Ellipsometric characterization of Langmuir monolayers of "hairy-rod" polymers at the air-water interface

Langmuir ◽  
1991 ◽  
Vol 7 (11) ◽  
pp. 2743-2747 ◽  
Author(s):  
H. Motschmann ◽  
R. Reiter ◽  
R. Lawall ◽  
G. Duda ◽  
M. Stamm ◽  
...  
Keyword(s):  
Langmuir Monolayers ◽  
Water Interface ◽  
Ellipsometric Characterization ◽  
Air Water Interface

Ellipsometric Characterization of Ethylene Oxide−Butylene Oxide Diblock Copolymer Adsorption at the Air−Water Interface

Langmuir ◽  
2005 ◽  
Vol 21 (11) ◽  
pp. 5061-5068 ◽  
Author(s):  
B. Rippner Blomqvist ◽  
J.-W. Benjamins ◽  
T. Nylander ◽  
T. Arnebrant
Keyword(s):  
Ethylene Oxide ◽  
Diblock Copolymer ◽  
Water Interface ◽  
Ellipsometric Characterization ◽  
Air Water Interface

SYNTHESIS OF AMPHIPHILIE TEMPO DERIVATIVE AND CHARACTERIZATION OF LANGMUIR MONOLAYERS OF AMPHIPHILIC ALKYL-TEMPOs AT THE AIR/WATER INTERFACE

2006 ◽  
Vol 05 (06) ◽  
pp. 787-793
Author(s):  
YOUNG SOO KANG ◽  
MI HYANG JEONG ◽  
SOO JA SHIN ◽  
YOUNG HWAN KIM ◽  
CHANG WOO KIM
Keyword(s):  
Alkyl Chain ◽  
Langmuir Monolayers ◽  
Langmuir Monolayer ◽  
Water Interface ◽  
Brewster Angle Microscopy ◽  
Collapse Pressure ◽  
Air Water Interface ◽  
Pressure Area ◽  
Hydrophobic Tail

The amphiphilic TEMPO molecules consist of two dissimilar parts. One part is hydrophilic (head) and the rest part is hydrophobic (tail). The derivatives of 4-alkaneamino-2, 2, 6, 6-tetramethyl-1-piperidinyloxy radical ( C n-amino-TEMPO, n = 14, 16, 18, 20, 22) was synthesized with 4-amino-TEMPO and carboxylic acid. The C n-amino-TEMPOs equilibrated at the air/water interface form Langmuir monolayer by classical Langmuir monolayer techniques. The stable monolayers of C 14-22-amino-TEMPOs were characterized by pressure–area isotherms. The features of collapse pressure of C 14-22-amino-TEMPOs were confirmed on alkyl chain length. Limiting area points and take-off area points from surface pressure-MMA isotherms were subjected to the influence of subphase. The monolayer of C 22-amino-TEMPO which has longer alkyl chain was characterized by Brewster Angle Microscopy. So we can confirm phase transition by BAM images as monolayer is expanding at the room temperature.

In situ structure and force characterization of 2D nano-colloids at the air/water interface

Soft Matter ◽  
2019 ◽  
Vol 15 (42) ◽  
pp. 8475-8482
Author(s):  
Giovanni Li-Destri ◽  
Roberta Ruffino ◽  
Nunzio Tuccitto ◽  
Giovanni Marletta
Keyword(s):  
Quantitative Determination ◽  
Experimental Method ◽  
Water Interface ◽  
Liquid Interfaces ◽  
Interaction Forces ◽  
Air Water Interface

We have developed a novel experimental method, which enables quantitative determination of interaction forces between interfacial nanoparticles as a function of the inter-particle distance at liquid interfaces.

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