Effect of Sequential Layer-by-Layer Surface Modifications on the Surface Energy of Plasma-Modified Poly(dimethylsiloxane)

Langmuir ◽  
2007 ◽  
Vol 23 (2) ◽  
pp. 667-672 ◽  
Author(s):  
Woo-Sung Bae ◽  
Anthony J. Convertine ◽  
Charles L. McCormick ◽  
Marek W. Urban
2019 ◽  
Vol 413 ◽  
pp. 182-190 ◽  
Author(s):  
Saidatul Sophia Sha'rani ◽  
Ebrahim Abouzari-Lotf ◽  
Mohamed Mahmoud Nasef ◽  
Arshad Ahmad ◽  
Teo Ming Ting ◽  
...  

Langmuir ◽  
2014 ◽  
Vol 30 (19) ◽  
pp. 5545-5556 ◽  
Author(s):  
Luis Escobar-Ferrand ◽  
Diya Li ◽  
Daeyeon Lee ◽  
Christopher J. Durning

2015 ◽  
Vol 493 ◽  
pp. 807-819 ◽  
Author(s):  
Papatya Kaner ◽  
Daniel J. Johnson ◽  
Erol Seker ◽  
Nidal Hilal ◽  
Sacide Alsoy Altinkaya

1993 ◽  
Vol 318 ◽  
Author(s):  
Michael A. Grinfeld

ABSTRACTWe study possible morphologies of epitaxial films atop attractive substrates appearing as a result of competition of misfit stresses, van der Waals forces and surface energy. Corresponding formula for the critical thickness of the dislocation-free Stranski-Krastanov pattern is established for the isotropic deformable films and substrates. If the film thickness exceeds the critical magnitude the layer-by-layer pattern switches to islanding. At the first stage the islands have a shape of striae (i.e. long parallel trenches with periodic spacing). We discuss also i)the circumstances in which surface morphology of the film corresponds to a two-dimensional superlattice of islands rather than a one dimensional lattice of striae and ii)the influence of a buffer inter-layer.


Membranes ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 160 ◽  
Author(s):  
Francis Kotoka ◽  
Ivan Merino-Garcia ◽  
Svetlozar Velizarov

Reverse electrodialysis (RED) technology represents a promising electro-membrane process for renewable energy harvesting from aqueous streams with different salinity. However, the performance of the key components of the system, that is, the ion exchange membranes, is limited by both the presence of multivalent ions and fouling phenomena, thus leading to a reduced generated net power density. In this context, the behavior of anion exchange membranes (AEMs) in RED systems is more severely affected, due to the undesirable interactions between their positively charged fixed groups and, mostly negatively charged, foulant materials present in natural streams. Therefore, controlling both the monovalent anion permselectivity and the membrane surface hydrophilicity is crucial. In this respect, different surface modification procedures were considered in the literature, to enhance the above-mentioned properties. This review reports and discusses the currently available approaches for surface modifications of AEMs, such as graft polymerization, dip coating, and layer-by-layer, among others, mainly focusing on preparing monovalent permselective AEMs with antifouling characteristics, but also considering hydrophilicity aspects and identifying the most promising modifying agents to be utilized. Thus, the present study aimed at providing new insights for the further design and development of selective, durable, and cost-effective modified AEMs for an enhanced RED process performance, which is indispensable for a practical implementation of this electro-membrane technology at an industrial scale.


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