Highly Active Platinum Nanoparticles on Graphene Nanosheets with a Significant Improvement in Stability and CO Tolerance

Langmuir ◽  
2012 ◽  
Vol 28 (8) ◽  
pp. 3979-3986 ◽  
Author(s):  
Daping He ◽  
Kun Cheng ◽  
Huaiguang Li ◽  
Tao Peng ◽  
Feng Xu ◽  
...  
Catalysts ◽  
2020 ◽  
Vol 10 (6) ◽  
pp. 597
Author(s):  
Martin González-Hernández ◽  
Ermete Antolini ◽  
Joelma Perez

Pt electrocatalysts supported on pristine graphene nanosheets (GNS) and nitrogen-doped graphene nanoplatelets (N-GNP) were prepared through the ethylene glycol process, and a comparison of their CO tolerance and stability as anode materials in polymer electrolyte membrane fuel cells (PEMFCs) with those of the conventional carbon (C)-supported Pt was made. Repetitive potential cycling in a half cell showed that Pt/GNS catalysts have the highest stability, in terms of the highest sintering resistance (lowest particle growth) and the lowest electrochemically active surface area loss. By tests in PEMFCs, the Pt/N-GNP catalyst showed the highest CO tolerance, while the poisoning resistance of Pt/GNS was lower than that of Pt/C. The higher CO tolerance of Pt/N-GNP than that of Pt/GNS was ascribed to the presence of a defect in graphene, generated by N-doping, decreasing CO adsorption energy.


2015 ◽  
Vol 3 (6) ◽  
pp. 2568-2571 ◽  
Author(s):  
Sanpei Zhang ◽  
Zhaoyin Wen ◽  
Kun Rui ◽  
Chen Shen ◽  
Yan Lu ◽  
...  

Graphene nanosheets loaded with highly dispersed platinum nanoparticles (Pt@GNSs) are prepared by a simple and effective hydrothermal method.


2019 ◽  
Vol 44 (59) ◽  
pp. 31506-31514 ◽  
Author(s):  
Jingnan Zheng ◽  
Kailu Huang ◽  
Guangya Hou ◽  
Huibin Zhang ◽  
Huazhen Cao

2017 ◽  
Vol 53 (20) ◽  
pp. 2962-2965 ◽  
Author(s):  
Thomas Galeandro-Diamant ◽  
Reine Sayah ◽  
Marie-Line Zanota ◽  
Sébastien Marrot ◽  
Laurent Veyre ◽  
...  

A catalyst containing platinum nanoparticles embedded into the walls of a mesostructured silica framework is highly active in alkene hydrosilylation and does not lead to Pt leaching.


2010 ◽  
Vol 153 (3-4) ◽  
pp. 189-192 ◽  
Author(s):  
Sayoko Shironita ◽  
Masahiko Goto ◽  
Takashi Kamegawa ◽  
Kohsuke Mori ◽  
Hiromi Yamashita

2008 ◽  
Vol 14 (19) ◽  
pp. 5988-5995 ◽  
Author(s):  
Juan M. Campelo ◽  
Adam F. Lee ◽  
Rafael Luque ◽  
Diego Luna ◽  
Jose M. Marinas ◽  
...  

2017 ◽  
Vol 242 ◽  
pp. 315-326 ◽  
Author(s):  
Petri Kanninen ◽  
Nguyen Dang Luong ◽  
Le Hoang Sinh ◽  
Jonathan Flórez-Montaño ◽  
Hua Jiang ◽  
...  

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