Static light scattering from aqueous poly(ethylene oxide) solutions in the temperature range 20-90°C

1983 ◽  
Vol 16 (6) ◽  
pp. 978-982 ◽  
Author(s):  
William F. Polik ◽  
Walther Burchard
Polymer ◽  
1997 ◽  
Vol 38 (12) ◽  
pp. 2885-2891 ◽  
Author(s):  
Seigou Kawaguchi ◽  
Genji Imai ◽  
Junto Suzuki ◽  
Akira Miyahara ◽  
Toshiaki Kitano ◽  
...  

Author(s):  
Shinichi Kinugasa ◽  
Hisae Nakahara ◽  
Jun-Ichi Kawahara ◽  
Yoshinori Koga ◽  
Haruo Takaya

Polymers ◽  
2019 ◽  
Vol 11 (12) ◽  
pp. 2013 ◽  
Author(s):  
Martin Fauquignon ◽  
Emmanuel Ibarboure ◽  
Stéphane Carlotti ◽  
Annie Brûlet ◽  
Marc Schmutz ◽  
...  

In the emerging field of hybrid polymer/lipid vesicles, relatively few copolymers have been evaluated regarding their ability to form these structures and the resulting membrane properties have been scarcely studied. Here, we present the synthesis and self-assembly in solution of poly(dimethylsiloxane)-block-poly(ethylene oxide) diblock copolymers (PDMS-b-PEO). A library of different PDMS-b-PEO diblock copolymers was synthesized using ring-opening polymerization of hexamethylcyclotrisiloxane (D3) and further coupling with PEO chains via click chemistry. Self-assembly of the copolymers in water was studied using Dynamic Light Scattering (DLS), Static Light Scattering (SLS), Small Angle Neutron Scattering (SANS), and Cryo-Transmission Electron Microscopy (Cryo-TEM). Giant polymersomes obtained by electroformation present high toughness compared to those obtained from triblock copolymer in previous studies, for similar membrane thickness. Interestingly, these copolymers can be associated to phospholipids to form Giant Hybrid Unilamellar Vesicles (GHUV); preliminary investigations of their mechanical properties show that tough hybrid vesicles can be obtained.


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