Effects of Structural Fe Oxidation State on the Coupling of Interlayer Water and Structural Si−O Stretching Vibrations in Montmorillonite

Langmuir ◽  
1999 ◽  
Vol 15 (13) ◽  
pp. 4648-4657 ◽  
Author(s):  
Laibin Yan ◽  
Joseph W. Stucki
2015 ◽  
Author(s):  
E G Potter ◽  
R Sharpe ◽  
I Girard ◽  
M Fayek ◽  
P Gammon ◽  
...  

Author(s):  
V. C. Farmer

SummaryThe absorption spectra of talc, saponite, and hectorite between 4000 and 400 cm. −1 are closely related, although the bands of the smectites are more diffuse as a result of isomorphous substitutions in the tale structure. Using oriented specimens, vibrations in which the change of dipole moment is perpendicular to the sheets of the minerals are identified, and the results compared with theoretical predictions. Three bands arising from the stretching vibrations of interlayer water molecules in the smectites are distinguished, one of which corresponds to a very weak hydrogen bond. Spectral changes arising from vigorous grinding are discussed.


2020 ◽  
Vol 22 (42) ◽  
pp. 24624-24632
Author(s):  
Jacob M. Garcia ◽  
Ryan E. Shaffer ◽  
Scott G. Sayres

The femtosecond dynamics of iron oxide clusters are shown to depend on both the cluster size and Fe oxidation state.


2002 ◽  
Vol 87 (5-6) ◽  
pp. 630-641 ◽  
Author(s):  
Claire-Isabelle Fialips ◽  
Dongfang Huo ◽  
Laibin Yan ◽  
Jun Wu ◽  
Joseph W. Stucki

2008 ◽  
Vol 43 (5) ◽  
pp. 981-986 ◽  
Author(s):  
Gabriele GIULI ◽  
Sigrid Griet EECKHOUT ◽  
Christian KOEBERL ◽  
Giovanni PRATESI ◽  
Eleonora PARIS

2006 ◽  
Vol 41 (9) ◽  
pp. 1321-1329 ◽  
Author(s):  
Akira Monkawa ◽  
Takashi Mikouchi ◽  
Eisuke Koizumi ◽  
Kazumasa Sugiyama ◽  
Masamichi Miyamoto

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