Supramolecular Assemblies with Tunable Morphologies from Homopolymeric and Small Organic Molecular Building Blocks

Langmuir ◽  
2006 ◽  
Vol 22 (13) ◽  
pp. 5525-5527 ◽  
Author(s):  
Huisheng Peng ◽  
Yunfeng Lu
Keyword(s):  
Building Blocks ◽  
Supramolecular Assemblies ◽  
Molecular Building Blocks

scholarly journals Supramolecular Chemistry and Self-Organization: A Veritable Playground for Catalysis

Catalysts ◽  
2019 ◽  
Vol 9 (2) ◽  
pp. 163 ◽  
Author(s):  
Loïc Leclercq ◽  
Grégory Douyère ◽  
Véronique Nardello-Rataj
Keyword(s):  
Supramolecular Chemistry ◽  
Intermolecular Interactions ◽  
Noncovalent Interactions ◽  
Directed Assembly ◽  
Building Blocks ◽  
Reaction Rates ◽  
Supramolecular Assemblies ◽  
Self Organization ◽  
Catalytic Systems ◽  
Molecular Building Blocks

The directed assembly of molecular building blocks into discrete supermolecules or extended supramolecular networks through noncovalent intermolecular interactions is an ongoing challenge in chemistry. This challenge may be overcome by establishing a hierarchy of intermolecular interactions that, in turn, may facilitate the edification of supramolecular assemblies. As noncovalent interactions can be used to accelerate the reaction rates and/or to increase their selectivity, the development of efficient and practical catalytic systems, using supramolecular chemistry, has been achieved during the last few decades. However, between discrete and extended supramolecular assemblies, the newly developed “colloidal tectonics” concept allows us to link the molecular and macroscopic scales through the structured engineering of colloidal structures that can be applied to the design of predictable, versatile, and switchable catalytic systems. The main cutting-edge strategies involving supramolecular chemistry and self-organization in catalysis will be discussed and compared in this review.

A First Principles Approach for Partitioning Linear Response Properties into Additive and Cooperative Contributions

2018 ◽  
Author(s):  
Daniel Lambrecht ◽  
Eric Berquist
Keyword(s):  
First Principles ◽  
Linear Response ◽  
Building Blocks ◽  
Field Method ◽  
Response Property ◽  
Response Properties ◽  
Consistent Field ◽  
Molecular Building Blocks ◽  
Self Consistent ◽  
Self Consistent Field

We present a first principles approach for decomposing molecular linear response properties into orthogonal (additive) plus non-orthogonal/cooperative contributions. This approach enables one to 1) identify the contributions of molecular building blocks like functional groups or monomer units to a given response property and 2) quantify cooperativity between these contributions. In analogy to the self consistent field method for molecular interactions, SCF(MI), we term our approach LR(MI). The theory, implementation and pilot data are described in detail in the manuscript and supporting information.

A new molecular building blocks: Synthesis, crystal structure, magnetic and spectroscopic properties of Cu(II) and Ni(II) macrocyclic complexes

Polyhedron ◽  
2011 ◽  
Vol 30 (15) ◽  
pp. 2550-2557 ◽  
Author(s):  
Katarzyna Suracka ◽  
Alina Bieńko ◽  
Jerzy Mroziński ◽  
Rafał Kruszyński ◽  
Dariusz Bieńko ◽  
...  
Keyword(s):  
Crystal Structure ◽  
Building Blocks ◽  
Spectroscopic Properties ◽  
Macrocyclic Complexes ◽  
Molecular Building Blocks

scholarly journals Acid-Catalysed Liquid-to-Solid Transitioning of Arylazoisoxazole Photoswitches

2021 ◽  
Author(s):  
Luuk Kortekaas ◽  
Julian Simke ◽  
Niklas Arndt ◽  
Marcus Böckmann ◽  
Nikos Doltsinis ◽  
...  
Keyword(s):  
Building Blocks ◽  
Vital Role ◽  
Responsive Materials ◽  
Molecular Building Blocks ◽  
Physical Changes

Molecular photoswitches play a vital role in the development of responsive materials. These molecular building blocks are particularly attractive when multiple stimuli can be combined to bring about physical changes,...

2,2':6',2''-Terpyridine metal complexes as building blocks for extended functional metallo-supramolecular assemblies and polymers

2001 ◽  
Vol 121 (1-3) ◽  
pp. 1249-1252 ◽  
Author(s):  
U.S. Schubert ◽  
C. Eschbaumer ◽  
P. Andres ◽  
H. Hofmeier ◽  
C.H. Weidl ◽  
...  
Keyword(s):  
Metal Complexes ◽  
Building Blocks ◽  
Supramolecular Assemblies

Novel water soluble cationic Au(I) complexes with cyclic PNNP ligand as building blocks for heterometallic supramolecular assemblies with anionic hexarhenium cluster units

2018 ◽  
Vol 196 ◽  
pp. 485-491 ◽  
Author(s):  
Julia Elistratova ◽  
Igor Strelnik ◽  
Konstantin Brylev ◽  
Michael A. Shestopalov ◽  
Tatiana Gerasimova ◽  
...  
Keyword(s):  
Building Blocks ◽  
Supramolecular Assemblies ◽  
Water Soluble

A Molecular Artisans Guide to Supramolecular Coordination Complexes and Metal Organic Frameworks

2015 ◽  
Vol 03 (01n02) ◽  
pp. 1540004 ◽  
Author(s):  
Xialu Wu ◽  
David J. Young ◽  
T. S. Andy Hor
Keyword(s):  
Chemical Reactivity ◽  
Metal Organic Frameworks ◽  
Building Blocks ◽  
Coordination Complexes ◽  
Large Molecules ◽  
Molecular Building Blocks ◽  
Supramolecular Coordination ◽  
Metal Organic ◽  
Molecular Synthesis ◽  
And Function

As molecular synthesis advances, we are beginning to learn control of not only the chemical reactivity (and function) of molecules, but also of their interactions with other molecules. It is this basic idea that has led to the current explosion of supramolecular science and engineering. Parallel to this development, chemists have been actively pursuing the design of very large molecules using basic molecular building blocks. Herein, we review the general development of supramolecular chemistry and particularly of two new branches: supramolecular coordination complexes (SCCs) and metal organic frameworks (MOFs). These two fields are discussed in detail with typical examples to illustrate what is now possible and what challenges lie ahead for tomorrow's molecular artisans.

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