Interactions between Charged Surfaces Immersed in a Polyelectrolyte Solution

Langmuir ◽  
2007 ◽  
Vol 23 (19) ◽  
pp. 9555-9558 ◽  
Author(s):  
Martin Turesson ◽  
Torbjörn Åkesson ◽  
Jan Forsman
Keyword(s):  
Polyelectrolyte Solution ◽  
Charged Surfaces

A topological quantum-chemical study of the chemisorption of carbon monoxide on the fcc (112) surfaces of Ni, Pt, Pd, Rh, and Ir

1990 ◽  
Vol 55 (8) ◽  
pp. 1907-1919
Author(s):  
Jiří Pancíř ◽  
Ivana Haslingerová
Keyword(s):  
Carbon Monoxide ◽  
Quantum Chemical ◽  
Co Adsorption ◽  
Quantum Chemical Study ◽  
Chemical Study ◽  
Dissociative Chemisorption ◽  
Frontier Orbitals ◽  
Surface Sites ◽  
Charged Surfaces ◽  
Topological Quantum

A semiempirical quantum-chemical topological method is applied to the study of the fcc (112) surfaces of Ni, Pt, Pd, Rh, and Ir and the nondissociative as well as dissociative chemisorption of carbon monoxide on them. On Ni, dissociative chemisorption is preferred to linear capture, whereas on Pd and Pt, linear capture is preferred although dissociative chemisorption is also feasible. On Rh and, in particular, on Ir, dissociative chemisorption is energetically prohibited. The high dissociative ability of the Ni surface can be ascribed to a rather unusual charge alteration and to the degeneracy of the frontier orbitals. Negative charges at the surface level are only found on the Ni and Pt surfaces whereas concentration of positive charges is established on the Rh and Ir surfaces; the Pd surface is nearly uncharged. Metals with negatively charged surfaces seem to be able to dissociate molecules of carbon monoxide. It is demonstrated that CO adsorption can take place on all metal surface sites, most effectively in the valley of the step. In all the cases studied, the attachment to the surface is found to be energetically more favourable for the carbon than for the oxygen.

scholarly journals Untangling superposed double layer and structural forces across confined nanoparticle suspensions

2021 ◽  
Author(s):  
Michael Ludwig ◽  
Regine von Klitzing
Keyword(s):  
Double Layer ◽  
Interaction Force ◽  
Charged Surfaces ◽  
Structural Forces ◽  
Nanoparticle Suspensions ◽  
Confined Suspensions ◽  
Force Profiles

Complete interaction force profiles of charged surfaces across confined suspensions were successfully described using a superposition of double layer and structural forces.

scholarly journals Interfacial, Electroviscous, and Nonlinear Dielectric Effects on Electrokinetics at Highly Charged Surfaces

2021 ◽  
Author(s):  
Majid Rezaei ◽  
Bernhard G. Mitterwallner ◽  
Philip Loche ◽  
Yuki Uematsu ◽  
Roland R. Netz ◽  
...  
Keyword(s):  
Nonlinear Dielectric ◽  
Charged Surfaces

scholarly journals Effect of Bjerrum pairs on electrostatic properties in an electrolyte solution near charged surfaces: A mean-field approach

2021 ◽  
Author(s):  
Jun-Sik Sin
Keyword(s):  
Electrolyte Solution ◽  
Size Effects ◽  
Mean Field ◽  
Finite Size ◽  
Ion Association ◽  
Finite Size Effects ◽  
Field Approach ◽  
Electrostatic Properties ◽  
Charged Surfaces ◽  
Orientational Ordering

In this paper, we investigate the consequences of ion association, coupled with the considerations of finite size effects and orientational ordering of Bjerrum pairs as well as ions and water...

Interaction of charged surfaces in electrolyte solutions

1986 ◽  
Vol 127 (4) ◽  
pp. 402-407 ◽  
Author(s):  
Roland Kjellander ◽  
Stjepan Marčelja
Keyword(s):  
Electrolyte Solutions ◽  
Charged Surfaces

On the Self‐Diffusion of Ions in a Polyelectrolyte Solution

1962 ◽  
Vol 36 (9) ◽  
pp. 2410-2414 ◽  
Author(s):  
Shneior Lifson ◽  
Julius L. Jackson
Keyword(s):  
The Self ◽  
Polyelectrolyte Solution ◽  
Self Diffusion
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