Simulated Adsorption Properties and Synthesis Prospects of Homochiral Porous Solids Based on Their Heterochiral Analogs

Langmuir ◽  
2005 ◽  
Vol 21 (6) ◽  
pp. 2267-2272 ◽  
Author(s):  
Louis A. Clark ◽  
Shaji Chempath ◽  
Randall Q. Snurr
Keyword(s):  
Adsorption Properties ◽  
Porous Solids

The role of accessibility in the characterization of porous solids and their adsorption properties

Adsorption ◽  
2009 ◽  
Vol 16 (1-2) ◽  
pp. 3-15 ◽  
Author(s):  
D. D. Do ◽  
L. Herrera ◽  
Chunyan Fan ◽  
A. Wongkoblap ◽  
D. Nicholson
Keyword(s):  
Adsorption Properties ◽  
Porous Solids

scholarly journals Understanding static, dynamic and cooperative porosity in molecular materials

2016 ◽  
Vol 7 (8) ◽  
pp. 4875-4879 ◽  
Author(s):  
Daniel Holden ◽  
Samantha Y. Chong ◽  
Linjiang Chen ◽  
Kim E. Jelfs ◽  
Tom Hasell ◽  
...  
Keyword(s):  
Molecular Simulations ◽  
Adsorption Properties ◽  
Adsorption Behavior ◽  
Porous Solids ◽  
Molecular Materials

The practical adsorption properties of molecular porous solids can be dominated by dynamic flexibility but these effects are still poorly understood. Here, we combine molecular simulations and experiments to rationalize the adsorption behavior of a flexible porous organic cage.

Effect of gas-dynamic phenomena on adsorption properties of coal in Krasnolimanskaya Mine

2018 ◽  
Vol 11 ◽  
pp. 46-55
Author(s):  
E.V. Ulyanova ◽  
◽  
V.A. Vasilkovskiy ◽  
O.N. Malinnikova ◽  
◽  
...  
Keyword(s):  
Adsorption Properties ◽  
Gas Dynamic ◽  
Dynamic Phenomena

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Controlling Gas Selectivity in Molecular Porous Liquids by Tuning the Cage Window Size

2019 ◽  
Author(s):  
Benjamin Egleston ◽  
Konstantin V. Luzyanin ◽  
Michael C. Brand ◽  
Rob Clowes ◽  
Michael E. Briggs ◽  
...  
Keyword(s):  
Nmr Spectroscopy ◽  
Chemical Synthesis ◽  
Field Gradient ◽  
Window Size ◽  
Standard Approach ◽  
Porous Solids ◽  
Pulsed Field Gradient Nmr ◽  
Pulsed Field ◽  
Cage Molecules ◽  
Gas Selectivity

Control of pore window size is the standard approach for tuning gas selectivity in porous solids. Here, we present the first example where this is translated into a molecular porous liquid formed from organic cage molecules. Reduction of the cage window size by chemical synthesis switches the selectivity from Xe-selective to CH<sub>4</sub>-selective, which is understood using <sup>129</sup>Xe, <sup>1</sup>H, and pulsed-field gradient NMR spectroscopy.

Two Consecutive Magneto-Structural Gas-Solid Transformations with Single-Crystal Retention in Non-Porous Molecular Materials

2018 ◽  
Author(s):  
Julia Miguel-Donet ◽  
Javier López-Cabrelles ◽  
Nestor Calvo Galve ◽  
Eugenio Coronado ◽  
Guillermo Minguez Espallargas
Keyword(s):  
Solid State ◽  
Single Crystal ◽  
Structural Rearrangement ◽  
Magnetic Behaviour ◽  
Porous Solids ◽  
Potential Applications ◽  
Hcl Gas ◽  
Porous Coordination Polymer ◽  
Gas Molecules ◽  
Magnetostructural Transformation

<p>Modification of the magnetic properties in a solid-state material upon external stimulus has attracted much attention in the recent years for their potential applications as switches and sensors. Within the field of coordination polymers, gas sorption studies typically focus on porous solids, with the gas molecules accommodating in the channels. Here we present a 1D non-porous coordination polymer capable of incorporating HCl gas molecules, which not only causes a reordering of its atoms in the solid state but also provokes dramatic changes in the magnetic behaviour. Subsequently, a further solid-gas transformation can occur with the extrusion of HCl gas molecules causing a second structural rearrangement which is also accompanied by modification in the magnetic path between the metal centres. Unequivocal evidence of the two-step magnetostructural transformation is provided by X-ray single-crystal diffraction.</p>

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