the angle between the plane through the C4-O-C bond and the aromatic plane is small, whereas for the C1-O-C bond this angle is estimated to be about 70°.

Sign in / Sign up

Export Citation Format

Share Document