Competitive Adsorption of Gelatin and Sodium Dodecylbenzenesulfonate at Hydrophobic Surfaces

Langmuir ◽  
1998 ◽  
Vol 14 (11) ◽  
pp. 3107-3114 ◽  
Author(s):  
D. Muller ◽  
M. Malmsten ◽  
B. Bergenståhl ◽  
J. Hessing ◽  
J. Olijve ◽  
...  
Keyword(s):  
Competitive Adsorption ◽  
Hydrophobic Surfaces ◽  
Sodium Dodecylbenzenesulfonate

Competitive Adsorption of Monoclonal Antibodies and Nonionic Surfactants at Solid Hydrophobic Surfaces

2015 ◽  
Vol 104 (2) ◽  
pp. 593-601 ◽  
Author(s):  
Sebastian J. Kapp ◽  
Iben Larsson ◽  
Marco Van De Weert ◽  
Marité Cárdenas ◽  
Lene Jorgensen
Keyword(s):  
Monoclonal Antibodies ◽  
Nonionic Surfactants ◽  
Competitive Adsorption ◽  
Hydrophobic Surfaces

PHYTOACCUMULATION, COMPETITIVE ADSORPTION AND EVALUATION OF CHELATORS-METAL INTERACTION IN LETTUCE PLANT

2014 ◽  
Vol 13 (10) ◽  
pp. 2583-2592 ◽  
Author(s):  
Beenish Saba ◽  
Audil Rashid ◽  
Tariq Mahmood ◽  
Faisal Mehmood ◽  
Azeem Khalid ◽  
...  
Keyword(s):  
Competitive Adsorption ◽  
Lettuce Plant ◽  
Metal Interaction

Competitive adsorption of organic solvents using modified and unmodified calcium bentonite clay mineral

2019 ◽  
Author(s):  
Chem Int
Keyword(s):  
Adsorption Isotherm ◽  
Adsorption Capacity ◽  
Organic Solvents ◽  
Competitive Adsorption ◽  
Correlation Factor ◽  
Isotherm Model ◽  
Isotherm Models ◽  
High Concentration ◽  
Dual Purpose ◽  
Calcium Bentonite

Dodecyltrimethylammonium bromide (DTAB)–modified and unmodified calcium bentonite were both used for the competitive adsorption of aromatics (xylene, ethylbenzene and toluene) and petroleum products (gasoline, dual purpose kerosene and diesel) from their aqueous solution. Infrared spectroscopy (IR) and expansion tests (adsorption capacity and Foster swelling) measurement were performed in order to evaluate the performance of the adsorbents. The Foster swelling index and adsorption capacity of the DTAB modified calcium bentonite in the organic solvents follow the trend: xylene > ethylbenzene > toluene > gasoline > dual purpose kerosene (DPK) > diesel > water. However, the adsorption capacity of the adsorbent in diesel outweighed the adsorption capacity in DPK at high concentration of DTAB indicating that diesel has higher affinity for high DTAB concentration than DPK. The percentage removal of the solvent is directly proportional to the concentration of DTAB used in modifying the bentonite as well as the contact time between the adsorbent and the solvent, hence modified calcium bentonite adsorbed a higher percentage of organic solvents than the unmodified calcium bentonite. The adsorption characteristics of both adsorbents improved remarkably after proper agitation of the organic solvents, the unmodified calcium bentonite however adsorbed more water than the modified bentonite. Data obtained from adsorption isotherm models confirms that Freundlich adsorption isotherm model was favored more than Langmuir adsorption isotherm model with the correlation factor (R2) of the former tending more towards unity. The adsorption of ethylbenzene using DTAB modified and unmodified calcium bentonites follow a pseudo second order kinetics mechanism, suggesting that the rate determining step of adsorption involves both the adsorbent and the organic solvent.

Synergistic and Competitive Adsorption of Methylene Blue and Rhodamine B on Core-shell Magnetic Manganese Dioxide Nanocomposites

2017 ◽  
Vol 13 (6) ◽  
Author(s):  
Linshan Wang ◽  
Cholhwan Kim ◽  
Xinyue Zhang ◽  
Carlos Fernandez ◽  
Ting Sun ◽  
...  
Keyword(s):  
Methylene Blue ◽  
Manganese Dioxide ◽  
Rhodamine B ◽  
Competitive Adsorption ◽  
Core Shell

Utilisation of Biomass and Hybrid Biochar from Elephant Grass and Low Density Polyethylene for the Competitive Adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) from Aqueous Media

2020 ◽  
Vol 13 ◽  
Author(s):  
Joshua O. Ighalo ◽  
Lois T. Arowoyele ◽  
Samuel Ogunniyi ◽  
Comfort A. Adeyanju ◽  
Folasade M. Oladipo-Emmanuel ◽  
...  
Keyword(s):  
Heavy Metals ◽  
Removal Efficiency ◽  
Contact Time ◽  
Competitive Adsorption ◽  
Adsorption Process ◽  
Aqueous Media ◽  
Polluted Water ◽  
Batch Adsorption ◽  
Order Kinetic ◽  
Elephant Grass

Background: The presence of pollutants in polluted water is not singularized hence pollutant species are constantly in competition for active sites during the adsorption process. A key advantage of competitive adsorption studies is that it informs on the adsorbent performance in real water treatment applications. Objective: This study aims to investigate the competitive adsorption of Pb(II), Cu(II), Fe(II) and Zn(II) using elephant grass (Pennisetum purpureum) biochar and hybrid biochar from LDPE. Method: The produced biochar was characterised by Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). The effect of adsorption parameters, equilibrium isotherm modelling and parametric studies were conducted based on data from the batch adsorption experiments. Results: For both adsorbents, the removal efficiency was >99% over the domain of the entire investigation for dosage and contact time suggesting that they are very efficient for removing multiple heavy metals from aqueous media. It was observed that removal efficiency was optimal at 2 g/l dosage and contact time of 20 minutes for both adsorbent types. The Elovich isotherm and the pseudo-second order kinetic models were best-fit for the competitive adsorption process. Conclusion: The study was able to successfully reveal that biomass biochar from elephant grass and hybrid biochar from LDPE can be used as effective adsorbent material for the removal of heavy metals from aqueous media. This study bears a positive implication for environmental protection and solid waste management.

The competitive adsorption mechanism of CO2, H2O and O2 on a solid amine adsorbent

2021 ◽  
pp. 129007
Author(s):  
Yanxia Wang ◽  
Xiude Hu ◽  
Tuo Guo ◽  
Wengang Tian ◽  
Jian Hao ◽  
...  
Keyword(s):  
Adsorption Mechanism ◽  
Competitive Adsorption
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