Selective Degradation of Chemical Bonds:  from Single-Source Molecular Precursors to Metallic Ag and Semiconducting Ag2S Nanocrystals via Instant Thermal Activation

Langmuir ◽  
2006 ◽  
Vol 22 (6) ◽  
pp. 2802-2805 ◽  
Author(s):  
Qun Tang ◽  
Seok Min Yoon ◽  
Hyun Jin Yang ◽  
Yoonmi Lee ◽  
Hyun Jae Song ◽  
...  
Keyword(s):  
Thermal Activation ◽  
Chemical Bonds ◽  
Single Source ◽  
Molecular Precursors ◽  
Selective Degradation

Thorium amidates function as single-source molecular precursors for thorium dioxide

2021 ◽  
Author(s):  
Mark D. Straub ◽  
Erik T. Ouellette ◽  
Michael A. Boreen ◽  
Jacob A. Branson ◽  
Alex Ditter ◽  
...  
Keyword(s):  
Thermal Properties ◽  
Single Source ◽  
Thorium Dioxide ◽  
Molecular Precursors

Volatile thorium amidates can be converted to ThO2 in the absence of an external oxygen source, and the thermal properties of these precursors can be readily tuned by modifying the ligand substituents.

On-Particle EDS Analysis of Bimetallic, Carbon-Supported Catalysts

1999 ◽  
Vol 589 ◽  
Author(s):  
Deborah L. Boxall ◽  
Edward A. Kenik ◽  
Charles M. Lukehart
Keyword(s):  
Elemental Analysis ◽  
Energy Dispersive Spectroscopy ◽  
High Spatial Resolution ◽  
Supported Catalysts ◽  
Alloy Nanoparticles ◽  
Single Source ◽  
Volatile Species ◽  
Molecular Precursors ◽  
Eds Analysis ◽  
Compositional Variability

AbstractThermolysis of single-source molecular precursors has been used to prepare carbon-supported Pt1Sn1, Pt1Ru1, and Pt3Mo1 alloy nanoparticles. On-particle, high spatial resolution energy dispersive spectroscopy (HR-EDS) has been used to determine the extent of compositional variability between particles in the nanocomposite. The loss of volatile Ru and Mo oxides during the course of the HR-EDS analysis results in average compositions greatly enriched in Pt. Mathematical correction for loss of these volatile species results in average metal:metal ratios comparable to those measured by bulk elemental analysis.

Facile Access to Amides from Oxygenated or Unsaturated Organic Compounds by Metal Oxide Nanocatalysts Derived from Single-Source Molecular Precursors

2017 ◽  
Vol 56 (17) ◽  
pp. 10596-10608 ◽  
Author(s):  
Akbar Mohammad ◽  
Prakash Chandra ◽  
Topi Ghosh ◽  
Mauro Carraro ◽  
Shaikh M. Mobin
Keyword(s):  
Metal Oxide ◽  
Organic Compounds ◽  
Single Source ◽  
Molecular Precursors

Boron nitride ceramics from molecular precursors: synthesis, properties and applications

2016 ◽  
Vol 45 (3) ◽  
pp. 861-873 ◽  
Author(s):  
Samuel Bernard ◽  
Chrystelle Salameh ◽  
Philippe Miele
Keyword(s):  
Boron Nitride ◽  
Hexagonal Boron Nitride ◽  
Single Source ◽  
Single Source Precursors ◽  
Molecular Precursors ◽  
Nitride Ceramics ◽  
Synthesis Properties

Hexagonal boron nitride (h-BN) attracts considerable interest particularly when it is prepared from borazine-based single-source precursors through chemical routes suitable for the shaping and the nanostructuration of the final ceramic.

scholarly journals Synthesis of nanostructured powders and thin films of iron sulfide from molecular precursors

RSC Advances ◽  
2018 ◽  
Vol 8 (51) ◽  
pp. 29096-29103 ◽  
Author(s):  
Laila Almanqur ◽  
Inigo Vitorica-yrezabal ◽  
George Whitehead ◽  
David J. Lewis ◽  
Paul O'Brien
Keyword(s):  
Thin Films ◽  
Solid State ◽  
Spin Coating ◽  
Iron Sulfide ◽  
Single Source ◽  
Single Source Precursors ◽  
Molecular Precursors ◽  
Nanostructured Powders

Iron(iii) xanthate single-source precursors were used to deposit iron sulfide thin films and nanostructures by spin coating and solid state deposition.

Synthesis and Characterization of Cadmium Chalcogenide Nanomaterial (CdE; E=Se/Te) from Novel Single Source Molecular Precursor

2018 ◽  
Vol 14 (2) ◽  
pp. 160-168 ◽  
Author(s):  
Arunendera Kumar Tiwari ◽  
Tripti A. Jain ◽  
Sonal Choubey ◽  
Parmendra Kumar Bajpai
Keyword(s):  
Average Particle Size ◽  
Average Particle ◽  
Single Source ◽  
X Ray Diffraction ◽  
Metal Chalcogenide ◽  
Molecular Precursors ◽  
Molecular Precursor ◽  
Cadmium Chalcogenide ◽  
Visible Spectra

Background: Metal chalcogenide nanomaterials represent an important group of efficient materials, in which the subtle variations in shape, size and phase of nano-powders resulted in physical properties (e.g., electronic and optical) differing from their bulk counterparts, which makes them useful materials for various technological devices. Objective: Synthesis and growth of chalcogenide nano powders from novel single source molecular precursors (i.e., Cd(II) bis-(aminopropane) selenide, Cd(II) bis-(aminoethane) telluride) for the production of cadmium chalcogenide (CdE, E= Se/Te) at nano scale. Method: Single source molecular precursor inserted in quinoline, acting as a coordinating solvent at suitable temperature, yielded vacuum dried powders of CdSe and CdTe nanomaterials. Results: The average particle size was estimated as CdSe ≈ 3 nm, and CdTe ≈ 29 nm from powder X-ray diffraction pattern of synthesized nanoparticles. The produced nanomaterials possess optical properties and calculated energy band gap of nanoparticles as CdTe = 5.2 eV and CdSe = 4.0 eV from UV-Visible spectra. Conclusion: The economical, harmless single source molecular method may be a striking technique to fabricate metal chalcogenide nanoparticles.

ChemInform Abstract: Synthesis of Fe2-xMnxP Nanoparticles from Single-Source Molecular Precursors.

ChemInform ◽  
2011 ◽  
Vol 42 (44) ◽  
pp. no-no
Author(s):  
Adam C. Colson ◽  
Kenton H. Whitmire
Keyword(s):  
Single Source ◽  
Molecular Precursors
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