On the correlation between the negative intrinsic viscosity and the rotatory relaxation time of solvent molecules in dilute polymer solutions

1993 ◽  
Vol 26 (25) ◽  
pp. 6891-6896 ◽  
Author(s):  
Takenao Yoshizaki ◽  
Yoshio Takaeda ◽  
Hiromi Yamakawa
Keyword(s):  
Relaxation Time ◽  
Intrinsic Viscosity ◽  
Polymer Solutions ◽  
Dilute Polymer Solutions ◽  
Solvent Molecules

Surface-tension-driven breakup of viscoelastic liquid threads

1982 ◽  
Vol 120 ◽  
pp. 245-266 ◽  
Author(s):  
Simon L. Goren ◽  
Moshe Gottlieb
Keyword(s):  
Relaxation Time ◽  
Stress Relaxation ◽  
Polymer Solutions ◽  
Small Diameter ◽  
Shear Thinning ◽  
Prior History ◽  
Axial Tension ◽  
Dilute Polymer Solutions ◽  
Linearized Stability ◽  
Newtonian Liquids

A linearized stability analysis is carried out for the breakup of small-diameter liquid filaments of dilute polymer solutions into droplets. Oldroyd's 8-constant model expressed in a corotational reference frame is used as the rheological equation of state. The crucial idea in this theory is the recognition that the liquid may be subject to an unrelaxed axial tension due to its prior history. If the tension is zero, the present analysis predicts that jets of shear-thinning liquids are less stable than comparable jets of Newtonian liquids; this is in agreement with previous analyses. However, when the axial tension is not zero, and provided the stress relaxation time constant is sufficiently large, the new theory predicts that the axial elastic tension can be a significant stabilizing influence. With reasonable values for the tension and stress relaxation time the theory explains the great stability observed for jets of some shear- thinning, dilute polymer solutions. The theory explains why drops produced from jets of such liquids are larger than drops from corresponding Newtonian liquids. The theory also appears capable of explaining the sudden appearance of irregularly spaced bulges on jets after long distances of t,ravel with little amplification of disturbances.

scholarly journals Breakup Dynamics of Semi-dilute Polymer Solutions in a Microfluidic Flow-focusing Device

Micromachines ◽  
2020 ◽  
Vol 11 (4) ◽  
pp. 406
Author(s):  
Chun-Dong Xue ◽  
Xiao-Dong Chen ◽  
Yong-Jiang Li ◽  
Guo-Qing Hu ◽  
Tun Cao ◽  
...  
Keyword(s):  
Relaxation Time ◽  
Polymer Solutions ◽  
Newtonian Fluids ◽  
Droplet Microfluidics ◽  
Droplet Generation ◽  
Flow Focusing ◽  
Polymeric Fluids ◽  
Practical Applications ◽  
Dilute Polymer Solutions ◽  
Microfluidic Flow

Droplet microfluidics involving non-Newtonian fluids is of great importance in both fundamental mechanisms and practical applications. In the present study, breakup dynamics in droplet generation of semi-dilute polymer solutions in a microfluidic flow-focusing device were experimentally investigated. We found that the filament thinning experiences a transition from a flow-driven to a capillary-driven regime, analogous to that of purely elastic fluids, while the highly elevated viscosity and complex network structures in the semi-dilute polymer solutions induce the breakup stages with a smaller power-law exponent and extensional relaxation time. It is elucidated that the elevated viscosity of the semi-dilute solution decelerates filament thinning in the flow-driven regime and the incomplete stretch of polymer molecules results in the smaller extensional relaxation time in the capillary-driven regime. These results extend the understanding of breakup dynamics in droplet generation of non-Newtonian fluids and provide guidance for microfluidic synthesis applications involving dense polymeric fluids.

scholarly journals The laminar flow of dilute polymer solutions around circular cylinders

1970 ◽  
Vol 42 (2) ◽  
pp. 269-288 ◽  
Author(s):  
David F. James ◽  
Allan J. Acosta
Keyword(s):  
Heat Transfer ◽  
Relaxation Time ◽  
Polymer Solutions ◽  
Fluid Velocity ◽  
Maxwell Model ◽  
Circular Cylinders ◽  
Stream Velocity ◽  
Dimensionless Group ◽  
Number Range ◽  
Dilute Polymer Solutions

This paper describes the measurements of heat transfer and drag for the flow of dilute polymer solutions around very small cylinders. The thermal experiments were carried out at Reynolds numbers less than 50, and the results establish the dependence of the heat transfer on fluid velocity, cylinder diameter, solution concentration, and polymer molecular weight. The drag measurements were conducted with the same type of solutions and in the same Reynolds-number range. To complement the heat-transfer and drag measurements, the flows around a cylinder and through an orifice were examined visually. These flow-visualization studies showed that the streamline pattern with dilute polymer solutions can be significantly different from that with Newtonian fluids because of viscoelastic effects.An analysis of Rouse's theory of macromolecules shows that for low accelerations a dilute polymer solution behaves mechanically like a Maxwell model. The analysis thereby produces a relaxation time, a single parameter representing the elasticity of the fluid, which can be related to the properties of the solute and solvent. This relaxation time is contained in a new dimensionless group which governs dynamic similarity when induced elastic stresses dominate viscous stresses in the flow around a circular cylinder. The dimensionless group is shown to correlate the thermal data when the heat transfer does not depend on the free stream velocity.

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