Emulsion Polymerization of Styrene Using the Homopolymer of a Reactive Surfactant

Langmuir ◽  
2001 ◽  
Vol 17 (22) ◽  
pp. 6865-6870 ◽  
Author(s):  
X. Wang ◽  
E. D. Sudol ◽  
M. S. El-Aasser
Keyword(s):  
Emulsion Polymerization ◽  
Reactive Surfactant

A novel copolymer of N-[(tert-butylperoxy)methyl]acrylamide and maleic anhydride for use as a reactive surfactant in emulsion polymerization

2013 ◽  
Vol 73 (9) ◽  
pp. 1290-1298 ◽  
Author(s):  
Andriy Popadyuk ◽  
Ihor Tarnavchyk ◽  
Nadiya Popadyuk ◽  
Ananiy Kohut ◽  
Volodymyr Samaryk ◽  
...  
Keyword(s):  
Maleic Anhydride ◽  
Emulsion Polymerization ◽  
Reactive Surfactant

Effect of a Reactive Surfactant and Its Polymeric Counterpart on the Kinetics of Seeded Emulsion Polymerization of Styrene

2001 ◽  
Vol 34 (26) ◽  
pp. 8907-8912 ◽  
Author(s):  
Xiaoru Wang ◽  
Bito Boya ◽  
E. David Sudol ◽  
Mohamed S. El-Aasser
Keyword(s):  
Emulsion Polymerization ◽  
Seeded Emulsion Polymerization ◽  
Reactive Surfactant ◽  
Kinetics Of

Preparation and Properties of Anionic Polymer Emulsion in the Presence of a Reactive Surfactant

2012 ◽  
Vol 262 ◽  
pp. 430-434
Author(s):  
Hua Sheng Lu ◽  
Zhong Xiao Li ◽  
Yu Guang Feng ◽  
Jia Ling Pu
Keyword(s):  
Emulsion Polymerization ◽  
Solid Content ◽  
Nano Particles ◽  
Butyl Methacrylate ◽  
Particle Sizes ◽  
Material System ◽  
Polymer Emulsion ◽  
Sensitive Material ◽  
Anionic Polymer ◽  
Reactive Surfactant

Stable polymer emulsion derived from Butyl Methacrylate (BMA), 4-vinyl pyridine (4-VP), vinylidene chloride (VDC) and divinylbenzene (DVB) with different size and distribution were prepared through soapless emulsion polymerization by using a reactive surfactant and a redox initiator. The influences of the quality ratio of the reactive surfactant to the monomers and the dosages of the cross-linking agent on the stability and thermal properties of the emulsion were studied. The obtained polymer nano-particles have higher ξ potential, and the particle sizes have narrow distribution. This polymerization system can give some further understanding on the mechanism of emulsion polymerization .The solid content of the emulsion could be as high as 40% and the particle sizes could be adjusted in the range of 40-300nm. Otherwise, using infrared spectroscopy, size and ξ analyzer, gravitational thermal analysis and differential scanning calorimeter, properties of the emulsion latex were tested. This kind of latex may have applications in the development of water-developable thermal-sensitive material system.

Kinetics of emulsion polymerization of styrene using the reactive surfactant HITENOL BC20

2008 ◽  
Vol 109 (4) ◽  
pp. 2275-2282 ◽  
Author(s):  
Zhen Lai ◽  
E. David Sudol ◽  
Victoria L. Dimonie ◽  
Mohamed S. El-Aasser
Keyword(s):  
Emulsion Polymerization ◽  
Reactive Surfactant ◽  
Kinetics Of
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