Kinetic Study on Reduction of NO of Low Concentration in Air with NH3at Room Temperature over Pitch-Based Active Carbon Fibers of Moderate Surface Area

Langmuir ◽  
1997 ◽  
Vol 13 (20) ◽  
pp. 5316-5321 ◽  
Author(s):  
Isao Mochida ◽  
Shizuo Kawano ◽  
Motohiro Hironaka ◽  
Yuji Kawabuchi ◽  
Yozo Korai ◽  
...  
1995 ◽  
Vol 9 (4) ◽  
pp. 659-664 ◽  
Author(s):  
Isao Mochida ◽  
Shizuo Kawano ◽  
Motohiro Hironaka ◽  
Shunsuke Yatsunami ◽  
Yozo Korai ◽  
...  

1995 ◽  
Vol 24 (5) ◽  
pp. 385-386 ◽  
Author(s):  
Isao Mochida ◽  
Shizuo Kawano ◽  
Motohiro Hironaka ◽  
Shunsuke Yatsunami ◽  
Yozo Korai ◽  
...  

1996 ◽  
Vol 39 (2) ◽  
pp. 151-157 ◽  
Author(s):  
Isao MOCHIDA ◽  
Yuji KAWABUCHI ◽  
Motohiro HIRONAKA ◽  
Shizuo KAWANO ◽  
Yuji MATSUMURA ◽  
...  

1991 ◽  
Vol 6 (5) ◽  
pp. 1040-1047 ◽  
Author(s):  
K. Kuriyama ◽  
M.S. Dresselhaus

The conductivity and photoconductivity are measured on a high-surface-area disordered carbon material, i.e., activated carbon fibers, to investigate their electronic properties. This material is a highly disordered carbon derived from a phenolic precursor, having a huge specific surface area of 1000–2000 m2/g. Our preliminary thermopower measurements show that the dominant carriers are holes at room temperature. The x-ray diffraction pattern reveals that the microstructure is amorphous-like with Lc ≃ 10 Å. The intrinsic electrical conductivity, on the order of 20 S/cm at room temperature, increases by a factor of several with increasing temperature in the range 30–290 K. In contrast, the photoconductivity in vacuum decreases with increasing temperature. The magnitude of the photoconductive signal was reduced by a factor of ten when the sample was exposed to air. The recombination kinetics changes from a monomolecular process at room temperature to a bimolecular process at low temperatures, indicative of an increase in the photocarrier density at low temperatures. The high density of localized states, which limits the motion of carriers and results in a slow recombination process, is responsible for the observed photoconductivity.


1992 ◽  
Vol 57 (11) ◽  
pp. 2302-2308
Author(s):  
Karel Mocek ◽  
Erich Lippert ◽  
Emerich Erdös

The kinetics of the reaction of solid sodium carbonate with sulfur dioxide depends on the microstructure of the solid, which in turn is affected by the way and conditions of its preparation. The active form, analogous to that obtained by thermal decomposition of NaHCO3, emerges from the dehydration of Na2CO3 . 10 H2O in a vacuum or its weathering in air at room temperature. The two active forms are porous and have approximately the same specific surface area. Partial hydration of the active Na2CO3 in air at room temperature followed by thermal dehydration does not bring about a significant decrease in reactivity. On the other hand, if the preparation of anhydrous Na2CO3 involves, partly or completely, the liquid phase, the reactivity of the product is substantially lower.


2021 ◽  
pp. 1-21
Author(s):  
Zhuangzhuang Guo ◽  
Zhihong Zhang ◽  
Xiaoyan Cao ◽  
Dongfang Feng

Sign in / Sign up

Export Citation Format

Share Document