Dielectric relaxation studies of ion motions in electrolyte-containing perfluorosulfonate ionomers. 4. Long-range ion transport

1989 ◽  
Vol 22 (12) ◽  
pp. 4483-4488 ◽  
Author(s):  
Kenneth A. Mauritz
2015 ◽  
Vol 8 (3) ◽  
pp. 2176-2188 ◽  
Author(s):  
Keisham Nanao Singh

This article reports on the Dielectric Relaxation Studies of two Liquid Crystalline compounds - 7O.4 and 7O.6 - doped with dodecanethiol capped Silver Nanoparticles. The liquid crystal molecules are aligned homeotropically using CTAB. The low frequency relaxation process occurring above 1 MHz is fitted to Cole-Cole formula using the software Dielectric Spectra fit. The effect of the Silver Nanoparticles on the molecular dipole dynamics are discussed in terms of the fitted relaxation times, Cole-Cole distribution parameter and activation energy. The study indicate a local molecular rearrangement of the liquid crystal molecules without affecting the order of the bulk liquid crystal molecules but these local molecules surrounding the Silver Nanoparticles do not contribute to the relaxation process in the studied frequency range. The observed effect on activation energy suggests a change in interaction between the nanoparticles/liquid crystal molecules.


Nature ◽  
1970 ◽  
Vol 228 (5270) ◽  
pp. 456-457 ◽  
Author(s):  
A. SUGGETT ◽  
P. A. MACKNESS ◽  
M. J. TAIT ◽  
H. W. LOEB ◽  
G. M. YOUNG

2010 ◽  
Vol 12 (7) ◽  
pp. 1231-1234 ◽  
Author(s):  
A.K. Himanshu ◽  
B.K. Choudhary ◽  
S.N. Singh ◽  
D.C. Gupta ◽  
S.K. Bandyopadhayay ◽  
...  

2020 ◽  
Vol 11 (2) ◽  
pp. 461-471 ◽  
Author(s):  
Jiacheng Liu ◽  
Phillip D. Pickett ◽  
Bumjun Park ◽  
Sunil P. Upadhyay ◽  
Sara V. Orski ◽  
...  

Non-solvating, side-chain polymer electrolytes with more dissociable pendent anion chemistries exhibit a dielectric relaxation dominated lithium ion transport mechanism.


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