Microstructure and isotopic labeling effects on the miscibility of polybutadiene blends studied by the small-angle neutron scattering technique

1990 ◽  
Vol 23 (2) ◽  
pp. 451-459 ◽  
Author(s):  
Shinichi Sakurai ◽  
Hirokazu Hasegawa ◽  
Takeji Hashimoto ◽  
I. Glen Hargis ◽  
S. L. Aggarwal ◽  
...  
1989 ◽  
Vol 166 ◽  
Author(s):  
Charles C. Han ◽  
Hirokazu Hasegawa ◽  
Takeji Hashimoto ◽  
I. Glen Hargis ◽  
S. L. Aggarwal

ABSTRACTDeuterated polybutadiene and protonated polybutadiene (PBD/PBH) blends with various microstructures have been studied by the small-angle neutron scattering experiments. Correlation length, ξ, zero-wavenumber structure factor, S(q=o), and interaction parameter, Xblend have been obtained. All PBD/PBH blends exhibit UCST behavior. With the use of random copolymer theory, the interaction parameter, Xblend, has been successfully separated into X1, X2 and X3 which are interaction parameters between the same isotope labeled 1,2-unit and 1,4-unit, opposite isotope labeled 1,2-unit and 1,4- unit, and opposite isotope labeled 1,2-unit with 1,2-unit or 1,4-unit with 1,4-unit, respectively.


2000 ◽  
Vol 33 (3) ◽  
pp. 847-850 ◽  
Author(s):  
K. Aizawa ◽  
H. Tomimitsu ◽  
H. Tamaki ◽  
A. Yoshinari

2018 ◽  
Vol 59 (s2) ◽  
pp. E65-E70 ◽  
Author(s):  
Tae Hui Kang ◽  
Brett G. Compton ◽  
William T. Heller ◽  
Shuo Qian ◽  
Gregory S. Smith ◽  
...  

2018 ◽  
Vol 18 (6) ◽  
pp. 1800018 ◽  
Author(s):  
Baohu Wu ◽  
Maria Siglreitmeier ◽  
Christian Debus ◽  
Dietmar Schwahn ◽  
Helmut Cölfen ◽  
...  

2007 ◽  
Vol 136 (1-2) ◽  
pp. 147-155 ◽  
Author(s):  
Toshiyuki Takamuku ◽  
Yasukuni Noguchi ◽  
Masaru Matsugami ◽  
Hiroki Iwase ◽  
Toshiya Otomo ◽  
...  

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