Aggregation and Dissolution of 4 nm ZnO Nanoparticles in Aqueous Environments: Influence of pH, Ionic Strength, Size, and Adsorption of Humic Acid

Langmuir ◽  
2011 ◽  
Vol 27 (10) ◽  
pp. 6059-6068 ◽  
Author(s):  
Shao-Wei Bian ◽  
Imali A. Mudunkotuwa ◽  
Thilini Rupasinghe ◽  
Vicki H. Grassian
2013 ◽  
Vol 832 ◽  
pp. 728-733 ◽  
Author(s):  
Mohd Omar Fatehah ◽  
Hamidi Abdul Aziz ◽  
Serge Stoll

The surface charge and average size of ZnO was studied with a function of pH and time. The interactions between ZnO and Suwannee River humic acid (SRHA) were further investigated under a range of environmentally relevant conditions with the pHPZC as a point of reference. The anionic charge carried by aquatic humic substances plays a major part in the aggregation and disaggregation of metal oxide nanoparticles. At low concentrations of SRHA (<0.05 mg="" l="" the="" positively="" charged="" zno="" aggregates="" were="" rapidly="" adsorbed="" below="" ph="" sub="">PZC. With similar SRHA concentrations, at pH=pHPZC, SRHA was able to control the suspension behavior of the ZnO and promoted partial disaggregation in small volumes. This was more distinguishable as SRHA form a surface coating on the nanoparticles and enhances stability via electrostatic stabilization mechanism which induces the disaggregation behavior in the ZnO nanoparticles and hence, decreases the aggregate size.


2018 ◽  
Vol 316 (3) ◽  
pp. 981-991 ◽  
Author(s):  
Liqiang Tan ◽  
Xiaoli Tan ◽  
Xuemei Ren ◽  
Huiyang Mei ◽  
Xiangke Wang

2015 ◽  
Vol 57 (40) ◽  
pp. 18817-18824 ◽  
Author(s):  
Jing Lu ◽  
Dongmei Liu ◽  
Xiaonan Yang ◽  
Haixing Liu ◽  
Shiguang Liu ◽  
...  

Author(s):  
Yosep Han ◽  
Donghyun Kim ◽  
Gukhwa Hwang ◽  
Byoungcheun Lee ◽  
Igchun Eom ◽  
...  

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