Interface Investigations of a Commercial Lithium Ion Battery Graphite Anode Material by Sputter Depth Profile X-ray Photoelectron Spectroscopy

Langmuir ◽  
2013 ◽  
Vol 29 (19) ◽  
pp. 5806-5816 ◽  
Author(s):  
Philip Niehoff ◽  
Stefano Passerini ◽  
Martin Winter
Keyword(s):  
Lithium Ion Battery ◽  
Anode Material ◽  
Depth Profile ◽  
Photoelectron Spectroscopy ◽  
Lithium Ion ◽  
Graphite Anode ◽  
X Ray

scholarly journals Synthesis and Electrochemical Performance of Mesoporous NiMn2O4 Nanoparticles as an Anode for Lithium-Ion Battery

2021 ◽  
Vol 5 (3) ◽  
pp. 69
Author(s):  
Swapnil J. Rajoba ◽  
Rajendra D. Kale ◽  
Sachin B. Kulkarni ◽  
Vinayak G. Parale ◽  
Rohan Patil ◽  
...  
Keyword(s):  
Lithium Ion Battery ◽  
Anode Material ◽  
Discharge Capacity ◽  
Photoelectron Spectroscopy ◽  
Lithium Ion ◽  
Combustion Method ◽  
Good Alternative ◽  
X Ray ◽  
Potential Applications ◽  
Different Temperatures

NiMn2O4 (NMO) is a good alternative anode material for lithium-ion battery (LIB) application, due to its superior electrochemical activity. Current research shows that synthesis of NMO via citric acid-based combustion method envisaged application in the LIB, due to its good reversibility and rate performance. Phase purity and crystallinity of the material is controlled by calcination at different temperatures, and its structural properties are investigated by X-ray diffraction (XRD). Composition and oxidation state of NMO are further investigated by X-ray photoelectron spectroscopy (XPS). For LIB application, lithiation delithiation potential and phase transformation of NMO are studied by cyclic voltammetry curve. As an anode material, initially, the average discharge capacity delivered by NMO is 983 mA·h/g at 0.1 A/g. In addition, the NMO electrode delivers an average discharge capacity of 223 mA·h/g after cell cycled at various current densities up to 10 A/g. These results show the potential applications of NMO electrodes for LIBs.

scholarly journals Operando hard X-ray photoelectron spectroscopy of LiCoO2 thin film in an all-solid-state lithium ion battery

2020 ◽  
Vol 118 ◽  
pp. 106790
Author(s):  
Hisao Kiuchi ◽  
Kazuhiro Hikima ◽  
Keisuke Shimizu ◽  
Ryoji Kanno ◽  
Fukunaga Toshiharu ◽  
...  
Keyword(s):  
Thin Film ◽  
Solid State ◽  
Lithium Ion Battery ◽  
Photoelectron Spectroscopy ◽  
Lithium Ion ◽  
X Ray

Surface engineering of graphite anode material with black TiO2-x for fast chargeable lithium ion battery

2017 ◽  
Vol 258 ◽  
pp. 336-342 ◽  
Author(s):  
Dae Sik Kim ◽  
Dong Jae Chung ◽  
Juhye Bae ◽  
Goojin Jeong ◽  
Hansu Kim
Keyword(s):  
Lithium Ion Battery ◽  
Anode Material ◽  
Surface Engineering ◽  
Lithium Ion ◽  
Graphite Anode ◽  
Black Tio2

Synthesis, Structure and Electronic Properties of Li4Ti5O12 Anode Material for Lithium Ion Batteries

2018 ◽  
Vol 271 ◽  
pp. 9-17 ◽  
Author(s):  
Lkhagvajav Sarantuya ◽  
Galsan Sevjidsuren ◽  
Pagvajav Altantsog ◽  
Namsrai Tsogbadrakh
Keyword(s):  
Lithium Ion Batteries ◽  
Anode Material ◽  
Photoelectron Spectroscopy ◽  
Density Functional ◽  
Spinel Phase ◽  
Rate Capability ◽  
Lithium Ion ◽  
X Ray Diffraction ◽  
X Ray ◽  
Average Grain Size

Nanosized spinel Li4Ti5O12 was successfully synthesized by a solid state reaction method at 800°C according to the Li4Ti5O12cubic spinel phase structure. In this synthesizing process, anatase TiO2and Li2CO3were used as reactants. The average grain size of the synthesized powders was around 200 nm. The synthesized Li4Ti5O12powder was characterized X-ray Diffraction (XRD), X-ray Photoelectron Spectroscopy (XPS), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray spectrometry (EDS), and Specific Surface Area Analyzer (BET, Brunner-Emmett-Teller) respectively. X-ray diffraction results show that calcination temperature and time have the important effects on the crystal structure of Li4Ti5O12powder. In this study, we used a first principle method, based on the density functional theory to explore electronic and structural properties of Li4Ti5O12, as anode material for lithium ion batteries. Differences on these properties between delithiation state Li4Ti5O12and lithiation state Li7Ti5O12are compared. All the predicted structural and electrochemical properties agree closely with the experimental findings in literature. The average intercalation voltage of 1.4V during charging/discharging were obtained. We have shown that the Li4Ti5O12material exhibits insulating behavior with the band gap of 3.16 and 3.90 eV using the GGA and GGA+U+J0calculations respectively. Li7Ti5O12becomes metallic as Li atoms inserted in Li4Ti5O12material. Spinel Li4Ti5O12has been regarded as an attractive anode material for the development of high-power lithium-ion batteries because of its unique attributes of high safety and rate capability.

Sign in / Sign up

Export Citation Format

Share Document