On the chain length dependence of the dynamics of coil expansion of poly(methacrylic acid)

1986 ◽  
Vol 19 (11) ◽  
pp. 2846-2850 ◽  
Author(s):  
Masahiro Irie ◽  
Wolfram Schnabel
1995 ◽  
Vol 152 (1) ◽  
pp. 137-146 ◽  
Author(s):  
E.W. Kuipers ◽  
I.H. Vinkenburg ◽  
H. Oosterbeek

2002 ◽  
Vol 55 (7) ◽  
pp. 399 ◽  
Author(s):  
G. T. Russell

Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed.


Physica B+C ◽  
1979 ◽  
Vol 96 (3) ◽  
pp. 385-390
Author(s):  
F.A. Gianturco ◽  
E. Semprini ◽  
F. Stefani

2014 ◽  
Vol 7 (1) ◽  
pp. 351-358 ◽  
Author(s):  
Jang Yeol Back ◽  
Tae Kyu An ◽  
Ye Rim Cheon ◽  
Hyojung Cha ◽  
Jaeyoung Jang ◽  
...  

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