Two-Dimensional Solvent-Mediated Phase Transformation in Lipid Membranes Induced by Sphingomyelinase

Langmuir ◽  
2011 ◽  
Vol 27 (16) ◽  
pp. 10050-10060 ◽  
Author(s):  
Ling Chao ◽  
Fei Chen ◽  
Klavs F. Jensen ◽  
T. Alan Hatton
2021 ◽  
Author(s):  
Dasith Liyanage ◽  
Suk-Chun Moon ◽  
Ajith S. Jayasekare ◽  
Abheek Basu ◽  
Madeleine Du Toit ◽  
...  

Abstract High-temperature laser-scanning confocal microscopy (HT-LSCM) has proven to be an excellent experimental technique through in-situ observations of high temperature phase transformation to study kinetics and morphology using thin disk steel specimens. A 1.0 kW halogen lamp, within the elliptical cavity of the HT-LSCM furnace radiates heat and imposes a non-linear temperature profile across the radius of the steel sample. This local temperature profile when exposed at the solid/liquid interface determines the kinetics of solidification and phase transformation morphology. A two-dimensional numerical heat transfer model for both isothermal and transient conditions is developed for a concentrically solidifying sample. The model can accommodate solid/liquid interface velocity as an input parameter under concentric solidification with cooling rates up to 100 K/min. The model is validated against a commercial finite element analysis software package, Strand7, and optimized with experimental data obtained under near-to equilibrium conditions. The validated model can then be used to define the temperature landscape under transient heat transfer conditions.


2018 ◽  
Vol 20 (46) ◽  
pp. 29462-29471 ◽  
Author(s):  
Jin Zhang

We report a novel phase transformation in 2D COFs under compression, which greatly alters the material properties of 2D COFs.


Author(s):  
Ting Geng ◽  
Shuai Wei ◽  
Wenya Zhao ◽  
Zhiwei Ma ◽  
Ruijing Fu ◽  
...  

Pressure-induced phase transformation and narrowed band gap of two-dimensional lead-free halide perovskite Cs3Bi2Br9 nanocrystals.


2019 ◽  
Vol 131 (30) ◽  
pp. 10336-10341
Author(s):  
Juna Bae ◽  
Magdalena O. Cichocka ◽  
Yi Zhang ◽  
Zoltán Bacsik ◽  
Sara Bals ◽  
...  

1995 ◽  
Vol 402 ◽  
Author(s):  
J. A. Kittl ◽  
D. A. Prinslow ◽  
P. P Apte ◽  
M. F. Pas

AbstractThe kinetics of the TiSi2 C49 to C54 phase transformation in thin films on patterned deepsub- micron lines, were studied to obtain the full time, temperature and linewidth dependence of the fraction transformed during rapid thermal annealing. A Johnson-Mehl-Avrami kinetic analysis was performed, obtaining Avrami exponents of 0.8±0.2 for all sub-micron lines and 1. 9±0.2 for a 40 μm side square structure, indicating heterogeneous nucleation followed by one dimensional growth for the narrow lines, and two dimensional growth for the square structure. The activation energy, of 3.9 eV, was independent of linewidth in the sub-micron range. Transformation times increased dramatically for decreasing linewidth, as the linewidth approached the grain size of the starting C49 phase. A kinetic model based on the density of nucleation sites as a function of linewidth and C49 grain size is proposed and shown to fit the data, for samples with two different C49 grain sizes.


1999 ◽  
Vol 14 (7) ◽  
pp. 2922-2928 ◽  
Author(s):  
Jau-Ho Jean ◽  
Shih-Chun Lin

The effects of borosilicate glass (BSG) on the kinetics and mechanism of anataseto- rutile phase transformation have been investigated. The displacive anatase-to-rutile phase transformation kinetics of TiO2 were greatly enhanced in the presence of BSG. The transformation kinetics followed the Avrami equation, and the results showed an apparent activation energy of 260–370 kJ/mol, which was close to the bond strength of Ti–O, suggesting a reaction-controlling mechanism. The values of the Avrami exponent were in the range of 1.4–2.3, which could be interpreted as two-dimensional reaction-controlled growth at zero nucleation rate. The rutile particles obtained by the phase transformation were always much larger than the starting anatase powders, which was explained by a mechanism of phase-transformation–induced particle coalescence.


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