Contact Angles of Liquid Drops on Super Hydrophobic Surfaces: Understanding the Role of Flattening of Drops by Gravity

Langmuir ◽  
2010 ◽  
Vol 26 (22) ◽  
pp. 17090-17099 ◽  
Author(s):  
C. W. Extrand ◽  
Sung In Moon
Author(s):  
Rami Benkreif ◽  
Fatima Zohra Brahmia ◽  
Csilla Csiha

AbstractSurface tension of solid wood surfaces affects the wettability and thus the adhesion of various adhesives and wood coatings. By measuring the contact angle of the wood, the surface tension can be calculated based on the Young-Dupré equation. Several publications have reported on contact angle measured with different test liquids, under different conditions. Results can only be compared if the test conditions are similar. While the roles of the drop volume, image shooting time etc., are widely recognized, the role of the wood surface moisture content (MC) is not evaluated in detail. In this study, the effect of wood moisture content on contact angle values, measured with distilled water and diiodomethane, on sanded birch (Betula pendula) surfaces was investigated, in order to find the relationship between them. With increasing MC from approximately 6% to 30%, increasing contact angle (decreasing surface tension) values were measured according to a logarithmic function. The function makes possible the calculation of contact angles that correspond to different MCs.


2021 ◽  
Vol 12 (1) ◽  
Author(s):  
Qingzhe Liu ◽  
Jack Hau Yung Lo ◽  
Ye Li ◽  
Yuan Liu ◽  
Jinyu Zhao ◽  
...  

AbstractThe impact and splash of liquid drops on solid substrates are ubiquitous in many important fields. However, previous studies have mainly focused on spherical drops while the non-spherical situations, such as raindrops, charged drops, oscillating drops, and drops affected by electromagnetic field, remain largely unexplored. Using ferrofluid, we realize various drop shapes and illustrate the fundamental role of shape in impact and splash. Experiments show that different drop shapes produce large variations in spreading dynamics, splash onset, and splash amount. However, underlying all these variations we discover universal mechanisms across various drop shapes: the impact dynamics is governed by the superellipse model, the splash onset is triggered by the Kelvin-Helmholtz instability, and the amount of splash is determined by the energy dissipation before liquid taking off. Our study generalizes the drop impact research beyond the spherical geometry, and reveals the potential of using drop shape to control impact and splash.


2012 ◽  
Vol 562-564 ◽  
pp. 56-59 ◽  
Author(s):  
Jian Zhuang ◽  
Meng Meng Du ◽  
Heng Zhi Cai ◽  
Ya Jun Zhang ◽  
Da Ming Wu

A facile method for manufacturing super hydrophobic surfaces is presented using the stainless steel wire mesh as templates. The rough surfaces of polymers including polycarbonate, polypropylene and PMMA are prepared with hot embossing on different specifications of stainless steel wire mesh. Scanning electron microscopy (SEM) results reveal that the surfaces roughness of the polymers can be controlled by selecting templates. Contact angle measurement shows that the water contact angles(WCA) rise with the increase of surface roughness, especially, the water contact angle on the PC surfaces prepared with specifications of 635mesh screen can reach to 152.3°, alias super hydrophobic surfaces.


Author(s):  
Y. Y. Yan

A micro/meso scale modelling of two-phase droplets move on hydrophilic/hydrophobic surfaces with micro roughness is reported. The physical model is basically of two-phase flow interacting with the surfaces of different hydrophobicity or wettability. Numerical modelling based on the lattice Boltzmann method (LBM) is developed and applied to the computational calculation and simulation. The LBM modelling deals with surface tension dominated behaviour of water droplets in air spreading on a hydrophilic surface with hydrophobic strips of different sizes and contact angles under different physical and interfacial conditions, and aims to find quantitative data and physical conditions of the biomimetic approaches. The current LBM can be applied to simulate two-phase fluids with large density ratio (up to 1000), and meanwhile deal with interactions between a fluid-fluid interface and a partial wetting wall. In the simulation, the interactions between the fluid-fluid interface and the partial wetting wall with different hydrophobic strips such as single strip, intersecting stripes, and alternating & parallel stripes, of different sizes and contact angles are considered and tested numerically; the phenomena of droplets spreading and breaking up, and the effect of hydrophobic strips on the surface wettability or self-cleaning characteristics are simulated, reported and discussed.


1973 ◽  
Vol 59 (4) ◽  
pp. 753-767 ◽  
Author(s):  
E. Pitts

We consider a drop of liquid hanging from a horizontal support and sandwiched between two vertical plates separated by a very narrow gap. Equilibrium profiles of such ‘two-dimensional’ drops were calculated by Neumann (1894) for the case when the angle of contact between the liquid and the horizontal support is zero. This paper gives the equilibrium profiles for other contact angles and the criterion for their stability. Neumann showed that, as the drop height increases, its cross-sectional area increases until a maximum is reached. Thereafter, as the height increases, the equilibrium area decreases. This behaviour is shown to be typical of all contact angles. When the maximum area is reached, the total energy is a minimum. It is shown that the drops are stable as long as the height and the area increase together.


2009 ◽  
Vol 131 (8) ◽  
Author(s):  
R. Shukla ◽  
K. A. Sallam

An experimental investigation of the role of liquid transparency in controlling laser-induced motion of liquid drops is carried out. The study was motivated by application to manipulation of liquid drops over a solid substrate. Droplets with diameters of 1–4 mm were propelled on a hydrophobic substrate using a pulsed-laser beam (532 nm, 10 Hz, 3–12 mJ/pulse) with a 0.9 mm diameter fired parallel to the substrate. The test liquid was distilled water whose transparency was varied by adding different concentrations of Rhodamine 6G dye. Motion of the drops was observed using a video camera. Measurements include direction of motion and the distance traveled before the drops come to rest. The present results show that the direction of the motion depends on the drop transparency; opaque drops moved away from the laser beam, whereas transparent drops moved at small angles toward the laser beam. The motion of both transparent and opaque drops was dominated by thermal Marangoni effect; the motion of opaque drops was due to direct heating by the laser beam, whereas in the case of transparent drops, the laser beam was focused near the rear face of the transparent drops to form a spark that pushed the drops in the opposite direction. Energies lower than 3 mJ were incapable of moving the drops, and energies higher than 12 mJ shattered the drops instead of moving them. A phenomenological model was developed for the drop motion to explain the physics behind the phenomenon.


2011 ◽  
Vol 9 (67) ◽  
pp. 313-327 ◽  
Author(s):  
Yang Shen ◽  
Guixue Wang ◽  
Xianliang Huang ◽  
Qin Zhang ◽  
Jiang Wu ◽  
...  

Vascular endothelial cell (EC) adhesion and migration are essential processes in re-endothelialization of implanted biomaterials. There is no clear relationship and mechanism between EC adhesion and migration behaviour on surfaces with varying wettabilities. As model substrates, plasma SiO x :H nanocoatings with well-controlled surface wettability (with water contact angles in the range of 98.5 ± 2.3° to 26.3 ± 4.0°) were used in this study to investigate the effects of surface wettability on cell adhesion/migration and associated protein expressions in FAK-Rho GTPases signalling pathways. It was found that EC adhesion/migration showed opposite behaviour on the hydrophilic and hydrophobic surfaces (i.e. hydrophobic surfaces promoted EC migration but were anti-adhesions). The number of adherent ECs showed a maximum on hydrophilic surfaces, while cells adhered to hydrophobic surfaces exhibited a tendency for cell migration. The focal adhesion kinase (FAK) inhibitor targeting the Y-397 site of FAK could significantly inhibit cell adhesion/migration, suggesting that EC adhesion and migration on surfaces with different wettabilities involve ( p )FAK and its downstream signalling pathways. Western blot results suggested that the FAK-Rho GTPases signalling pathways were correlative to EC migration on hydrophobic plasma SiO x :H surfaces, but uncertain to hydrophilic surfaces. This work demonstrated that surface wettability could induce cellular behaviours that were associated with different cellular signalling events.


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