Noncovalent Microcontact Printing for Grafting Patterned Polymer Brushes on Graphene Films

Langmuir ◽  
2013 ◽  
Vol 29 (4) ◽  
pp. 1054-1060 ◽  
Author(s):  
Tingting Gao ◽  
Xiaolong Wang ◽  
Bo Yu ◽  
Qiangbing Wei ◽  
Yanqiu Xia ◽  
...  
2015 ◽  
Vol 51 (6) ◽  
pp. 1027-1030 ◽  
Author(s):  
Friederike Kettling ◽  
Benjamin Vonhören ◽  
Jennifer A. Krings ◽  
Susumu Saito ◽  
Bart Jan Ravoo

A novel method to prepare microstructured polymer brushes using TiO2 nanoparticles and photocatalytic microcontact printing is described.


2013 ◽  
Vol 49 (95) ◽  
pp. 11167 ◽  
Author(s):  
Peng Xiao ◽  
Jincui Gu ◽  
Jing Chen ◽  
Di Han ◽  
Jiawei Zhang ◽  
...  

2014 ◽  
Vol 35 (11) ◽  
pp. 1046-1054 ◽  
Author(s):  
Qiangbing Wei ◽  
Bo Yu ◽  
Xiaolong Wang ◽  
Feng Zhou

2016 ◽  
Vol 23 (25) ◽  
pp. 6042-6047 ◽  
Author(s):  
Moritz Buhl ◽  
Matthias Tesch ◽  
Sebastian Lamping ◽  
Johanna Moratz ◽  
Armido Studer ◽  
...  

2004 ◽  
Vol 572 (2-3) ◽  
pp. 490-496 ◽  
Author(s):  
Kai Yu ◽  
Yang Cong ◽  
Jun Fu ◽  
Rubo Xing ◽  
Nana Zhao ◽  
...  

1990 ◽  
Vol 51 (8) ◽  
pp. 701-707 ◽  
Author(s):  
D.F.K. Shim ◽  
M. E. Cates
Keyword(s):  

2002 ◽  
Vol 727 ◽  
Author(s):  
Denys Usov ◽  
Manfred Stamm ◽  
Sergiy Minko ◽  
Christian Froeck ◽  
Andreas Scholl ◽  
...  

AbstractWe investigated the interplay between different mechanisms of the lateral and vertical segregation in the synthesized via “grafting from” approach symmetric A/B (where A and B are poly(styrene-co-2,3,4,5,6-pentafluorostyrene) and poly(methylmethacrylate), respectively) polymer brushes upon exposure to different solvents. We used X-ray photoemission electron spectroscopy and microscopy (X-PEEM), AFM, water contact angle measurements, and oxygen plasma etching to study morphology of the brushes. The ripple morphology after toluene (nonselective solvent) revealed elongated lamellar-like domains of A and B polymers alternating across the surface. The dimple-A morphology consisting of round clusters of the polymer A was observed after acetone (selective solvent for B). The top layer was enriched with the polymer B showing that the brush underwent both the lateral and vertical phase segregation. A qualitative agreement with predictions of SCF theory was found.


2019 ◽  
Author(s):  
Yanchun Tang ◽  
Kohzo Ito ◽  
Hideaki Yokoyama

In this study, we prepared ultrafiltration membranes with a decoupled responses of filtration property to temperature and pH. The membrane preparation method was developed based on our previous work. We utilized methanol-supercritical carbon dioxide (methanol-scCO<sub>2</sub>) selective swelling method to introduce nanopores to block copolymers containing poly(diethylene glycol) methyl ether methacrylate (PMEO<sub>2</sub>MA), poly(N,N-dimethylaminoethyl methacrylate) (PDMAEMA) and polystyrene (PS) blocks. Formation of the mesoporous barrier layer with PS being the mechanically stable part of the matrix was driven by selective swelling of the PMEO<sub>2</sub>MA-b-PDMAEMA domains. Due to the selective swelling of PMEO<sub>2</sub>MA or PDMAEMA domains to introduce pores, the interior of the pores are covered with PMEO<sub>2</sub>MA or PDMAEMA blocks after pore formation. The PMEO<sub>2</sub>MA-b-PDMAEMA polymer brushes are naturally attached on the pore walls and worked as functional gates. PMEO<sub>2</sub>MA is a non-toxic, neutral thermo-responsive polymer with LCST at 26 ᴼC. PDMAEMA is a typical weak polyelectrolyte with pK<sub>a</sub> value at 7.0-7.5 and also a thermo-responsive polymer revealed a LCST of 20-80 °C in aqueous solution. Therefore, these membranes were expected to have multi dimensions as function of the combination of temperature and pH. Moreover, to understand the detail of the temperature and pH depended conformation transitions of PMEO<sub>2</sub>MA-b-PDMAEMA brushes, those diblock copolymers were end-tethered on flat substrates and analyzed via neutron reflectivity (NR).


2020 ◽  
Vol 54 (12) ◽  
pp. 1674-1677
Author(s):  
I. A. Eliseyev ◽  
V. Yu. Davydov ◽  
A. N. Smirnov ◽  
S. V. Belov ◽  
A. V. Zubov ◽  
...  
Keyword(s):  

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