General analysis of the measurement of the crystal lattice modulus of semicrystalline polymers by x-ray diffraction

1990 ◽  
Vol 23 (13) ◽  
pp. 3261-3266 ◽  
Author(s):  
Masaru Matsuo
Keyword(s):  
Crystal Lattice ◽  
Semicrystalline Polymers ◽  
General Analysis ◽  
X Ray Diffraction ◽  
X Ray ◽  
Lattice Modulus

Evaluating the high-pressure structural response and crystal lattice interactions of the magnetically-bistable organic radical TTTA

CrystEngComm ◽  
2021 ◽  
Author(s):  
Jonathan Richardson ◽  
Asato Mizuno ◽  
Yoshiaki Shuku ◽  
Kunio Awaga ◽  
Neil Robertson ◽  
...  
Keyword(s):  
High Pressure ◽  
Crystal Lattice ◽  
Structural Response ◽  
Pressure Response ◽  
Organic Radical ◽  
X Ray Diffraction ◽  
X Ray

Magnetic bistability has previously been observed and evaluated in an organic thiazyl radical 1,3,5 triathia 2,4,6-triazapentalenyl (TTTA). Herein, the structure-pressure response of TTTA has been evaluated by X-ray diffraction, where...

scholarly journals Magnetically Oriented Powder Crystal to Indexing and Structure Determination

2014 ◽  
Vol 70 (a1) ◽  
pp. C1560-C1560
Author(s):  
Fumiko Kimura ◽  
Wataru Oshima ◽  
Hiroko Matsumoto ◽  
Hidehiro Uekusa ◽  
Kazuaki Aburaya ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Single Crystal ◽  
Crystal Lattice ◽  
Powder Diffraction ◽  
Diffraction Method ◽  
Lattice Parameters ◽  
X Ray Diffraction ◽  
X Ray ◽  
Crystal Lattice Parameters

In pharmaceutical sciences, the crystal structure is of primary importance because it influences drug efficacy. Due to difficulties of growing a large single crystal suitable for the single crystal X-ray diffraction analysis, powder diffraction method is widely used. In powder method, two-dimensional diffraction information is projected onto one dimension, which impairs the accuracy of the resulting crystal structure. To overcome this problem, we recently proposed a novel method of fabricating a magnetically oriented microcrystal array (MOMA), a composite in which microcrystals are aligned three-dimensionally in a polymer matrix. The X-ray diffraction of the MOMA is equivalent to that of the corresponding large single crystal, enabling the determination of the crystal lattice parameters and crystal structure of the embedded microcrytals.[1-3] Because we make use of the diamagnetic anisotropy of crystal, those crystals that exhibit small magnetic anisotropy do not take sufficient three-dimensional alignment. However, even for these crystals that only align uniaxially, the determination of the crystal lattice parameters can be easily made compared with the determination by powder diffraction pattern. Once these parameters are determined, crystal structure can be determined by X-ray powder diffraction method. In this paper, we demonstrate possibility of the MOMA method to assist the structure analysis through X-ray powder and single crystal diffraction methods. We applied the MOMA method to various microcrystalline powders including L-alanine, 1,3,5-triphenyl benzene, and cellobiose. The obtained MOMAs exhibited well-resolved diffraction spots, and we succeeded in determination of the crystal lattice parameters and crystal structure analysis.

(Tnmethylphosphine)(triphenylsilyl)gold(I) and Related Compounds

1999 ◽  
Vol 54 (1) ◽  
pp. 26-29 ◽  
Author(s):  
Miguel Monge Oroz ◽  
Annette Schier ◽  
Hubert Schmidbaur
Keyword(s):  
Crystal Structure ◽  
Crystal Lattice ◽  
Coordination Compounds ◽  
Ionic Species ◽  
X Ray Diffraction ◽  
X Ray ◽  
Halide Complexes ◽  
Related Compounds ◽  
Heteroleptic Complex

Mononuclear coordination compounds of the type (R3P)AuSiR′3 with R = R’ = Ph and R = Me, R′ = Ph have been obtained from reactions of the corresponding halide complexes (R3P)AuCl with the silyllithium reagent LiSiPh3. The fully phenylated species undergoes ligand redistribution in solution to give homoleptic ionic species. (Me3P)AuSiPh3 is less susceptible to this process and crystallizes from solutions as the heteroleptic complex. The crystal structure of this compound has been determined by X-ray diffraction. In the crystal lattice the molecules are not associated.

Direct X-Ray Measurement of Residual Strains in Textured Steel

1983 ◽  
Vol 27 ◽  
pp. 197-206
Author(s):  
C. P. Gazzara
Keyword(s):  
Residual Stress ◽  
Crystal Lattice ◽  
Elastic Constants ◽  
Random Distribution ◽  
Elastic Anisotropy ◽  
X Ray Diffraction ◽  
X Ray ◽  
Residual Strains ◽  
Residual Stress Analysis ◽  
Textured Materials

One of the most detrimental effects on the accuracy of an X-ray diffraction residual stress analysis, XRDRSA(l), is found in the examination of textured materials. The degree of elastic anisotropy and texture is in general agreement with the extent of the error in the residual stress. Several approaches have been made to correct for the effects of texture, particularly involving experimental techniques. Reviews of such efforts are given by H. D811e(2), v.M. Hauk﹛3) and G. Maeder, J.L. Lebrun and J.M. Sprauel (4), just to mention a few.A brief chronology of the texture corrections involved in XRDRSA follows. With isotropic materials the d spacing of a crystal lattice, d, is assumed to vary linearly with sin2ψ. With textured materials the d vs sin2ψ relationship is nonlinear. This is due to the anisotropy of the elastic constants and their departure from a random distribution, or taking on a preferred orientation.

The crystal structure of visible light absorbing piezoelectric semiconductor SrNb2V2O11 revisited: high-resolution X-ray diffraction, vibrational spectroscopy and computational study

2019 ◽  
Vol 7 (18) ◽  
pp. 5497-5505
Author(s):  
Ievgen V. Odynets ◽  
Sergiy Khainakov ◽  
Santiago Garcia-Granda ◽  
Roman Gumeniuk ◽  
Matthias Zschornak ◽  
...  
Keyword(s):  
Crystal Structure ◽  
High Resolution ◽  
Visible Light ◽  
Crystal Lattice ◽  
Vibrational Spectroscopy ◽  
Computational Study ◽  
X Ray Diffraction ◽  
Piezoelectric Semiconductor ◽  
X Ray

The crystal lattice of piezoelectric semiconductor Sr2Nb2V2O11 adopts Cc ordering due to Γ2− mode distortion.

scholarly journals Rotation of fullerene molecules in the crystal lattice of fullerene/porphyrin: C60 and Sc3N@C80

2021 ◽  
Vol 8 (1) ◽  
pp. 122-126
Author(s):  
Yajuan Hao ◽  
Yaofeng Wang ◽  
Lukas Spree ◽  
Fupin Liu
Keyword(s):  
Crystal Lattice ◽  
Variable Temperature ◽  
Fullerene Cage ◽  
X Ray Diffraction ◽  
X Ray

The temperature driven rotation of the encapsulated Sc3N cluster in a C80 fullerene cage was unraveled by variable temperature X-ray diffraction, which is significantly different from its analogues (Ho2LuN/Lu3N).

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