scholarly journals Laser Ablation Direct Writing of Metal Nanoparticles for Hydrogen and Humidity Sensors

Langmuir ◽  
2011 ◽  
Vol 27 (3) ◽  
pp. 1241-1244 ◽  
Author(s):  
Michail J. Beliatis ◽  
Nicholas A. Martin ◽  
Edward J. Leming ◽  
S. Ravi P. Silva ◽  
Simon J. Henley
Chemosensors ◽  
2021 ◽  
Vol 9 (4) ◽  
pp. 77
Author(s):  
Davide Spanu ◽  
Gilberto Binda ◽  
Marcello Marelli ◽  
Laura Rampazzi ◽  
Sandro Recchia ◽  
...  

A laser ablation–inductively coupled plasma–mass spectrometry (LA–ICP–MS) based method is proposed for the quantitative determination of the spatial distribution of metal nanoparticles (NPs) supported on planar substrates. The surface is sampled using tailored ablation patterns and the data are used to define three-dimensional functions describing the spatial distribution of NPs. The volume integrals of such interpolated surfaces are calibrated to obtain the mass distribution of Ag NPs by correlation with the total mass of metal as determined by metal extraction and ICP–MS analysis. Once this mass calibration is carried out on a sacrificial sample, quantifications can be performed over multiple samples by a simple micro-destructive LA–ICP–MS analysis without requiring the extraction/dissolution of metal NPs. The proposed approach is here tested using a model sample consisting of a low-density polyethylene (LDPE) disk decorated with silver NPs, achieving high spatial resolution over cm2-sized samples and very high sensitivity. The developed method is accordingly a useful analytical tool for applications requiring both the total mass and the spatial distribution of metal NPs to be determined without damaging the sample surface (e.g., composite functional materials and NPs, decorated catalysts or electrodic materials).


1998 ◽  
Vol 10 (5) ◽  
pp. 853-863 ◽  
Author(s):  
M.F. Becker ◽  
J.R. Brock ◽  
Hong Cai ◽  
D.E. Henneke ◽  
J.W. Keto ◽  
...  

2003 ◽  
Vol 42 (31) ◽  
pp. 6349 ◽  
Author(s):  
Kris Naessens ◽  
Heidi Ottevaere ◽  
Roel Baets ◽  
Peter Van Daele ◽  
Hugo Thienpont

Langmuir ◽  
2010 ◽  
Vol 26 (10) ◽  
pp. 7458-7463 ◽  
Author(s):  
Ernesto Jiménez ◽  
Kamal Abderrafi ◽  
Rafael Abargues ◽  
José L. Valdés ◽  
Juan P. Martínez-Pastor

2011 ◽  
Vol 51 (3) ◽  
pp. 248-259 ◽  
Author(s):  
Vadimas Dudoitis ◽  
Vidmantas Ulevičius ◽  
Gediminas Račiukaitis ◽  
Narciza Špirkauskaitė ◽  
Kristina Plauškaitė

2010 ◽  
Vol 1247 ◽  
Author(s):  
Seung H. Ko ◽  
Dong Yeol Yang ◽  
Heng Pan ◽  
Jean M. Frechet ◽  
Yong Son ◽  
...  

AbstractAll-printed electronics is the key technology to ultra-low-cost, large-area electronics. As a critical step in this direction, we demonstrate that femtosecond laser processing (sintering and ablation) of solution deposited metal nanoparticles enables direct metal patterning at low-temperature with ultra high resolution (∼300nm) to overcome the resolution limitation of the current inkjet direct writing processes.This could be explained by the combined effects of novel properties of metal nanoparticles such as melting temperature drop, strong absorption of the incident laser beam at surface plasmon mode, lower conductive heat transfer loss, and the relatively weak bonding between nanoparticles. Local thermal control of the laser sintering process could minimize the heat-affected zone and the thermal damage to the substrate and further enhance the resolution of the process. This local nanoparticle deposition and energy coupling enable an environmentally friendly and cost-effective process as well as a low-temperature manufacturing sequence to realize large-area, flexible electronics on polymer substrates.


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