scholarly journals Arrested Chain Growth During Magnetic Directed Particle Assembly in Yield Stress Matrix Fluids

Langmuir ◽  
2012 ◽  
Vol 28 (8) ◽  
pp. 3683-3689 ◽  
Author(s):  
Jason P. Rich ◽  
Gareth H. McKinley ◽  
Patrick S. Doyle
Keyword(s):  
Yield Stress ◽  
Chain Growth ◽  
Particle Assembly ◽  
Stress Matrix

scholarly journals Magnetorheology in an aging, yield stress matrix fluid

2012 ◽  
Vol 51 (7) ◽  
pp. 579-593 ◽  
Author(s):  
Jason P. Rich ◽  
Patrick S. Doyle ◽  
Gareth H. McKinley
Keyword(s):  
Yield Stress ◽  
Stress Matrix

Carbon Chain Growth by Sequential Reactions of CO and CO2 with a Transition Metal Carbonyl Complex

2018 ◽  
Author(s):  
Richard Kong ◽  
Mark Crimmin
Keyword(s):  
Transition Metal ◽  
Metal Carbonyl ◽  
Carbon Chain ◽  
Chain Growth ◽  
Carbonyl Complex ◽  
Fischer Tropsch ◽  
Carbon Chains ◽  
Sequential Coupling ◽  
Energy Economy ◽  
Sequential Reactions

<i>The formation of carbon chains by the coupling of COx (X = 1 or 2) units on transition metals is a fundamental step relevant to Fischer-Tropsch catalysis. Fischer-Tropsch catalysis produces energy dense liquid hydrocarbons from synthesis gas (CO and H2) and has been a mainstay of the energy economy since its discovery nearly a century ago. Despite detailed studies aimed at elucidating the steps of catalysis, experimental evidence for chain growth (Cn to Cn+1 ; n > 2) from the reaction of CO with metal complexes is unprecedented. In this paper, we show that carbon chains can be grown from sequential reactions of CO or CO2 with a transition metal carbonyl complex. By exploiting the cooperative effect of transition and main group metals, we document the first example of chain propagation from sequential coupling of CO units (C1 to C3 to C4), along with the first example of incorporation of CO2 into the growing carbon chain.</i><br>

Polymer Chemistry

2004 ◽  
Keyword(s):  
Conducting Polymers ◽  
Liquid Crystalline ◽  
Polymer Chemistry ◽  
Chain Growth ◽  
Crystalline Polymers ◽  
Wide Range ◽  
Cyclic Oligomers ◽  
Step Growth

Polymer Chemistry: A Practical Approach in Chemistry has been designed for both chemists working in and new to the area of polymer synthesis. It contains detailed instructions for preparation of a wide-range of polymers by a wide variety of different techniques, and describes how this synthetic methodology can be applied to the development of new materials. It includes details of well-established techniques, e.g. chain-growth or step-growth processes together with more up-to-date examples using methods such as atom-transfer radical polymerization. Less well-known procedures are also included, e.g. electrochemical synthesis of conducting polymers and the preparation of liquid crystalline elastomers with highly ordered structures. Other topics covered include general polymerization methodology, controlled/"living" polymerization methods, the formation of cyclic oligomers during step-growth polymerization, the synthesis of conducting polymers based on heterocyclic compounds, dendrimers, the preparation of imprinted polymers and liquid crystalline polymers. The main bulk of the text is preceded by an introductory chapter detailing some of the techniques available to the scientist for the characterization of polymers, both in terms of their chemical composition and in terms of their properties as materials. The book is intended not only for the specialist in polymer chemistry, but also for the organic chemist with little experience who requires a practical introduction to the field.

Influence of initial water content and strain rate on remolded yield stress in marine clay

2021 ◽  
pp. 1-8
Author(s):  
Xiaobing Li ◽  
Jianpeng Chen ◽  
Xiuqing Hu ◽  
Hongtao Fu ◽  
Jun Wang ◽  
...  
Keyword(s):  
Strain Rate ◽  
Water Content ◽  
Yield Stress ◽  
Initial Water Content ◽  
Marine Clay ◽  
Initial Water

Changes in underflow solid fraction and yield stress in paste thickeners by circulation

2021 ◽  
Vol 28 (3) ◽  
pp. 349-357
Author(s):  
Hong Li ◽  
Ai-xiang Wu ◽  
Hong-Jiang Wang ◽  
Hui Chen ◽  
Liu-Hua Yang
Keyword(s):  
Yield Stress ◽  
Solid Fraction
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