Relationship between Work of Adhesion and Equilibrium Interatomic Distance at the Interface

Langmuir ◽  
1996 ◽  
Vol 12 (17) ◽  
pp. 4238-4242 ◽  
Author(s):  
Michel Nardin ◽  
Jacques Schultz
Keyword(s):  
Interatomic Distance ◽  
Work Of Adhesion ◽  
Equilibrium Interatomic Distance

How the work of adhesion affects the mechanical properties of silica-filled polymer composites

1994 ◽  
Vol 29 (9) ◽  
pp. 2406-2416 ◽  
Author(s):  
S. W. Shang ◽  
J. W. Williams ◽  
K. -J. M. Söderholm
Keyword(s):  
Mechanical Properties ◽  
Polymer Composites ◽  
Work Of Adhesion ◽  
Filled Polymer

scholarly journals Substrate adhesion evolves non-monotonically with processing time in millimeter-scale aligned carbon nanotube arrays

Nanoscale ◽  
2021 ◽  
Vol 13 (1) ◽  
pp. 261-271
Author(s):  
Ashley L. Kaiser ◽  
Dale L. Lidston ◽  
Sophie C. Peterson ◽  
Luiz H. Acauan ◽  
Stephen A. Steiner ◽  
...  
Keyword(s):  
Carbon Nanotube ◽  
Adhesion Strength ◽  
Processing Time ◽  
Effective Modulus ◽  
Work Of Adhesion ◽  
Process Time ◽  
Nanotube Arrays ◽  
Substrate Adhesion ◽  
Carbon Nanotube Arrays

Aligned carbon nanotube (CNT) array adhesion strength evolves with CNT process time, decreasing and then increasing during growth and annealing, as captured by models relating CNT diameter, array effective modulus, and CNT–substrate work of adhesion.

A simplified formulation of adhesion problems with elastic plates

2009 ◽  
Vol 465 (2107) ◽  
pp. 2217-2230 ◽  
Author(s):  
Carmel Majidi ◽  
George G. Adams
Keyword(s):  
Potential Energy ◽  
Contact Area ◽  
Contact Region ◽  
Bending Moment ◽  
Total Potential Energy ◽  
Work Of Adhesion ◽  
Contact Radius ◽  
Algebraic Complexity ◽  
Elastic Plates ◽  
Total Potential

The solution of adhesion problems with elastic plates generally involves solving a boundary-value problem with an assumed contact area. The contact region is then found by minimizing the total potential energy with respect to the contact area (i.e. the contact radius for the axisymmetric case). Such a procedure can be extremely long and tedious. Here, we show that the inclusion of adhesion is equivalent to specifying a discontinuous internal bending moment at the contact region boundary. The magnitude of this moment discontinuity is related to the work of adhesion and flexural rigidity of the plate. Such a formulation can greatly reduce the algebraic complexity of solving these problems. It is noted that the related plate contact problems without adhesion can also be solved by minimizing the total potential energy. However, it has long been recognized that it is mathematically more efficient to find the contact area by specifying a continuous internal bending moment at the boundary of the contact region. Thus, our moment discontinuity method can be considered to be a generalization of that procedure which is applicable for problems with adhesion.

scholarly journals Improving Drug Loading of Mucosal Solvent Cast Films Using a Combination of Hydrophilic Polymers with Amoxicillin and Paracetamol as Model Drugs

2013 ◽  
Vol 2013 ◽  
pp. 1-8 ◽  
Author(s):  
Joshua Boateng ◽  
Justine Mani ◽  
Farnoosh Kianfar
Keyword(s):  
Drug Loading ◽  
Film Surface ◽  
Work Of Adhesion ◽  
Drug Dissolution ◽  
X Ray ◽  
Drug Diffusion ◽  
Molecular Dispersion ◽  
Swelling Capacity ◽  
Solvent Cast ◽  
Polymer Erosion

Solvent cast mucosal films with improved drug loading have been developed by combining carboxymethyl cellulose (CMC), sodium alginate (SA), and carrageenan (CAR) using paracetamol and amoxicillin as model drugs and glycerol (GLY) as plasticizer. Films were characterized using X-ray powder diffraction (XRPD), scanning electron microscopy (SEM), folding resilience, swelling capacity, mucoadhesivity, and drug dissolution studies. SA, CMC, and GLY (5 : 3 : 6) films showed maximum amoxicillin loading of 26.3% whilst CAR, CMC, and GLY (1 : 2 : 3) films had a maximum paracetamol loading of 40%. XRPD analysis showed different physical forms of the drugs depending on the amount loaded. Films containing 29.4% paracetamol and 26.3% amoxicillin showed molecular dispersion of the drugs while excess paracetamol was observed on the film surface when the maximum 40% was loaded. Work of adhesion was similar for blank films with slightly higher cohesiveness for CAR and CMC based films, but the differences were significant between paracetamol and amoxicillin containing films. The stickiness and cohesiveness for drug loaded films were generally similar with no significant differences. The maximum percentage cumulative drug release was 84.65% and 70.59% for paracetamol and amoxicillin, respectively, with anomalous case two transport mechanism involving both drug diffusion and polymer erosion.

Ce:LaB3O6 glass for high-resolution radiation dosimetry

2022 ◽  
Author(s):  
Dongsheng Yuan ◽  
Encarnación G. Víllora ◽  
Takumi Kato ◽  
Daisuke Nakauchi ◽  
Takayuki YANAGIDA ◽  
...  
Keyword(s):  
High Resolution ◽  
Quantum Efficiency ◽  
Linear Dependence ◽  
Interatomic Distance ◽  
Irradiation Dose ◽  
Radiation Dosimetry ◽  
Dipole Interaction ◽  
Concentration Quenching ◽  
Optimum Concentration ◽  
Reducing Atmosphere

Abstract Ce:LaB3O6 (LBO) glass, whose constituents are abundant elements and fabrication is easy and cheap, is found to be a promising thermoluminescence (TL) dosimeter. This is originally achieved by CeF3 doping and melting under a reducing atmosphere, with the optimum concentration of 0.1% (quantum efficiency = 66%). The corresponding Ce interatomic distance is ~ 4 nm, below which concentration quenching occurs via Ce dipole-dipole interaction, as elucidated experimentally by Dexter’s theory. Ce:LBO exhibits a good dose resolution, with a linear dependence covering five orders of magnitude on both irradiation-dose and TL-response. Furthermore, it can be cyclically irradiated and read without degradation.

Sign in / Sign up

Export Citation Format

Share Document