Kinetics of Nonionic Surfactant Adsorption and Desorption at the Silica−Water Interface:  Binary Systems

Langmuir ◽  
1998 ◽  
Vol 14 (20) ◽  
pp. 5863-5876 ◽  
Author(s):  
Johanna Brinck ◽  
Bengt Jönsson ◽  
Fredrik Tiberg
Langmuir ◽  
2005 ◽  
Vol 21 (1) ◽  
pp. 149-159 ◽  
Author(s):  
Jan-Willem Benjamins ◽  
Krister Thuresson ◽  
Tommy Nylander

2005 ◽  
Vol 3 (2) ◽  
pp. 347-360 ◽  
Author(s):  
Gheorghe Tomoaia ◽  
Andrada Tomoaia-Cotisel ◽  
Maria Tomoaia-Cotisel ◽  
Aurora Mocanu

AbstractThe adsorption kinetics of some local anesthetics, like dibucaine and tetracaine, and of stearic acid from bulk solutions at the oil/water interface was studied by using the pendent drop and ring methods. The anesthetics were dissolved in aqueous solutions (pH 2), and the fatty acid was dissolved in benzene, each biocompound at several different concentrations in bulk solutions. Kinetic equations for Langmuir mechanism of adsorption at oil/water interface were tested. The kinetic analysis shows that Langmuir kinetic approach describes the dynamic interfacial pressures within the limits of the experimental errors over a wide range of time and for different surfactant concentrations in bulk solutions. It is also concluded that this approach allows the calculation of the ratio of the adsorption and desorption rate constants of these biocompounds at the oil/water interface. Obtained results are in substantial agreement with earlier reported data for the surfactant adsorption as, well as with their molecular structure.


Langmuir ◽  
2021 ◽  
Vol 37 (7) ◽  
pp. 2237-2255 ◽  
Author(s):  
Mengsu Peng ◽  
Timothy T. Duignan ◽  
Cuong V. Nguyen ◽  
Anh V. Nguyen

Langmuir ◽  
1997 ◽  
Vol 13 (12) ◽  
pp. 3191-3197 ◽  
Author(s):  
Ruey-Yug Tsay ◽  
Shi-Yow Lin ◽  
Lung-Wei Lin ◽  
Shou-I Chen

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