scholarly journals Hydrogen-Bonding-Driven Self-Assembly of PEGylated Organosilica Nanoparticles with Poly(acrylic acid) in Aqueous Solutions and in Layer-by-Layer Deposition at Solid Surfaces

Langmuir ◽  
2011 ◽  
Vol 28 (1) ◽  
pp. 299-306 ◽  
Author(s):  
Galiya S. Irmukhametova ◽  
Brian J. Fraser ◽  
Joseph L. Keddie ◽  
Grigoriy A. Mun ◽  
Vitaliy V. Khutoryanskiy
Keyword(s):  
Hydrogen Bonding ◽  
Acrylic Acid ◽  
Aqueous Solutions ◽  
Self Assembly ◽  
Solid Surfaces ◽  
Layer By Layer ◽  
Layer Deposition ◽  
Poly Acrylic Acid

High conducting multilayer films from poly(acrylic acid) and graphite by layer-by-layer self-assembly

2009 ◽  
Vol 31 (1) ◽  
pp. 145-151 ◽  
Author(s):  
Qunwei Tang ◽  
Qinghua Li ◽  
Jianming Lin ◽  
Shijun Fan ◽  
De Hu ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Self Assembly ◽  
Multilayer Films ◽  
Layer By Layer ◽  
Poly Acrylic Acid

Poly(Acrylic Acid)-Ferric Hydroxide Photosensitive Self-Assembly Film

2010 ◽  
Vol 663-665 ◽  
pp. 252-255
Author(s):  
Xue Feng Li ◽  
Shao Xian Peng
Keyword(s):  
Acrylic Acid ◽  
Self Assembly ◽  
Ferric Hydroxide ◽  
Surface Friction ◽  
Cationic Polyelectrolyte ◽  
Layer By Layer ◽  
Covalent Bonds ◽  
Force Microscopy ◽  
Assembly Technique ◽  
Poly Acrylic Acid

A stable and high lubricant ultrathin film was fabricated by self-assembled procedure at room temperature. Thickness of the films was regularly increased with the layer-by-layer self-assembly process in which poly (acrylic acid)-ferric hydroxide (PAA-Fe(OH)3) sol as anion polyelectrolyte and photosensitive diazoresin (DR) as cationic polyelectrolyte. And the process which based on electrostatic attraction was verified by UV-vis measurement. Furthermore, the ionic bonds in the films converted to covalent bonds under UV irradiation. Finally, the surface morphology and microtribology of the films were investigated by atomic force microscopy (AFM) and friction force microscopy (FFM). The results indicate that the films are flat and uniform through the self-assembly technique and the surface friction coefficients maintain at a rather low value.

Conducting Film from Graphite Oxide Nanoplatelets and Poly(acrylic acid) by Layer-by-Layer Self-Assembly

Langmuir ◽  
2008 ◽  
Vol 24 (9) ◽  
pp. 4800-4805 ◽  
Author(s):  
Jihuai Wu ◽  
Qunwei Tang ◽  
Hui Sun ◽  
Jianming Lin ◽  
Haiyong Ao ◽  
...  
Keyword(s):  
Acrylic Acid ◽  
Graphite Oxide ◽  
Self Assembly ◽  
Layer By Layer ◽  
Conducting Film ◽  
Poly Acrylic Acid

Photoresponsive nanostructures of azobenzene-containing block copolymers at solid surfaces

2021 ◽  
Author(s):  
Shaodong Sun ◽  
Chenrui Yuan ◽  
Zhulu Xie ◽  
Wen-Cong Xu ◽  
Qijin Zhang ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Block Copolymers ◽  
Acrylic Acid ◽  
Self Assembly ◽  
The Self ◽  
Solid Surfaces ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

The self-assembly properties and photoresponsive behaviours of an azobenzene-containing block copolymer poly(acrylic acid-block-6-(4-(p-tolyldiazenyl)phenoxy)hexyl acrylate) (PAA-b-PAzo) are reported. As azobenzene has reversible trans–cis photoisomerization abilities, the trans PAA-b-PAzo solutions were converted...

Synthesis of poly(methyl methacrylate)-b-poly(acrylic acid) by DPE method

e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Dong Chen ◽  
Ruixue Liu ◽  
Zhifeng Fu ◽  
Yan Shi
Keyword(s):  
Molecular Weight ◽  
Acrylic Acid ◽  
Methyl Methacrylate ◽  
Diblock Copolymer ◽  
Self Assembly ◽  
Gel Permeation Chromatography ◽  
Amphiphilic Diblock Copolymer ◽  
Poly Methyl Methacrylate ◽  
Copolymer Poly ◽  
Poly Acrylic Acid

AbstractAmphiphilic diblock copolymer poly(methyl methacrylate)-b-poly(acrylic acid) (PMMA-b-PAA) was prepared by 1,1-diphenylethene (DPE) method. Firstly, free radical polymerization of methyl methacrylate was carried out with AIBN as initiator in the presence of DPE, giving a DPE-containing PMMA precursor with controlled molecular weight. tert-Butyl acrylate (tBA) was then polymerized in the presence of the PMMA precursor, and PMMA-b-PtBA diblock copolymer with controlled molecular weight was prepared. Finally, amphiphilic diblock copolymer PMMA-b-PAA was obtained by hydrolysis of PMMA-b-PtBA. The formation of PMMA-b-PAA was confirmed by 1H NMR spectrum and gel permeation chromatography. Transmission electron microscopy and dynamic light scattering were used to detect the self-assembly behavior of the amphiphilic diblock polymers in methanol.

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