Unified Method for the Total Pore Volume and Pore Size Distribution of Hierarchical Zeolites from Argon Adsorption and Mercury Intrusion

Langmuir ◽  
2015 ◽  
Vol 31 (4) ◽  
pp. 1242-1247 ◽  
Author(s):  
Jeffrey Kenvin ◽  
Jacek Jagiello ◽  
Sharon Mitchell ◽  
Javier Pérez-Ramírez
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Pore Volume ◽  
Total Pore Volume ◽  
Hierarchical Zeolites ◽  
Mercury Intrusion ◽  
Argon Adsorption ◽  
Unified Method

Pore Structure Of Hydrated Cement Determined By Mercury Porosimetry And Nitrogen Sorption Techniques.

1988 ◽  
Vol 137 ◽  
Author(s):  
Yahia Abdel-Jawad ◽  
Will Hansen
Keyword(s):  
Pore Structure ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Pore Volume ◽  
Mercury Porosimetry ◽  
Total Pore Volume ◽  
Curing Temperature ◽  
Vycor Glass ◽  
Degree Of Hydration

AbstractThe pore structure (i.e. total pore volume, surface area and pore-size distribution curves) was measured using mercury porosimetry and nitrogen sorption. Hydrated portland cement (type I) of water-cement (w/c) ratios 0.3, 0.4 and 0.6 by weight was analyzed at three degrees of hydration (i.e., 30%, 50% and 80%; 70% for the 0.3 w/c system) corresponding to low, intermediate and high levels of hydration. The effect of curing temperature (3°, 23°, and 43°C) on pore structure was also studied. The two techniques were evaluated as well on porous Vycor glass, which has a narrow pore size distribution in the size range accessible to both. Results obtained by both techniques on porous Vycor glass agreed well. However neither technique can be used alone to study the entire pore structure in well-hydrated cement due to the wide range in pore sizes and the presence of micropores. Due to the unstable pore structure in cement a specimen treatment procedure such as methanol replacement, combined with volume-thickness (V-t) analysis, is necessary in order to measure the micropores. At low hydration values the pore structure can be estimated by mercury intrusion porosimetry (MIP). At higher hydration values, however, this technique underestimates total pore volume and surface area due to the presence of micropores which MIP cannot determine. In the pore size range of overlap, higher pore volumes were obtained with MIP. Nitrogen V-t analysis shows that micropores are more pronounced with lower w/c ratios. This finding is consistent with pore size distribution curves obtained by MIP. For a given w/c ratio and degree of hydration the total pore volume measured by MIP was found to be independent of curing temperature in the temperature range studied. At any w/c ratio, capillary porosity is controlled by degree of hydration alone.

scholarly journals Pore Structural Features of Granite under Different Temperatures

Materials ◽  
2021 ◽  
Vol 14 (21) ◽  
pp. 6470
Author(s):  
Hongmei Gao ◽  
Yongwei Lan ◽  
Nan Guo
Keyword(s):  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Pore Volume ◽  
Saturation Pressure ◽  
Total Pore Volume ◽  
Structural Features ◽  
Pore Throat ◽  
Throat Radius ◽  
Median Pore

To explore the effects of thermal actions on the pore structural features of granite, scanning electron microscope (SEM) and mercury injection experiments were carried out on granite after thermal treatment (25 °C to 400 °C). The pore structure was investigated from various perspectives, including the capillary pressure curve, the pore–throat ratio, the median saturation pressure, the median pore–throat radius, the porosity, the pore volume, and the pore size distribution. Based on mercury intrusion test data, the Winland model of permeability prediction was modified for a high-temperature tight granite reservoir. The results showed that: (1) As the temperature rose, the mercury injection curve was gradually flattened, and the mercury ejection efficiency gradually increased. Meanwhile, the pore–throat ratio and the median saturation pressure decreased exponentially, and the pore connectivity was enhanced. (2) The median pore–throat radius and the porosity of granite increased exponentially as the temperature increased. Above 200 °C, the median pore–throat radius and the porosity increased substantially. (3) The pore volumes of the transitional pores, mesopores and macropores, and the total pore volume inside the granite, increased as the temperature rose. Especially above 200 °C, the transitional pores and the mesopores were prominently developed, and the pore volumes of the transitional pores and the mesopores took up a significantly greater proportion of the total pore volume. (4) As the temperature rose, the pore size distribution of granite became more extensive, the pore–throat structure was obviously developed, and the pore–throat connectivity was enhanced. (5) The relationship between the micropores’ characteristic parameters and the macro-permeability in engineering was established though a modified Winland model, and the modified Winland model had a better prediction effect. The findings provide a solid basis for rock geothermal mining projects and related geotechnical engineering.

scholarly journals Microstructure and pore structure of polymer-cement composite joint sealants

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Chuanxin Lou ◽  
Jinyu Xu ◽  
Tengjiao Wang ◽  
Weibo Ren
Keyword(s):  
Pore Structure ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Pore Volume ◽  
Total Pore Volume ◽  
Cement Composite ◽  
Low Grade ◽  
Composite Joint ◽  
Fractal Characteristics

AbstractUtilizing methods such as scanning electron microscopy observation and mercury intrusion porosimetry, this paper investigates the basic microstructure and pore structure properties of polymer-cement composite joint sealants for pavements, and analyzes the effects and rules of various material types, ratio parameters and processing conditions. Further, the fractal characteristics and variation rules of pore size distribution are investigated for the joint sealants by introducing the fractal theory. The results show that changes in material type, ratio parameter and processing condition produce insignificant effects on the basic microstructure properties and configuration of joint sealants, with effects reflected primarily in the change of sealant pore structure. Measures like increasing the powder-liquid ratio and cement ratio, blending with sulphoaluminate cement or mica powder, adding latex powder or coupling agent, cold drawing and hot pressing, as well as ultraviolet irradiation treatment are all capable of reducing the total pore volume of joint sealants and refining their pore structure. In contrast, opposite effects are yielded when low-grade cement is used, styrene-acrylic emulsion is blended, or plasticizer is added. Additionally, after blending with talc powder or adding carbon fiber additive, the total pore volume of joint sealants remains basically unchanged or reduced, despite the coarsened pore structure. The total pore volume of joint sealants increases after wet–dry cycling treatment, while no obvious change in the pore size distribution is observed. Pore size distribution of the studied joint sealants presents distinct fractal characteristics, and the corresponding fractal dimension of pore surface area ranges between 2.6 and 2.8.

Effect of air-drying and critical point drying on the porosity of clay soils

1984 ◽  
Vol 21 (1) ◽  
pp. 181-185 ◽  
Author(s):  
C. R. De Kimpe
Keyword(s):  
Organic Matter ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Critical Point ◽  
Size Distribution ◽  
Pore Volume ◽  
Organic Matter Content ◽  
Total Pore Volume ◽  
Clay Soils ◽  
Critical Point Drying

Samples from four surface and one subsurface horizons of clay-rich soils from Quebec were air-dried and critical point dried. In the latter samples, the total pore volume was 19–84% larger than in the former samples. The total pore volume, determined by mercury intrusion porosimetry and density measurements, was subdivided into large (> 8.8 μm), medium, and small (< 0.19 μm) pores. The effect of drying on these pores was estimated. Medium-sized pores were affected most by the drying technique, followed next by the large pores, and finally by the small pores. The modifications due to drying could not be explained adequately by shrinkage and it was assumed, from the pore-size distribution curves, that organic matter content had a buffer effect on particle reorganization. Keywords: critical point drying, clay soils, pore volume, pore-size distribution, organic matter.

scholarly journals Alumina/silica aerogel with zinc chloride as an alkylation catalyst

2001 ◽  
Vol 66 (10) ◽  
pp. 685-695 ◽  
Author(s):  
Aleksandar Orlovic ◽  
Djordje Janackovic ◽  
Sasa Drmanic ◽  
Zorica Marinkovic ◽  
Dejan Skala
Keyword(s):  
Catalytic Activity ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Surface Area ◽  
Zinc Chloride ◽  
Pore Volume ◽  
Total Pore Volume ◽  
Chloride Content ◽  
Alkylation Catalyst

The alumina/silica with zinc chloride aerogel alkylation catalyst was obtained using a one step sol-gel synthesis, and subsequent drying with supercritical carbon dioxide. The aerogel catalyst activity was found to be higher compared to the corresponding xerogel catalyst, as a result of the higher aerogel surface area, total pore volume and favourable pore size distribution. Mixed Al-O-Si bonds were present in both gel catalyst types. Activation by thermal treatment in air was needed prior to catalytic alkylation, due to the presence of residual organic groups on the aerogel surface. The optimal activation temperature was found to be in the range 185-225 ?C, while higher temperatures resulted in the removal of zinc chloride from the surface of the aerogel catalyst with a consequential decrease in the catalytic activity. On varying the zinc chloride content, the catalytic activity of the aerogel catalyst exhibited a maximum. High zinc chloride contents decreased the catalytic activity of the aerogel catalyst as the result of the pores of the catalyst being plugged with this compound, and the separation of the alumina/silica support into Al-rich and Si-rich phases. The surface area, total pore volume, pore size distribution and zinc chloride content had a similar influence on the activity of the aerogel catalyst as was the case of xerogel catalyst and supported zinc chloride catalysts.

The relationship between geotechnical index properties and the pore-size distribution of compacted clayey silts

2015 ◽  
Vol 22 (6) ◽  
Author(s):  
Nazile Ural
Keyword(s):  
Specific Surface ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Surface Area ◽  
Specific Surface Area ◽  
Pore Volume ◽  
Correlation Coefficients ◽  
Liquid Limit ◽  
Index Properties

AbstractIn this study, the relationships between geotechnical index properties and the pore-size distribution of compacted natural silt and artificial soil mixtures, namely, silt with two different clays and three different clay percentages (10%, 20%, and 40%), were examined and compared. Atterberg’s limit tests, standard compaction tests, mercury intrusion porosimetry, X-ray diffraction, scanning electron microscopy (SEM) analysis, and Brunauer-Emmett-Teller specific surface analysis were conducted. The results show that the liquid limit, the cumulative pore volume, and specific surface area of artificially mixed soils increase with an increase in the percentage of clay. The cumulative pore volume and specific surface area with geotechnical index properties were compared. High correlation coefficients were observed between the specific areas and both the liquid limit and the plasticity index, as well as between the cumulative pore volume and both the clay percentage and the

scholarly journals Ink-bottle Effect and Pore Size Distribution of Cementitious Materials Identified by Pressurization–Depressurization Cycling Mercury Intrusion Porosimetry

Materials ◽  
2019 ◽  
Vol 12 (9) ◽  
pp. 1454 ◽  
Author(s):  
Yong Zhang ◽  
Bin Yang ◽  
Zhengxian Yang ◽  
Guang Ye
Keyword(s):  
Pore Structure ◽  
Pore Size Distribution ◽  
Pore Size ◽  
Size Distribution ◽  
Mercury Intrusion Porosimetry ◽  
Cementitious Materials ◽  
Limestone Powder ◽  
Accurate Estimation ◽  
Mercury Intrusion ◽  
Pore Size Distributions

Capturing the long-term performance of concrete must be underpinned by a detailed understanding of the pore structure. Mercury intrusion porosimetry (MIP) is a widely used technique for pore structure characterization. However, it has been proven inappropriate to measure the pore size distribution of cementitious materials due to the ink-bottle effect. MIP with cyclic pressurization–depressurization can overcome the ink-bottle effect and enables a distinction between large (ink-bottle) pores and small (throat) pores. In this paper, pressurization–depressurization cycling mercury intrusion porosimetry (PDC-MIP) is adopted to characterize the pore structure in a range of cementitious pastes cured from 28 to 370 days. The results indicate that PDC-MIP provides a more accurate estimation of the pore size distribution in cementitious pastes than the standard MIP. Bimodal pore size distributions can be obtained by performing PDC-MIP measurements on cementitious pastes, regardless of the age. Water–binder ratio, fly ash and limestone powder have considerable influences on the formation of capillary pores ranging from 0.01 to 0.5 µm.

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