Intelligent Reversible Nanoporous Antireflection Film by Solvent-Stimuli-Responsive Phase Transformation of Amphiphilic Block Copolymer

Langmuir ◽  
2012 ◽  
Vol 28 (28) ◽  
pp. 10584-10591 ◽  
Author(s):  
Xiao Li ◽  
Xinhong Yu ◽  
Yanchun Han
Keyword(s):  
Phase Transformation ◽  
Block Copolymer ◽  
Amphiphilic Block Copolymer ◽  
Stimuli Responsive

scholarly journals Stimuli-Responsive Lyotropic Liquid Crystalline Nanosystems with Incorporated Poly(2-Dimethylamino Ethyl Methacrylate)-b-Poly(Lauryl Methacrylate) Amphiphilic Block Copolymer

Polymers ◽  
2019 ◽  
Vol 11 (9) ◽  
pp. 1400 ◽  
Author(s):  
Maria Chountoulesi ◽  
Natassa Pippa ◽  
Varvara Chrysostomou ◽  
Stergios Pispas ◽  
Evangelia D. Chrysina ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Liquid Crystalline ◽  
Polymer Concentration ◽  
Morphological Characteristics ◽  
Amphiphilic Block Copolymer ◽  
Poloxamer 407 ◽  
Stimuli Responsive ◽  
Ph Responsive ◽  
Ethyl Methacrylate ◽  
Liquid Crystalline Nanoparticles

There is an emerging need to evolve the conventional lyotropic liquid crystalline nanoparticles to advanced stimuli-responsive, therapeutic nanosystems with upgraded functionality. Towards this effort, typically used stabilizers, such as Pluronics®, can be combined or replaced by smart, stimuli-responsive block copolymers. The aim of this study is to incorporate the stimuli-responsive amphiphilic block copolymer poly(2-(dimethylamino)ethyl methacrylate)-b-poly(lauryl methacrylate) (PDMAEMA-b-PLMA) as a stabilizer in lipidic liquid crystalline nanoparticles, in order to provide steric stabilization and simultaneous stimuli-responsiveness. The physicochemical and morphological characteristics of the prepared nanosystems were investigated by light scattering techniques, cryogenic-transmission electron microscopy (cryo-TEM), X-ray diffraction (XRD) and fluorescence spectroscopy. The PDMAEMA-b-PLMA, either individually or combined with Poloxamer 407, exhibited different modes of stabilization depending on the lipid used. Due to the protonation ability of PDMAEMA blocks in acidic pH, the nanoparticles exhibited high positive charge, as well as pH-responsive charge conversion, which can be exploited towards pharmaceutical applications. The ionic strength, temperature and serum proteins influenced the physicochemical behavior of the nanoparticles, while the polymer concentration differentiated their morphology; their micropolarity and microfluidity were also evaluated. The proposed liquid crystalline nanosystems can be considered as novel and attractive pH-responsive drug and gene delivery nanocarriers due to their polycationic content.

scholarly journals Controlled nanogel and macrogel structures from self-assembly of a stimuli-responsive amphiphilic block copolymer

RSC Advances ◽  
2016 ◽  
Vol 6 (69) ◽  
pp. 64791-64798 ◽  
Author(s):  
JianCheng Liu ◽  
Christina Uhlir ◽  
Parag K. Shah ◽  
Fang Sun ◽  
Jeffrey W. Stansbury
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Raft Polymerization ◽  
Amphiphilic Block Copolymer ◽  
Stimuli Responsive

RAFT polymerization was utilized to prepare an amphiphilic block copolymer containing both hydrophilic and hydrophobic segments.

Copper-Coordination Induced Fabrication of Stimuli-Responsive Polymersomes from Amphiphilic Block Copolymer Containing Pendant Thioethers

2021 ◽  
Author(s):  
Shuqi Dong ◽  
Li Liu ◽  
Hanying Zhao
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Raft Polymerization ◽  
Amphiphilic Block Copolymers ◽  
Amphiphilic Block Copolymer ◽  
Stimuli Responsive ◽  
Copper Coordination

In this work, we synthesized oxidation-responsive amphiphilic block copolymers PEG45-b-P(MET/PBC)n bearing pendant phenylboronic ester carbamate (PBC) and thioether moieties in the hydrophobic block by RAFT polymerization and post-polymerization modification. As...

The Self-Assembly of an Amphiphilic Block Copolymer: A Dissipative Particle Dynamics Study

2005 ◽  
Vol 42 (3) ◽  
pp. 180-183 ◽  
Author(s):  
S. G. Schulz ◽  
U. Frieske ◽  
H. Kuhn ◽  
G. Schmid ◽  
F. Müller ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Self Assembly ◽  
Dissipative Particle Dynamics ◽  
Particle Dynamics ◽  
The Self ◽  
Amphiphilic Block Copolymer

β-lactam Functionalized Poly(isoprene-b-ethylene oxide) Amphiphilic Block Copolymer Micelles as a New Nanocarrier System for Curcumin

2010 ◽  
Vol 6 (3) ◽  
pp. 277-284 ◽  
Author(s):  
Konstantinos Gardikis ◽  
Konstantinos Dimas ◽  
Aristidis Georgopoulos ◽  
Eleni Kaditi ◽  
Stergios Pispas ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Ethylene Oxide ◽  
Amphiphilic Block Copolymer ◽  
Block Copolymer Micelles ◽  
Copolymer Micelles

Regioregular Poly(3-hexylthiophene) in a Novel Conducting Amphiphilic Block Copolymer

2009 ◽  
Vol 30 (1) ◽  
pp. 11-16 ◽  
Author(s):  
C. Rockford Craley ◽  
Rui Zhang ◽  
Tomasz Kowalewski ◽  
Richard D. McCullough ◽  
Mihaela C. Stefan
Keyword(s):  
Block Copolymer ◽  
Amphiphilic Block Copolymer ◽  
Regioregular Poly

Amphiphilic block copolymer-based photonic platform towards efficient protein detection

2016 ◽  
Author(s):  
Afroditi Petropoulou ◽  
Thomas J. Gibson ◽  
Efrosyni Themistou ◽  
Stergios Pispas ◽  
Christos Riziotis
Keyword(s):  
Block Copolymer ◽  
Protein Detection ◽  
Amphiphilic Block Copolymer

Synthesis and Porous SiO2 Nanofilm Formation of the Silsesquioxane-Containing Amphiphilic Block Copolymer

Langmuir ◽  
2018 ◽  
Vol 34 (27) ◽  
pp. 8007-8014 ◽  
Author(s):  
Yuya Ishizaki ◽  
Shunsuke Yamamoto ◽  
Tokuji Miyashita ◽  
Masaya Mitsuishi
Keyword(s):  
Block Copolymer ◽  
Amphiphilic Block Copolymer ◽  
Porous Sio2
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