Synthesis, characterization, glass transition behavior, and the electronic structure of high-molecular-weight, symmetrically substituted poly(ferrocenylsilanes) with alkyl or aryl side groups

1993 ◽  
Vol 26 (11) ◽  
pp. 2878-2884 ◽  
Author(s):  
Daniel A. Foucher ◽  
Ralf Ziembinski ◽  
Ben Zhong Tang ◽  
Peter M. Macdonald ◽  
Jason Massey ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Electronic Structure ◽  
Glass Transition ◽  
High Molecular Weight ◽  
Transition Behavior

Stereo-chemical contributions to the glass transition and liquid–liquid phase separation in high molecular weight poly(N-vinyl carbazole)

RSC Advances ◽  
2016 ◽  
Vol 6 (35) ◽  
pp. 29326-29333 ◽  
Author(s):  
Abdul G. Al Lafi ◽  
James N. Hay
Keyword(s):  
Molecular Weight ◽  
Glass Transition ◽  
Phase Separation ◽  
Liquid Phase ◽  
High Molecular Weight ◽  
Structural Properties ◽  
Thermal History ◽  
Liquid Phase Separation ◽  
High Molecular Weight Poly ◽  
Liquid Liquid Phase Separation

Thermal history and purification effects on the structural properties of PVK were investigated. Liquid–liquid phase separation is suggested to occur by separation of isotactic rich segments from a matrix which is predominantly atactic.

Polyamide 6 and high molecular weight phenol novolac blend having excellent mechanical properties in humid conditions

2018 ◽  
Vol 32 (6) ◽  
pp. 778-794 ◽  
Author(s):  
Takayuki Hirai ◽  
Kenzo Fukumori ◽  
Taiji Ikawa ◽  
Tetsuya Oda
Keyword(s):  
Mechanical Properties ◽  
Molecular Weight ◽  
Glass Transition ◽  
High Molecular Weight ◽  
Room Temperature ◽  
Glassy State ◽  
Physical And Mechanical Properties ◽  
Polyamide 6 ◽  
Low Molecular Weight ◽  
Melt Mixing

Polymer blends of polyamide 6 (PA6) and phenol novolac (PN) were prepared by melt mixing. Up to 30 wt% of high molecular weight PN (HPN) or low molecular weight PN (LPN) was blended with PA6, and the physical and mechanical properties were examined. The water absorption of PA6 is inhibited by PN, and this effect is independent of the molecular weight of PN. PA6 and PN are miscible, and their blends show a single glass transition temperature ( T g) that is higher than that of PA6. HPN can enhance the T g of PA6 more efficiently than LPN because of its high T g. PA6 and the PA6/LPN blend after immersion in water had lower-than-room-temperature T gs transitioning to rubbery states. In contrast, the PA6/HPN blend after immersion in water had a higher-than-room-temperature T g. The PA6/HPN blend in water has excellent mechanical properties in its glassy state compared to those of PA6 in the dry state. Thus, the PA6/HPN blend can be used to broaden the applications of PA6, especially in humid conditions.

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