Stepwise Self-Assembly of Ordered Supramolecular Assemblies Based on Coordination Chemistry

Langmuir ◽  
2006 ◽  
Vol 22 (5) ◽  
pp. 2082-2089 ◽  
Author(s):  
Daniel R. Blasini ◽  
Samuel Flores-Torres ◽  
Detlef-M. Smilgies ◽  
Héctor D. Abruña
Keyword(s):  
Coordination Chemistry ◽  
Self Assembly ◽  
Supramolecular Assemblies

Estimating the shape and size of supramolecular assemblies by variable temperature diffusion ordered spectroscopy

2014 ◽  
Vol 12 (40) ◽  
pp. 7932-7936 ◽  
Author(s):  
Benjamin M. Schulze ◽  
Davita L. Watkins ◽  
Jing Zhang ◽  
Ion Ghiviriga ◽  
Ronald K. Castellano
Keyword(s):  
Self Assembly ◽  
Variable Temperature ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Conjugated Oligomers ◽  
Photovoltaic Devices ◽  
Temperature Diffusion ◽  
Shape And Size

Reported is characterization of the self-assembly of π-conjugated oligomers, molecules studied recently in photovoltaic devices, using variable temperature diffusion ordered spectroscopy; the approach has allowed estimation of assembly size, shape, and molecularity.

scholarly journals Supramolecular assemblies of organo-functionalised hybrid polyoxometalates: from functional building blocks to hierarchical nanomaterials

2022 ◽  
Author(s):  
Jamie M. Cameron ◽  
Geoffroy Guillemot ◽  
Theodor Galambos ◽  
Sharad S. Amin ◽  
Elizabeth Hampson ◽  
...  
Keyword(s):  
Self Assembly ◽  
Building Blocks ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Supramolecular Materials ◽  
Inorganic Hybrid ◽  
Hierarchical Nanomaterials

Organic–inorganic hybrid polyoxometalates are versatile building blocks for the self-assembly of functional supramolecular materials.

scholarly journals Influence of the hydrophobic domain on the self-assembly and hydrogen bonding of hydroxy-amphiphiles

2019 ◽  
Vol 21 (21) ◽  
pp. 11242-11258
Author(s):  
Valery Andrushchenko ◽  
Walter Pohle
Keyword(s):  
Hydrogen Bonding ◽  
Ir Spectroscopy ◽  
Self Assembly ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Hydrophobic Domain

IR spectroscopy paired with calculations reveals that structurally similar amphiphiles ODA and DOG form very different supramolecular assemblies.

Understanding the properties of dithienylethenes functionalized for supramolecular self-assembly: a molecular modeling study

2020 ◽  
Vol 22 (13) ◽  
pp. 6942-6952 ◽  
Author(s):  
Laura Le Bras ◽  
Roxanne Berthin ◽  
Ismaïl Hamdi ◽  
Maroua Louati ◽  
Stéphane Aloïse ◽  
...  
Keyword(s):  
Molecular Dynamics ◽  
Molecular Modeling ◽  
Dft Calculations ◽  
Self Assembly ◽  
Supramolecular Assemblies ◽  
Molecular Modeling Study ◽  
Td Dft ◽  
Modeling Study

The behaviour of light-responsive supramolecular assemblies is rationalized with the help of molecular dynamics and TD-DFT calculations.

Intermolecular interactions in dictating the self-assembly of halogen derivatives of bis-(N-substituted oxamato)palladate(ii) complexes

RSC Advances ◽  
2016 ◽  
Vol 6 (8) ◽  
pp. 6164-6170 ◽  
Author(s):  
Francisco Ramón Fortea-Pérez ◽  
Nadia Marino ◽  
Giovanni de Munno ◽  
Donatella Armentano ◽  
Miguel Julve ◽  
...  
Keyword(s):  
Hydrogen Bonds ◽  
Intermolecular Interactions ◽  
Self Assembly ◽  
Supramolecular Assemblies ◽  
The Self ◽  
Derivatives Of

The reaction of aqueous [PdCl4]2−withN-4-Xphenyloxamate ligands (X = F, Cl, Br) afforded three non-isostructural compounds exhibiting intriguing diverse supramolecular assemblies driven by hydrogen bonds and/or halogen⋯halogen interactions.

Synthese und Koordinationschemie eines neuartigen Bistetrazols: Ein 1D-Metallopolymer durch Selbstorganisation koordinativ ungesättigter Zink(II)-M4onomere [1] / Synthesis and Coordination Chemistry of a New Bistetrazole: A 1D-Metallopolymer via Self-Assembly of Monomeric Zinc(II)-Buildingblocks

1995 ◽  
Vol 50 (4) ◽  
pp. 642-648 ◽  
Author(s):  
Rolf W. Saalfrank ◽  
Klaus Schobert ◽  
Stefan Trümmer ◽  
Alexander Wolski
Keyword(s):  
Coordination Chemistry ◽  
Self Assembly ◽  
Intermediate Formation ◽  
The Self ◽  
Polymeric Chain ◽  
X Ray Diffraction ◽  
Bridging Ligands ◽  
Subsequent Formation ◽  
X Ray ◽  
Polymeric Compounds

The new bistetrazole 13 has been obtained by subsequent formation of the two heterocyclic units. In methanolic solution 13 reacts with zinc(II) acetate to yield the pseudo-meso-1 D-coordination polymer [ZnL2(MeOH)]n (n = ∞) 14. The structure of 14 was established by single crystal X-ray diffraction. The generation of the polymeric chain 14 is understandable, if intermediate formation of coordinatively unsaturated zinc(II) buildingblocks (Δ)-15 and (Λ)-15 is assumed. Alternating linkage of the self-complementary chiral monomers 15, across one cyanofunction each, leads to 14 with zinc being essentially octahedrally coordinated. Compared with polymeric compounds of similar bridging ligands, the Zn ··· N≡C-distance in 14 (225,7 pm) is short.

Multi-stimuli responsive fabrication of supramolecular assemblies using ionic self-assembly approach

2019 ◽  
Vol 286 ◽  
pp. 110861 ◽  
Author(s):  
Rupam Dutta ◽  
Sourav Sil ◽  
Sangita Kundu ◽  
Sourav Nandi ◽  
Nilmoni Sarkar
Keyword(s):  
Self Assembly ◽  
Supramolecular Assemblies ◽  
Stimuli Responsive

Synthesis of new lamellar materials by self-assembly and coordination chemistry in the solids

2008 ◽  
Vol 46 (3) ◽  
pp. 383-392 ◽  
Author(s):  
Johan Alauzun ◽  
Ahmad Mehdi ◽  
Rola Mouawia ◽  
Catherine Reyé ◽  
Robert J. P. Corriu
Keyword(s):  
Coordination Chemistry ◽  
Self Assembly ◽  
Lamellar Materials
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