On-Demand Degrafting and the Study of Molecular Weight and Grafting Density of Poly(methyl methacrylate) Brushes on Flat Silica Substrates

Langmuir ◽  
2015 ◽  
Vol 31 (8) ◽  
pp. 2372-2381 ◽  
Author(s):  
Rohan R. Patil ◽  
Salomon Turgman-Cohen ◽  
Jiří Šrogl ◽  
Douglas Kiserow ◽  
Jan Genzer
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
On Demand ◽  
Grafting Density ◽  
Silica Substrates

Direct Measurement of Molecular Weight and Grafting Density by Controlled and Quantitative Degrafting of Surface-Anchored Poly(methyl methacrylate)

2015 ◽  
Vol 4 (2) ◽  
pp. 251-254 ◽  
Author(s):  
Rohan R. Patil ◽  
Salomon Turgman-Cohen ◽  
Jiří Šrogl ◽  
Douglas Kiserow ◽  
Jan Genzer
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Direct Measurement ◽  
Poly Methyl Methacrylate ◽  
Grafting Density

Synthesis of poly(methyl methacrylate)-b-poly(acrylic acid) by DPE method

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi
Keyword(s):  
Molecular Weight ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Gel Permeation Chromatography ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.

Variation of periodic crazing based on polymer blends of an ultra-high and a low molecular weight poly(methyl methacrylate)

2016 ◽  
Vol 134 (1) ◽  
Author(s):  
Keishi Naito ◽  
Akiyoshi Takeno ◽  
Ryota Morifuji ◽  
Toshiaki Miyata ◽  
Minoru Miwa ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Polymer Blends ◽  
Low Molecular Weight ◽  
Poly Methyl Methacrylate

Molecular weight and processing effects on the dissolution properties of thin poly(methyl methacrylate) films

2008 ◽  
Vol 85 (1) ◽  
pp. 93-99 ◽  
Author(s):  
A. Kokkinis ◽  
E.S. Valamontes ◽  
D. Goustouridis ◽  
Th. Ganetsos ◽  
K. Beltsios ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Poly Methyl Methacrylate ◽  
Dissolution Properties ◽  
Processing Effects

scholarly journals Effect of Ferocene Concentration on the Percent Conversion and Molecular Weight of Poly(Methyl Methacrylate) Homopolymers

2017 ◽  
Vol 14 (2) ◽  
pp. 311-319
Author(s):  
Baghdad Science Journal
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Methyl Methacrylate ◽  
Benzoyl Peroxide ◽  
Radical Polymerization ◽  
Free Oxygen ◽  
Poly Methyl Methacrylate ◽  
Methacrylate Monomer ◽  
Percent Conversion ◽  
Methyl Methacrylate Monomer

This research is addressing the effect of different ferrocene concentration (0.00, 2.15x10-3, 4.30x10-3, 8.60x10-3, and 12.9x10-3) on the bulk free radical polymerization of methyl methacrylate monomer in benzene using benzoyl peroxide as initiator. The polymerization was conducted at 60º C under free oxygen atmosphere. The resulting polymers were characterized by FTIR. The results were compared with the presence and absence of ferrocene at 10% conversion. The %conversion was 3.04% with no ferrocene present in the polymerization medium and its increase to 9.06 with a first lowest ferrocene concentration added, i.e. 2.15 x10-3mol/l. This was positively reflected on the poly(methyl methacrylate) molecular weight measured by viscosity technique, especially in the presence of ferrocene.

Molecular weight variations in perylene-doped poly(methyl methacrylate) for luminescent solar concentrators

2018 ◽  
Vol 67 (9) ◽  
pp. 1179-1185 ◽  
Author(s):  
Daniel Zaremba ◽  
Robert Evert ◽  
Jana Kielhorn ◽  
Florian Jakobs ◽  
Reinhard Caspary ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Methyl Methacrylate ◽  
Solar Concentrators ◽  
Poly Methyl Methacrylate ◽  
Luminescent Solar Concentrators
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