Polymerizable Bis(2-ethylhexyl)sulfosuccinate:  Application in Microemulsion Polymerization

John Texter; Liehui Ge; Thomas H. Mourey; Trevor G. Bryan

doi:10.1021/la0489357

Modeling inverse microemulsion polymerization

Journal of Polymer Science Part A Polymer Chemistry ◽

10.1002/(sici)1099-0518(19990701)37:13<2167::aid-pola32>3.0.co;2-6 ◽

1999 ◽

Vol 37 (13) ◽

pp. 2167-2178 ◽

Cited By ~ 7

Author(s):

Alberto S�enz De Buruaga ◽

Jose C. De La Cal ◽

Jose M. Asua

Keyword(s):

Microemulsion Polymerization ◽

Inverse Microemulsion ◽

Inverse Microemulsion Polymerization

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Preparation of poly(methyl methacrylate)-Silica nanoparticles via differential microemulsion polymerization and physical properties of NR/PMMA-SiO2 hybrid membranes

Polymer Engineering & Science ◽

10.1002/pen.24611 ◽

2017 ◽

Vol 58 (5) ◽

pp. 759-766 ◽

Cited By ~ 3

Author(s):

Dusadee Tumnantong ◽

Garry L. Rempel ◽

Pattarapan Prasassarakich

Keyword(s):

Methyl Methacrylate ◽

Physical Properties ◽

Silica Nanoparticles ◽

Hybrid Membranes ◽

Microemulsion Polymerization ◽

Poly Methyl Methacrylate

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Microemulsion polymerization of styrene in the presence of anionic emulsifier

Advances in Colloid and Interface Science ◽

10.1016/s0001-8686(99)00020-2 ◽

1999 ◽

Vol 82 (1-3) ◽

pp. 253-273 ◽

Cited By ~ 41

Author(s):

Ignác Capek

Keyword(s):

Microemulsion Polymerization

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Microemulsion polymerization of styrene in the presence of macroinimer

Polymer ◽

10.1016/s0032-3861(03)00096-x ◽

2003 ◽

Vol 44 (8) ◽

pp. 2193-2200 ◽

Cited By ~ 20

Author(s):

Ufuk Yildiz ◽

Ignac Capek

Keyword(s):

Microemulsion Polymerization

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Preparation of a monodisperse poly (N-phenylmaleimide–acrylonitrile–styrene) structural nanolatex for heat-resistant modification of PVC

Journal of Thermoplastic Composite Materials ◽

10.1177/0892705718780976 ◽

2018 ◽

Vol 32 (3) ◽

pp. 409-423

Author(s):

Jin Wang ◽

Hua Qiu ◽

Bo Cheng ◽

Fan Zhang ◽

Shuhua Qi

Keyword(s):

Electron Microscope ◽

Elemental Analysis ◽

Hybrid Composite ◽

Average Diameter ◽

Microemulsion Polymerization ◽

Scanning Calorimetry ◽

Thermogravimetric Analyzer ◽

Melt Compounding ◽

Transmission Electron ◽

Ftir Spectrometer

A monodisperse poly ( N-phenylmaleimide–acrylonitrile–styrene) (PNAS) nanolatex was synthesized via seed microemulsion polymerization. The obtained PNAS nanolatex was then directly used as an organic nanofiller to prepare polyvinyl chloride (PVC)/PNAS hybrid composite through water blending and melt compounding. The characteristics of PNAS nanolatex were analyzed by Fourier transform infrared (FTIR) spectrometer, elemental analysis, scanning electron microscope, transmission electron microscope (TEM), dynamic laser lighting scattering (DLS), differential scanning calorimetry (DSC), and thermogravimetric analyzer (TGA). FTIR and elemental analysis confirmed the formation of PNAS copolymer with high monomers conversion; meanwhile, for the PNAS nanoparticles, the morphology of a well-defined core–shell spherical structure with average diameter ranging from 156 nm to 249 nm was observed. DSC analysis and TGA indicated that both polymers had excellent compatibility, and the corresponding heat resistance of PVC was greatly improved with the addition of PNAS. When PNAS loading was 50 wt%, the glass transition temperature value of PVC/PNAS hybrid composite was increased by 22.4°C, compared with that of pristine PVC. The mechanical properties of the PVC composite were also enhanced with the addition of PNAS.

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Preparation of Polymer Nanoparticles and Application on Nitrile-Butadiene Rubber Reinforcement

Materials Science Forum ◽

10.4028/www.scientific.net/msf.900.35 ◽

2017 ◽

Vol 900 ◽

pp. 35-39

Author(s):

Cheng Chien Wang ◽

Chih Lung Chiu ◽

Jian Sheng Shen

Keyword(s):

Mechanical Properties ◽

Hydroxyl Group ◽

Molar Ratio ◽

Butadiene Rubber ◽

Microemulsion Polymerization ◽

Rubber Latex ◽

Elongation At Break ◽

Divinyl Benzene ◽

Rubber Nanocomposites ◽

Average Size

The different amount of hydrophilic hydroxyl group, including 3, 5, 7 and 10 wt.% copoly (styrene-co - divinyl benzene – co - 2-hydroxylethylenemethacrylate) (poly (St-co-DVB- co -HEMA) s) nanoparticles were synthesized via microemulsion polymerization in the present paper. The average size of the poly (St-co-DVB-co-HEMA) s was ca. 44 nm after zetasizer (DLS) measurement and SEM observation. The characteristic peaks at 3200 ~3600 cm-1 in FTIR was assigned at hydroxyl group of HEMA unit. The NBR/poly (St-co-DVB-co-HEMA) s composites films with 250 μm thickness were prepared simply via latex mixing and followed by spinning coating. The mechanical properties of the poly (St-co-DVB-co-HEMA) s/rubber nanocomposites, including the tensile strength, modulus and elongation, were increased with that of increasing of poly (St-co-DVB-co-HEMA) s adding. In addition, as the poly (St-co-DVB-co-HEMA) s nanoparticles carried out with constant St/HEMA molar ratio of 97:3 and the DVB content in 10 wt.%, the elongation at break that up to more than 3500% and the ultimate stress increased from 0.2 MPa to 0.6 MPa. The poly (St-co-DVB-co-HEMA) s nanoparticles prepared by emulsion polymerization could be successfully enhanced the mechanical properties of rubber latex.

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