Nanostructure of a Poly(acrylic acid) Brush and Its Transition in the Amphiphilic Diblock Copolymer Monolayer on the Water Surface†

Langmuir ◽  
2009 ◽  
Vol 25 (24) ◽  
pp. 13752-13762 ◽  
Author(s):  
Hideki Matsuoka ◽  
Yoshiko Suetomi ◽  
Ploysai Kaewsaiha ◽  
Kozo Matsumoto
Keyword(s):  
Acrylic Acid ◽  
Diblock Copolymer ◽  
Water Surface ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Acrylic Acid

Synthesis of poly(methyl methacrylate)-b-poly(acrylic acid) by DPE method

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi
Keyword(s):  
Molecular Weight ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Gel Permeation Chromatography ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.

Palladium Nanoparticle Catalyst Prepared in Poly(Acrylic Acid)-lined Channels of Diblock Copolymer Microspheres

Nano Letters ◽  
2001 ◽  
Vol 1 (12) ◽  
pp. 683-687 ◽  
Author(s):  
Zhihua Lu ◽  
Guojun Liu ◽  
Heather Phillips ◽  
Josephine M. Hill ◽  
Jason Chang ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Diblock Copolymer ◽  
Palladium Nanoparticle ◽  
Nanoparticle Catalyst ◽  
Poly Acrylic Acid

Micellar interpolyelectrolyte complexes formed by star-shaped poly(acrylic acid) with double hydrophilic cationic diblock copolymer

2011 ◽  
Vol 441 (1) ◽  
pp. 219-223 ◽  
Author(s):  
I. A. Babin ◽  
D. V. Pergushov ◽  
A. Wolf ◽  
F. A. Plamper ◽  
H. Schmalz ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Diblock Copolymer ◽  
Interpolyelectrolyte Complexes ◽  
Poly Acrylic Acid

A Poly(acrylic acid)-block- Poly(L -glutamic acid) Diblock Copolymer with Improved Cell Adhesion for Surface Modification

2011 ◽  
Vol 11 (7) ◽  
pp. 970-977 ◽  
Author(s):  
Bin Cao ◽  
Shifeng Yan ◽  
Kunxi Zhang ◽  
Zhijiang Song ◽  
Tian Cao ◽  
...  
Keyword(s):  
Surface Modification ◽  
Cell Adhesion ◽  
Acrylic Acid ◽  
Glutamic Acid ◽  
Diblock Copolymer ◽  
Poly Acrylic Acid
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