Characterization of Highly Branched Poly(methyl methacrylate) by Solution Viscosity and Viscoelastic Spectroscopy

2001 ◽  
Vol 34 (6) ◽  
pp. 1677-1684 ◽  
Author(s):  
Peter F. W. Simon ◽  
Axel H. E. Müller ◽  
Tadeusz Pakula
Keyword(s):  
Methyl Methacrylate ◽  
Solution Viscosity ◽  
Poly Methyl Methacrylate

Detailed study on the characterization of silver nanocluster in poly(methyl methacrylate)

1997 ◽  
Vol 501 ◽  
Author(s):  
Naohisa Yanagihara ◽  
Kazutaka Uchida ◽  
Muyuki Wakabayashi ◽  
Toru Hara
Keyword(s):  
Heat Treatment ◽  
Methyl Methacrylate ◽  
Treatment Duration ◽  
Bulk Polymerization ◽  
Visible Spectroscopy ◽  
Poly Methyl Methacrylate ◽  
Silver Nanocluster ◽  
Ag Cluster ◽  
Heat Treatment Duration

ABSTRACTSolid sol of silver in poly(methyl methacrylate), Ag/PMMA, was prepared by bulk polymerization of methyl methacrylate solution of silver (I) triflluoroacetate (AgTfa) and followed by postheating. The formation of the metallic Ag nanocluster was characterized by visible spectroscopy, and effects of the concentrations of AIBN and AgTfa and the heat-treatment duration on the formation of Ag cluster were investigated. Furthermore, based on the kinetic study of MMA in the presence of AgTfa, possible mechanism for the reduction and agglomeration of silver is proposed.

Thermal and mechanical characterization of poly(methyl methacrylate) nanocomposites filled with TiO2 nanorods

2012 ◽  
Vol 43 (8) ◽  
pp. 3114-3119 ◽  
Author(s):  
Niranjan Patra ◽  
Marco Salerno ◽  
P. Davide Cozzoli ◽  
Alberto C. Barone ◽  
Luca Ceseracciu ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Mechanical Characterization ◽  
Tio2 Nanorods ◽  
Poly Methyl Methacrylate

PROTON MAGNETIC RESONANCE LINE WIDTH AS A FUNCTION OF POLYMER TACTICITY

1966 ◽  
Vol 44 (2) ◽  
pp. 153-156 ◽  
Author(s):  
S. Brownstein ◽  
D. M. Wiles
Keyword(s):  
Magnetic Resonance ◽  
Methyl Methacrylate ◽  
Proton Magnetic Resonance ◽  
Chloroform Solution ◽  
Spin Coupling ◽  
Solution Viscosity ◽  
Dilute Solution ◽  
Poly Methyl Methacrylate ◽  
Resonance Line Width ◽  
Polymer Tacticity

The high resolution proton magnetic resonance spectra of five samples of poly(methyl methacrylate) in chloroform solution have been measured with 100 Mc/s equipment. The widths of the absorption lines arising from the protons of the α-methyl and the methoxyl groups have been compared. The widths are greater when the polymer is predominantly syndiotactic than when it is predominantly isotactic. It is concluded that isotactic samples have the more extended conformation in chloroform solution. An analogy with dilute solution viscosity measurements is outlined in support of this conclusion. Differences between the widths of the lines of the methylene protons in a completely isotactic poly(methyl methacrylate) sample are attributed to long range spin coupling.

scholarly journals Characterization of Spirooxazine and Spiropyran Hosted in Poly(Methyl Methacrylate) for Germicidal UV Source Indicator Application

2013 ◽  
Vol 03 (07) ◽  
pp. 11-16 ◽  
Author(s):  
Julien Bonefacino ◽  
Ming-Leung Vincent Tse ◽  
Chi-Fung Jeff Pun ◽  
Xin Cheng ◽  
Wing Kin Edward Chan ◽  
...  
Keyword(s):  
Methyl Methacrylate ◽  
Poly Methyl Methacrylate
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