Controlled Loading of Building Blocks into Temporary Self-Assembled Scaffolds for Directed Assembly of Organic Nanostructures

Langmuir ◽  
2008 ◽  
Vol 24 (20) ◽  
pp. 11464-11473 ◽  
Author(s):  
L. Todd Banner ◽  
Delia C. Danila ◽  
Katie Sharpe ◽  
Melissa Durkin ◽  
Benjamin Clayton ◽  
...  
Nanoscale ◽  
2021 ◽  
Author(s):  
Michael Penth ◽  
Kordula Schellnhuber ◽  
Roland Bennewitz ◽  
Johanna Blass

Massive parallel force spectroscopy reveals a surprisingly high flexibility for DNA constructs used in DNA origami. The high flexibility is attributed to the structural dynamics of DNA self-assemblies.


Soft Matter ◽  
2021 ◽  
Author(s):  
Jiawei Lu ◽  
Xiangyu Bu ◽  
Xinghua Zhang ◽  
Bing Liu

The shapes of colloidal particles are crucial to the self-assembled superstructures. Understanding the relationship between the shapes of building blocks and the resulting crystal structures is an important fundamental question....


Author(s):  
Joshua D. Carter ◽  
Chenxiang Lin ◽  
Yan Liu ◽  
Hao Yan ◽  
Thomas H. LaBean

This article examines the DNA-based self-assembly of nanostructures. It first reviews the development of DNA self-assembly and DNA-directed assembly, focusing on the main strategies and building blocks available in the modern molecular construction toolbox, including the design, construction, and analysis of nanostructures composed entirely of synthetic DNA, as well as origami nanostructures formed from a mixture of synthetic and biological DNA. In particular, it considers the stepwise covalent synthesis of DNA nanomaterials, unmediated assembly of DNA nanomaterials, hierarchical assembly, nucleated assembly, and algorithmic assembly. It then discusses DNA-directed assembly of heteromaterials such as proteins and peptides, gold nanoparticles, and multicomponent nanostructures. It also describes the use of complementary DNA cohesion as 'smart glue' for bringing together covalently linked functional groups, biomolecules, and nanomaterials. Finally, it evaluates the potential future of DNA-based self-assembly for nanoscale manufacturing for applications in medicine, electronics, photonics, and materials science.


2001 ◽  
Vol 113 (15) ◽  
pp. 2993-2996 ◽  
Author(s):  
So-Jung Park ◽  
Anne A. Lazarides ◽  
Chad A. Mirkin ◽  
Robert L. Letsinger

ACS Photonics ◽  
2015 ◽  
Vol 3 (1) ◽  
pp. 35-42 ◽  
Author(s):  
Vladimir A. Turek ◽  
Yan Francescato ◽  
Paolo Cadinu ◽  
Colin R. Crick ◽  
Laura Elliott ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (108) ◽  
pp. 89025-89029 ◽  
Author(s):  
Vandana Singh ◽  
Mohan Monisha ◽  
Roy Anindya ◽  
Prolay Das

DNA–organic hybrid molecular building blocks are generated by covalent conjugation of the carboxyl groups of protoporphyrin IX with the amine functional groups of modified DNA oligomers.


RSC Advances ◽  
2018 ◽  
Vol 8 (28) ◽  
pp. 15675-15686 ◽  
Author(s):  
Jacquelyn G. Egan ◽  
Nicole Drossis ◽  
Iraklii I. Ebralidze ◽  
Holly M. Fruehwald ◽  
Nadia O. Laschuk ◽  
...  

The ability to form complex 3D architectures using nanoparticles as the building blocks and complex macromolecules that direct these assemblies remains a challenging objective for nanotechnology.


2019 ◽  
Vol 10 ◽  
pp. 894-900 ◽  
Author(s):  
Julian J Brunner ◽  
Marina Krumova ◽  
Helmut Cölfen ◽  
Elena V Sturm (née Rosseeva)

This letter describes the formation and detailed characterization of iron oxide mesocrystals produced by the directed assembly of superparamagnetic iron oxide-truncated nanocubes using the slow evaporation of the solvent within an externally applied homogeneous magnetic field. Anisotropic mesocrystals with an elongation along the direction of the magnetic field can be produced. The structure of the directed mesocrystals is compared to self-assembled mesocrystalline films, which are formed without the influence of a magnetic field. The remarkable structural difference of mesocrystals produced within the external magnetic field from those self-assembled without field indicates that the specific nanoparticle ordering within the superstructure is driven by competing of two types of anisotropic interactions caused by particle shape (i.e., faceting) and orientation of the magnetic moment (i.e., easy axes: <111>magnetite). Hence, these findings provide a fundamental understanding of formation mechanisms and structuring of mesocrystals built up from superparamagnetic nanoparticles and how a magnetic field can be used to design anisotropic mesocrystals with different structures.


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