Changes of liquid crystalline polymer structure with temperature. 6. Distortion of one-dimensional order in smectic B polymer

1986 ◽  
Vol 19 (5) ◽  
pp. 1308-1317 ◽  
Author(s):  
V. Tsukruk ◽  
V. Shilov ◽  
Yu. Lipatov
Keyword(s):  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Polymer Structure ◽  
One Dimensional

Morphology of Polyamideliquid Crystalline Polymer Blend

1990 ◽  
Vol 215 ◽  
Author(s):  
K. Nishii ◽  
M. Usui ◽  
T. Muraya ◽  
K. Kimura
Keyword(s):  
Mechanical Properties ◽  
Mechanical Strength ◽  
Polymer Blend ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Polymer Structure ◽  
High Mechanical Strength ◽  
Blend Morphology ◽  
The Relationship

Polymer blend technology is attractive from the standpoint of both science and industry, and many combinations have been studied. Recently, the polymer blends, including liquid crystalline polymer, have been especially worthy of notice, [1,2,3]. In order to obtain materials with a high mechanical strength and moldability for use in thin molded items, we chose polyamide (PA)-liquid crystalline polymer (LCP) blends. In this study, we first measured the mechanical properties, then studied the features of the polymer structure. We also examined the relationship between morphology and mechanical properties. As a result, we found that the mechanical properties of the blends depended largely on blend morphology, and that mechanical strength increased as blend compatibility increased. On the other hand, we also found that the blends showed compatible and microheterogeneous dispersion at less than 25 wt% LCP, while at more than 30 wt% LCP, blends tended to show twophase separation.

scholarly journals One dimensional isothermal spinning models for liquid crystalline polymer fibers

1997 ◽  
Vol 41 (4) ◽  
pp. 821-850 ◽  
Author(s):  
M. Gregory Forest ◽  
Qi Wang ◽  
Stephen E. Bechtel
Keyword(s):  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Polymer Fibers ◽  
One Dimensional

Changes of liquid-crystalline polymer structure with temperature

1984 ◽  
Vol 11 (6) ◽  
pp. 561-564 ◽  
Author(s):  
Vladimir Tsukruk ◽  
Valery Shilov ◽  
Oksana Lokhonya ◽  
Yury Lipatov
Keyword(s):  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Polymer Structure

Observing the relaxation of molecular orientation in sheared liquid crystalline polymer solutions

1990 ◽  
Vol 48 (4) ◽  
pp. 1092-1093
Author(s):  
Wendy Putnam ◽  
Christopher Viney
Keyword(s):  
Molecular Orientation ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Polymer Processing ◽  
Molecular Alignment ◽  
Global Alignment ◽  
Shear Direction ◽  
Axial Strength ◽  
Strength And Stiffness

Liquid crystalline polymers (solutions or melts) can be spun into fibers and films that have a higher axial strength and stiffness than conventionally processed polymers. These superior properties are due to the spontaneous molecular extension and alignment that is characteristic of liquid crystalline phases. Much of the effort in processing conventional polymers goes into extending and aligning the chains, while, in liquid crystalline polymer processing, the primary microstructural rearrangement involves converting local molecular alignment into global molecular alignment. Unfortunately, the global alignment introduced by processing relaxes quickly upon cessation of shear, and the molecular orientation develops a periodic misalignment relative to the shear direction. The axial strength and stiffness are reduced by this relaxation.Clearly there is a need to solidify the liquid crystalline state (i.e. remove heat or solvent) before significant relaxation occurs. Several researchers have observed this relaxation, mainly in solutions of hydroxypropyl cellulose (HPC) because they are lyotropic under ambient conditions.

Phase Separation in Liquid-Crystalline Copolymer/Poly(methyl methacrylate) Blends

1995 ◽  
Vol 60 (11) ◽  
pp. 1869-1874 ◽  
Author(s):  
Anatoly E. Nesterov ◽  
Yuri S. Lipatov ◽  
Vitaly V. Horichko
Keyword(s):  
Phase Separation ◽  
Methyl Methacrylate ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Ethylene Terephthalate ◽  
Crystalline Polymer ◽  
Scattering Method ◽  
Thermally Induced ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly

The phase separation in the blends of poly(methyl methacrylate) and liquid-crystalline polymer (copolymer of ethylene terephthalate and p-hydroxybenzoic acid) has been studied by the light scattering method and the cloud point curves have been obtained. Simultaneously some morphological features of the blends have been observed. It was found that the initial blends are in the state of forced compatibility and that thermally induced phase separation occurs by the mechanism of spinodal decomposition but presumably in the non-linear regime.

scholarly journals Fiber Formation and Structural Development of HBA/HNA Thermotropic Liquid Crystalline Polymer in High-Speed Melt Spinning

Polymers ◽  
2021 ◽  
Vol 13 (7) ◽  
pp. 1134
Author(s):  
Bo Seok Song ◽  
Jun Young Lee ◽  
Sun Hwa Jang ◽  
Wan-Gyu Hahm
Keyword(s):  
Mechanical Properties ◽  
Shear Rate ◽  
High Speed ◽  
Melt Spinning ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer ◽  
Fiber Formation ◽  
Structural Development ◽  
Thermotropic Liquid Crystalline Polymer

High-speed melt spinning of thermotropic liquid crystalline polymer (TLCP) resin composed of 4-hydroxybenzoic acid (HBA) and 2-hydroxy-6-napthoic acid (HNA) monomers in a molar ratio of 73/27 was conducted to investigate the characteristic structure development of the fibers under industrial spinning conditions, and the obtained as-spun TLCP fibers were analyzed in detail. The tensile strength and modulus of the fibers increased with shear rate in nozzle hole, draft in spin-line and spinning temperature and exhibited the high values of approximately 1.1 and 63 GPa, respectively, comparable to those of industrial as-spun TLCP fibers, at a shear rate of 70,000 s−1 and a draft of 25. X-ray diffraction demonstrated that the mechanical properties of the fibers increased with the crystalline orientation factor (fc) and the fractions of highly oriented crystalline and non-crystalline anisotropic phases. The results of structure analysis indicated that a characteristic skin–core structure developed at high drafts (i.e., spinning velocity) and low spinning temperatures, which contributed to weakening the mechanical properties of the TLCP fibers. It is supposed that this heterogeneous structure in the cross-section of the fibers was induced by differences in the cooling rates of the skin and core of the fiber in the spin-line.

In situ compatibilized polypropylene/liquid crystalline polymer blends

Polymer ◽  
1996 ◽  
Vol 37 (18) ◽  
pp. 4099-4106 ◽  
Author(s):  
Yei-Po Chiou ◽  
Kuo-Chan Chiou ◽  
Feng-Chih Chang
Keyword(s):  
Polymer Blends ◽  
Liquid Crystalline Polymer ◽  
Liquid Crystalline ◽  
Crystalline Polymer
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