Multitechnique Surface Characterization of Derivatization Efficiencies for Hydroxyl-Terminated Self-Assembled Monolayers

Langmuir ◽  
1998 ◽  
Vol 14 (13) ◽  
pp. 3545-3550 ◽  
Author(s):  
Sheng Pan ◽  
David G. Castner ◽  
Buddy D. Ratner
Keyword(s):  
Surface Characterization ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Synthesis and surface characterization of alkylthioacetyl-capped self-assembled monolayers on gold surface

2006 ◽  
Vol 252 (14) ◽  
pp. 5158-5167 ◽  
Author(s):  
Abdiaziz A. Farah ◽  
Raluca Voicu ◽  
Raluca Barjovanu ◽  
Farid Bensebaa ◽  
Kidus Tufa ◽  
...  
Keyword(s):  
Surface Characterization ◽  
Gold Surface ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Surface Characterization of Mixed Self-Assembled Monolayers Designed for Streptavidin Immobilization

Langmuir ◽  
2001 ◽  
Vol 17 (9) ◽  
pp. 2807-2816 ◽  
Author(s):  
Kjell E. Nelson ◽  
Lara Gamble ◽  
Linda S. Jung ◽  
Maximiliane S. Boeckl ◽  
Esmaeel Naeemi ◽  
...  
Keyword(s):  
Surface Characterization ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Surface characterization of sulfur and alkanethiol self-assembled monolayers on Au(111)

2006 ◽  
Vol 18 (48) ◽  
pp. R867-R900 ◽  
Author(s):  
C Vericat ◽  
M E Vela ◽  
G A Benitez ◽  
J A Martin Gago ◽  
X Torrelles ◽  
...  
Keyword(s):  
Surface Characterization ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Self-assembled Monolayers Preparation and Characterization of BiFeO3 Thin Films

2009 ◽  
Vol 25 (1) ◽  
pp. 83-86 ◽  
Author(s):  
Guo-Qiang TAN ◽  
Hai-Yang BO ◽  
Hong-Yan MIAO ◽  
Ao XIA ◽  
Zhong-Liang HE
Keyword(s):  
Thin Films ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals Characterization of Self-Assembled Monolayers on a Ruthenium Surface

Langmuir ◽  
2017 ◽  
Vol 33 (25) ◽  
pp. 6419-6426 ◽  
Author(s):  
A. Shaheen ◽  
J. M. Sturm ◽  
R. Ricciardi ◽  
J. Huskens ◽  
C. J. Lee ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Spectral and cyclic voltammetric characterization of self-assembled monolayers on gold of pyrene end-labeled oligonucleotide duplexes

1999 ◽  
Vol 77 (5-6) ◽  
pp. 1077-1084 ◽  
Author(s):  
R Scott Reese ◽  
Marye Anne Fox
Keyword(s):  
Gold Surface ◽  
Self Assembled Monolayers ◽  
Self Assembled Monolayer ◽  
Surface Emission ◽  
Assembled Monolayers ◽  
Oligonucleotide Duplex ◽  
Self Assembled ◽  
Duplex Formation

Self-assembled monolayers of sulfur-terminated oligonucleotide duplexes were formed on flat gold surfaces, either by exposure of a self-assembled monolayer bearing one oligonucleotide strand to the complementary strand or by preformation of a oligonucleotide duplex that was then deposited on a fresh gold surface. Virtually identical spectral behavior was observed whether the duplex was produced before deposition or by in situ complementary association. With a duplex bearing an appropriate pyrene end-label, the resulting thin film was photoresponsive. Surface emission measurements show no evidence for pyrene aggregation on the modified surfaces. The polarity of the photocurrent, reflecting photoinduced electron transfer initiated by photoexcitation of pyrene, is opposite that expected from the oligonucleotide-mediated reduction of the appended pyrene excited state.Key words: oligonucleotide, self-assembled monolayer, duplex formation, photoelectrochemistry, surface emission.

scholarly journals X-ray spectroscopy characterization of self-assembled monolayers of nitrile-substituted oligo(phenylene ethynylene)s with variable chain length

2012 ◽  
Vol 3 ◽  
pp. 12-24 ◽  
Author(s):  
Hicham Hamoudi ◽  
Ping Kao ◽  
Alexei Nefedov ◽  
David L Allara ◽  
Michael Zharnikov
Keyword(s):  
Chain Length ◽  
Photoelectron Spectroscopy ◽  
Self Assembled Monolayers ◽  
Phenylene Ethynylene ◽  
X Ray ◽  
Molecular Length ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Gold Thiolate

Self-assembled monolayers (SAMs) of nitrile-substituted oligo(phenylene ethynylene) thiols (NC-OPEn) with a variable chain length n (n ranging from one to three structural units) on Au(111) were studied by synchrotron-based high-resolution X-ray photoelectron spectroscopy and near-edge absorption fine-structure spectroscopy. The experimental data suggest that the NC-OPEn molecules form well-defined SAMs on Au(111), with all the molecules bound to the substrate through the gold–thiolate anchor and the nitrile tail groups located at the SAM–ambient interface. The packing density in these SAMs was found to be close to that of alkanethiolate monolayers on Au(111), independent of the chain length. Similar behavior was found for the molecular inclination, with an average tilt angle of ~33–36° for all the target systems. In contrast, the average twist of the OPEn backbone (planar conformation) was found to depend on the molecular length, being close to 45° for the films comprising the short OPE chains and ~53.5° for the long chains. Analysis of the data suggests that the attachment of the nitrile moiety, which served as a spectroscopic marker group, to the OPEn backbone did not significantly affect the molecular orientation in the SAMs.

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